#------------------------------------------------------------------------------ #$Date: 2020-06-30 07:56:05 +0300 (Tue, 30 Jun 2020) $ #$Revision: 253553 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/02/21/2022177.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2022177 loop_ _publ_author_name 'Deng, Qianjun' 'Wang, Jiming' 'Li, Guangzhao' 'Zhang, Shuhua' _publ_section_title ; Synthesis, structure and magnetism of a new ionic pentanuclear iron cluster ; _journal_coeditor_code YO3074 _journal_issue 7 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first ; ; _journal_paper_doi 10.1107/S205322962000861X _journal_volume 76 _journal_year 2020 _chemical_formula_iupac '(C6 H16 N) [Fe5 (C8 H4 Cl N5 O)4 (C H2 N5)4 O2], C2 H3 N, H2 O' _chemical_formula_moiety 'C6 H16 N +, C36 H24 Cl4 Fe5 N40 O6 -, C2 H3 N, H2 O' _chemical_formula_sum 'C44 H45 Cl4 Fe5 N42 O7' _chemical_formula_weight 1695.27 _chemical_name_systematic ;Triethylazanium tetrakis(\m~2~-5-amino-1,2,3,4-tetrazolido)tetrakis(\m~3~-4-chloro-2-{[(1H-tetrazol-1-id-5-yl)imino]methyl}phenolato)di-\m~3~-oxido-pentairon(III) acetonitrile monosolvate monohydrate ; _space_group_crystal_system monoclinic _space_group_IT_number 14 _space_group_name_Hall '-P 2yn' _space_group_name_H-M_alt 'P 1 21/n 1' _atom_sites_solution_hydrogens mixed _audit_creation_method SHELXL-2014 _cell_angle_alpha 90 _cell_angle_beta 98.393(2) _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 11.2862(3) _cell_length_b 29.3083(8) _cell_length_c 19.6024(6) _cell_measurement_reflns_used 11461 _cell_measurement_temperature 293(2) _cell_measurement_theta_max 27.6050 _cell_measurement_theta_min 3.6980 _cell_volume 6414.6(3) _computing_cell_refinement ; CrysAlis PRO (Rigaku OD, 2019) ; _computing_data_collection ; CrysAlis PRO (Rigaku OD, 2019) ; _computing_data_reduction ; CrysAlis PRO (Rigaku OD, 2019) ; _computing_molecular_graphics ; SHELXTL (Sheldrick, 2015b) ; _computing_publication_material ; SHELXL2018 (Sheldrick, 2015b) ; _computing_structure_refinement ; SHELXL2018 (Sheldrick, 2015b), OLEX2 (Dolomanov et al., 2009), olex2.refine (Bourhis et al., 2015) ; _computing_structure_solution ; SHELXT (Sheldrick, 2015a) ; _diffrn_ambient_temperature 293(2) _diffrn_detector_area_resol_mean 15.9784 _diffrn_measured_fraction_theta_full 0.971 _diffrn_measured_fraction_theta_max 0.998 _diffrn_measurement_device_type 'Rigaku OD SuperNova Single source diffractometer with an Eos detector' _diffrn_measurement_method 'phi and omega scans' _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0413 _diffrn_reflns_av_unetI/netI 0.0426 _diffrn_reflns_limit_h_max 13 _diffrn_reflns_limit_h_min -13 _diffrn_reflns_limit_k_max 34 _diffrn_reflns_limit_k_min -34 _diffrn_reflns_limit_l_max 23 _diffrn_reflns_limit_l_min -23 _diffrn_reflns_number 41127 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 25.009 _diffrn_reflns_theta_min 3.326 _diffrn_standards_decay_% 0 _diffrn_standards_interval_count 0 _diffrn_standards_interval_time 0 _diffrn_standards_number 0 _exptl_absorpt_coefficient_mu 1.356 _exptl_absorpt_correction_T_max 0.806 _exptl_absorpt_correction_T_min 0.741 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; (CrysAlis PRO; Rigaku OD, 2019) ; _exptl_crystal_colour 'Bright black' _exptl_crystal_density_diffrn 1.755 _exptl_crystal_description prism _exptl_crystal_F_000 3428 _exptl_crystal_size_max 0.23 _exptl_crystal_size_mid 0.19 _exptl_crystal_size_min 0.16 _refine_diff_density_max 0.873 _refine_diff_density_min -0.609 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.008 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 942 _refine_ls_number_reflns 11282 _refine_ls_number_restraints 66 _refine_ls_restrained_S_all 1.010 _refine_ls_R_factor_all 0.0765 _refine_ls_R_factor_gt 0.0536 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0967P)^2^+14.1292P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.1480 _refine_ls_wR_factor_ref 0.1746 _reflns_number_gt 8624 _reflns_number_total 11282 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file yo3074sup1.cif _cod_data_source_block I _cod_original_sg_symbol_H-M 'P 21/n' _cod_database_code 2022177 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_hkl_file ; 0 0 4 14.40 1.32 0 0 -4 14.65 1.26 0 0 -5 1.43 0.66 0 0 5 1.80 0.74 0 0 6 22.05 2.04 0 0 -6 25.43 2.18 0 0 7 1.23 0.69 0 0 -7 1.94 0.87 0 0 -8 128.90 5.49 0 0 -9 -0.69 0.98 0 0 -10 118.00 5.82 0 0 -11 -5.65 1.55 0 0 -12 22.37 2.80 0 0 -13 0.97 1.38 0 0 -14 291.26 11.42 0 0 -15 3.88 1.87 0 0 15 3.74 2.55 0 0 -16 41.62 4.56 0 0 16 41.01 5.40 0 0 -17 -0.23 1.43 0 0 17 -1.79 2.00 0 0 -18 14.99 