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Information card for entry 7035943
Preview
| Coordinates | 7035943.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C40 H50 N4 Rh2 |
|---|---|
| Calculated formula | C40 H50 N4 Rh2 |
| SMILES | c12n(cc[n]1[Rh]134(c5n(cc[n]5[Rh]5672[CH]2=[CH]5CC[CH]6=[CH]7CC2)c2c(cc(cc2C)C)C)[CH]2=[CH]1CC[CH]3=[CH]4CC2)c1c(cc(cc1C)C)C |
| Title of publication | Dinuclear iridium and rhodium complexes with bridging arylimidazolide-N(3),C(2) ligands: synthetic, structural, reactivity, electrochemical and spectroscopic studies. |
| Authors of publication | He, Fan; Ruhlmann, Laurent; Gisselbrecht, Jean-Paul; Choua, Sylvie; Orio, Maylis; Wesolek, Marcel; Danopoulos, Andreas A.; Braunstein, Pierre |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2015 |
| Journal volume | 44 |
| Journal issue | 39 |
| Pages of publication | 17030 - 17044 |
| a | 12.4452 ± 0.0007 Å |
| b | 18.7469 ± 0.001 Å |
| c | 17.5877 ± 0.0007 Å |
| α | 90° |
| β | 119.594 ± 0.003° |
| γ | 90° |
| Cell volume | 3568.1 ± 0.3 Å3 |
| Cell temperature | 173 ± 2 K |
| Ambient diffraction temperature | 173 ± 2 K |
| Number of distinct elements | 4 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0671 |
| Residual factor for significantly intense reflections | 0.0347 |
| Weighted residual factors for significantly intense reflections | 0.0695 |
| Weighted residual factors for all reflections included in the refinement | 0.0815 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.025 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 176428 (current) | 2016-02-13 | Replaced deprecated COD CIF data names with their more modern alternatives. The _cod_cif_authors_sg_Hall and _cod_cif_authors_sg_H-M data items were renamed to _cod_original_sg_symbol_Hall and _cod_cif_authors_sg_H-M respectively. |
7035943.cif |
| 161190 | 2015-10-09 | cif/ Updating files of 7035941, 7035942, 7035943, 7035944 Original log message: Adding full bibliography for 7035941--7035944.cif. |
7035943.cif |
| 152501 | 2015-07-24 | cif/ Adding structures of 7035941, 7035942, 7035943, 7035944 via cif-deposit CGI script. |
7035943.cif |
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