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Information card for entry 7035931
Preview
| Coordinates | 7035931.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C47 H41 Cl5 N P Si2 |
|---|---|
| Calculated formula | C47 H41 Cl5 N P Si2 |
| SMILES | P(N(c1c(cc(cc1C(c1ccccc1)c1ccccc1)C(C)C)C(c1ccccc1)c1ccccc1)[Si](Cl)(Cl)[Si](Cl)(Cl)Cl)(c1ccccc1)c1ccccc1 |
| Title of publication | Extremely bulky secondary phosphinoamines as substituents for sterically hindered aminosilanes. |
| Authors of publication | Böttcher, Tobias; Jones, Cameron |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2015 |
| Journal volume | 44 |
| Journal issue | 33 |
| Pages of publication | 14842 - 14853 |
| a | 10.124 ± 0.0008 Å |
| b | 20.1891 ± 0.0015 Å |
| c | 21.6338 ± 0.0019 Å |
| α | 90° |
| β | 92.815 ± 0.007° |
| γ | 90° |
| Cell volume | 4416.5 ± 0.6 Å3 |
| Cell temperature | 123 ± 2 K |
| Ambient diffraction temperature | 123 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0937 |
| Residual factor for significantly intense reflections | 0.0577 |
| Weighted residual factors for significantly intense reflections | 0.1276 |
| Weighted residual factors for all reflections included in the refinement | 0.1466 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.021 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 176428 (current) | 2016-02-13 | Replaced deprecated COD CIF data names with their more modern alternatives. The _cod_cif_authors_sg_Hall and _cod_cif_authors_sg_H-M data items were renamed to _cod_original_sg_symbol_Hall and _cod_cif_authors_sg_H-M respectively. |
7035931.cif |
| 161827 | 2015-10-09 | cif/ Updating files of 7035922, 7035923, 7035924, 7035925, 7035926, 7035927, 7035928, 7035929, 7035930, 7035931, 7035932, 7035933, 7035934 Original log message: Adding full bibliography for 7035922--7035934.cif. |
7035931.cif |
| 152459 | 2015-07-23 | cif/ Adding structures of 7035922, 7035923, 7035924, 7035925, 7035926, 7035927, 7035928, 7035929, 7035930, 7035931, 7035932, 7035933, 7035934 via cif-deposit CGI script. |
7035931.cif |
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Users of the data should acknowledge the original authors of the
structural data.