2.85 0 0 18 12.03 3.24 0 0 -19 -1.81 1.90 0 0 19 0.18 1.84 0 0 -20 44.23 5.25 0 0 20 43.71 6.23 0 0 -21 -0.54 1.48 0 0 21 -2.98 2.72 0 0 22 34.80 6.14 0 0 -22 40.40 5.26 0 0 23 3.14 2.61 0 0 -23 -1.83 1.39 0 0 24 26.09 5.73 0 0 -24 23.91 4.33 0 1 4 -0.15 0.31 0 -1 4 0.23 0.35 0 1 -4 -0.02 0.33 0 -1 -4 0.76 0.46 0 -1 5 107.64 4.27 0 -1 -5 109.36 3.99 0 1 5 103.62 4.09 0 1 -5 100.01 3.99 0 1 6 291.79 8.29 0 -1 6 282.10 8.38 0 1 -6 300.23 8.22 0 -1 -6 306.44 8.14 0 1 -7 18.45 1.84 0 -1 7 15.30 1.82 0 -1 -7 18.43 1.84 0 1 7 17.40 1.90 0 1 -8 88.54 4.54 0 -1 -8 81.70 4.33 0 1 -9 58.69 3.84 0 -1 -9 67.24 4.04 0 1 -10 106.46 5.50 0 -1 -10 112.99 5.62 0 1 -11 3.84 1.19 0 -1 -11 6.21 1.63 0 -1 -12 315.94 10.96 0 1 -12 308.02 10.95 0 1 -13 2.79 1.60 0 -1 -13 3.01 1.91 0 1 13 6.27 2.75 0 1 -14 259.79 10.62 0 -1 -14 252.46 10.45 0 1 14 265.45 12.81 0 -1 -15 41.74 4.39 0 1 -15 43.28 4.40 0 1 15 34.53 4.83 0 1 -15 33.08 1.69 0 1 -16 63.32 5.41 0 -1 -16 61.75 5.40 0 1 16 60.85 6.39 0 -1 -17 4.44 1.89 0 1 -17 4.81 1.75 0 -1 17 3.42 2.09 0 1 17 6.38 2.29 0 -1 -18 -4.39 2.32 0 1 -18 -1.00 1.25 0 -1 18 -1.86 2.02 0 1 18 -1.05 2.23 0 1 -19 31.00 4.39 0 -1 -19 28.72 4.20 0 -1 19 22.96 4.81 0 1 19 28.90 5.11 0 -1 -20 0.37 1.58 0 1 -20 3.66 2.31 0 -1 20 -1.30 2.38 0 1 20 2.72 2.70 0 1 -21 0.06 1.52 0 1 21 0.19 1.85 0 -1 21 -0.25 2.06 0 -1 -21 0.88 1.59 0 1 22 8.54 3.86 0 -1 22 5.97 3.74 0 1 -22 3.40 2.72 0 -1 -22 8.48 2.90 0 -1 23 1.74 2.41 0 1 23 1.60 2.10 0 -1 -23 1.53 1.52 0 1 -23 3.39 1.91 0 1 24 -0.69 2.01 0 -1 24 7.02 3.59 0 -1 -24 0.96 1.67 0 1 -24 2.60 2.14 0 2 -3 58.54 2.77 0 -2 3 63.34 2.63 0 2 -3 62.60 2.53 0 -2 -3 66.29 2.38 0 2 3 61.43 2.39 0 2 3 61.01 2.71 0 -2 -3 58.57 2.68 0 -2 -4 1141.40 20.27 0 2 -4 1122.88 20.59 0 2 4 1073.89 20.33 0 -2 4 1127.26 20.94 0 2 4 1153.83 21.41 0 2 5 75.88 3.37 0 -2 -5 78.38 3.32 0 2 -5 73.95 3.37 0 -2 5 78.86 3.65 0 2 5 71.15 3.74 0 2 -6 1.08 0.58 0 2 6 0.35 0.41 0 -2 -6 -0.51 0.71 0 -2 6 1.92 0.69 0 2 6 0.05 0.93 0 2 -7 52.81 3.26 0 -2 -7 56.47 3.24 0 2 7 52.53 3.32 0 -2 7 54.75 3.58 0 2 7 50.96 3.66 0 2 -8 16.97 1.98 0 -2 -8 14.93 1.83 0 2 8 12.29 1.63 0 2 -9 37.55 3.09 0 -2 -9 38.73 3.04 0 2 9 35.19 3.39 0 2 -10 38.32 3.26 0 -2 -10 38.82 3.32 0 2 10 30.84 3.50 0 2 -10 36.67 1.51 0 2 -11 70.78 4.72 0 -2 -11 77.23 4.79 0 2 11 81.43 5.88 0 2 -11 68.65 2.22 0 2 -12 80.86 5.32 0 -2 -12 73.58 5.00 0 2 12 80.66 6.24 0 2 -13 141.85 7.37 0 -2 -13 134.54 7.24 0 2 13 144.02 8.92 0 -2 -14 84.47 5.97 0 2 -14 83.53 5.90 0 2 14 91.87 7.48 0 2 -15 16.38 2.83 0 -2 -15 17.51 2.91 0 2 15 16.29 3.65 0 2 -16 28.99 3.77 0 -2 -16 21.10 3.35 0 2 16 25.43 4.35 0 2 -17 8.63 2.46 0 -2 -17 9.40 2.18 0 2 17 9.95 2.82 0 -2 -18 11.63 2.55 0 2 -18 14.02 2.99 0 2 18 16.26 3.65 0 -2 -19 83.05 6.93 0 2 -19 92.28 7.46 0 -2 19 84.51 8.50 0 2 19 94.17 8.87 0 2 -20 96.99 7.89 0 -2 -20 95.27 7.67 0 -2 20 93.43 9.38 0 2 20 90.21 8.97 0 2 -21 25.80 4.32 0 2 21 13.13 3.86 0 -2 21 24.04 4.83 0 -2 -21 16.36 3.46 0 -2 -22 113.57 9.05 0 2 -22 130.82 9.55 0 -2 22 132.57 11.48 0 2 22 113.12 10.67 0 -2 23 5.71 3.05 0 2 23 7.10 3.31 0 2 -23 3.71 1.97 0 -2 -23 3.66 2.19 0 2 -24 47.66 6.09 0 -2 -24 36.23 5.46 0 2 24 38.40 6.69 0 -2 24 27.16 5.93 0 -3 3 110.45 3.80 0 3 -3 107.16 3.59 0 3 3 107.42 3.34 0 -3 -3 109.84 3.30 0 3 3 105.82 3.84 0 -3 -3 108.82 3.94 0 -3 3 111.14 4.02 0 3 -3 102.15 3.94 0 -3 4 65.72 3.14 0 3 -4 70.17 3.12 0 3 4 61.29 2.75 0 -3 -4 59.16 2.63 0 3 4 64.24 3.23 0 -3 -4 58.64 3.12 0 3 -4 62.69 3.31 0 3 5 8.09 1.36 0 3 -5 4.72 1.08 0 -3 5 5.41 1.15 0 -3 -5 8.62 1.37 0 3 -5 9.54 1.77 0 3 5 6.87 1.62 0 3 -6 214.18 6.81 0 -3 6 220.99 7.24 0 3 6 207.14 6.68 0 -3 -6 220.36 6.62 0 3 6 220.54 7.70 0 3 7 14.03 1.70 0 -3 7 12.96 1.71 0 3 -7 14.49 1.83 0 3 7 12.06 1.73 0 -3 -8 302.06 9.05 0 3 -8 289.57 9.17 0 3 8 296.80 10.43 0 3 -9 599.83 15.23 0 -3 -9 570.22 14.79 0 3 -10 178.36 7.42 0 -3 -10 172.70 7.18 0 3 10 168.75 8.40 0 3 -11 91.75 5.43 0 -3 -11 95.33 5.47 0 3 11 95.41 6.48 0 3 -12 74.44 5.07 0 -3 -12 62.44 4.65 0 3 12 63.20 5.67 0 -3 -13 298.11 11.18 0 3 -13 293.93 11.17 0 3 13 315.15 13.47 0 -3 -14 63.91 5.12 0 3 -14 63.82 5.08 0 3 14 77.81 6.75 0 -3 -15 76.13 5.73 0 3 -15 75.45 5.83 0 3 15 72.31 6.85 0 3 -16 5.80 2.12 0 -3 -16 2.65 1.27 0 3 16 4.80 2.31 0 3 -17 8.89 2.43 0 -3 -17 5.88 1.79 0 3 17 9.59 2.74 0 3 -18 3.57 2.33 0 3 18 0.79 1.94 0 -3 -18 -0.89 1.38 0 3 -19 13.04 3.14 0 3 19 8.96 3.23 0 -3 -19 9.48 2.79 0 3 -20 7.34 3.00 0 -3 20 5.10 3.04 0 3 20 6.28 2.72 0 -3 -20 4.66 2.39 0 3 -21 9.29 3.07 0 -3 21 2.56 2.96 0 3 21 3.96 3.01 0 -3 -21 3.08 2.37 0 3 -22 8.84 2.95 0 3 22 4.55 3.31 0 -3 22 4.38 3.54 0 -3 -22 6.45 2.67 0 3 -23 6.69 2.52 0 -3 -23 3.16 2.09 0 -3 23 1.85 2.06 0 3 23 5.83 2.95 0 3 -24 3.45 2.15 0 -3 -24 4.83 2.50 0 3 24 6.55 2.71 0 -3 24 3.62 3.12 0 4 -2 131.61 3.79 0 -4 2 123.29 3.83 0 4 2 124.22 3.37 0 4 2 124.99 4.15 0 -4 -2 122.63 4.15 0 4 -2 125.76 4.18 0 -4 2 133.97 4.22 0 4 -3 410.31 9.08 0 4 3 393.59 8.45 0 -4 3 407.90 9.24 0 -4 -3 412.35 8.47 0 4 3 409.86 9.68 0 -4 -3 418.89 9.69 0 -4 3 433.24 9.87 0 4 -3 399.02 9.65 0 -4 -4 3034.65 50.06 0 -4 4 3015.74 51.27 0 4 -4 3025.59 50.80 0 4 4 2970.84 50.16 0 4 4 3063.37 51.75 0 -4 -4 3058.07 51.81 0 -4 4 3193.86 52.18 0 4 -4 2969.23 51.90 0 4 -5 5218.62 86.90 0 -4 -5 5603.43 86.28 0 4 5 5293.00 86.35 0 -4 5 5314.59 87.56 0 -4 -5 5367.45 88.08 0 4 5 5488.78 88.18 0 4 -5 5311.39 88.41 0 -4 -6 14.09 1.55 0 4 -6 13.07 1.80 0 -4 6 13.62 1.66 0 4 6 13.44 1.53 0 4 -6 13.99 1.76 0 -4 -6 14.29 1.74 0 4 6 17.46 2.11 0 -4 7 257.51 8.75 0 4 -7 272.64 8.45 0 4 7 266.07 8.34 0 -4 -7 296.86 8.36 0 4 7 287.05 9.52 0 -4 -8 257.23 8.23 0 4 -8 239.67 8.36 0 4 8 246.87 9.44 0 4 -9 4.48 1.81 0 -4 -9 7.81 1.97 0 4 9 2.22 1.43 0 -4 -10 2.54 1.36 0 4 -10 1.36 1.41 0 4 10 2.08 1.53 0 -4 -11 83.26 5.16 0 4 -11 90.35 5.45 0 4 11 87.09 6.36 0 -4 -12 174.06 7.85 0 4 -12 163.27 7.73 0 4 12 156.84 8.99 0 4 -13 100.36 6.13 0 -4 -13 84.37 5.72 0 4 13 95.25 7.12 0 4 -14 61.55 4.97 0 -4 -14 63.65 5.02 0 4 14 59.70 5.96 0 -4 -15 60.93 5.25 0 4 -15 71.22 5.61 0 4 15 60.98 6.46 0 4 -16 7.20 2.27 0 4 16 5.98 2.38 0 -4 -16 7.05 2.12 0 4 -17 8.18 2.48 0 4 17 5.45 2.25 0 -4 -17 5.58 1.87 0 4 -18 61.05 5.85 0 -4 -18 49.18 5.18 0 4 18 48.49 6.09 0 4 -19 113.20 8.12 0 -4 -19 122.80 8.37 0 4 19 113.58 9.70 0 4 -20 31.48 4.53 0 4 20 27.06 5.13 0 -4 -20 30.03 4.55 0 -4 -21 94.36 7.84 0 4 -21 99.44 8.02 0 -4 21 76.21 8.70 0 4 21 82.72 8.85 0 4 -22 6.86 2.56 0 -4 22 8.23 3.61 0 4 22 5.56 2.74 0 -4 -22 10.64 2.98 0 4 -23 23.19 4.44 0 -4 -23 18.01 3.80 0 4 23 16.82 4.39 0 -4 23 19.97 4.79 0 4 -24 4.50 2.40 0 -4 -24 4.93 2.56 0 -4 24 5.00 3.06 0 4 24 0.00 2.01 0 -5 0 0.45 0.61 0 -5 0 1.66 0.68 0 5 0 1.00 0.56 0 5 -1 300.65 6.56 0 5 1 297.48 7.43 0 -5 -1 297.23 7.43 0 -5 1 290.03 7.50 0 5 -1 288.57 7.18 0 -5 -1 307.31 7.13 0 5 1 290.16 7.08 0 -5 1 294.46 7.18 0 -5 2 91.33 3.41 0 5 -2 95.69 3.35 0 5 2 96.16 2.94 0 -5 -2 94.57 2.91 0 5 2 100.43 3.84 0 -5 -2 95.97 3.80 0 -5 -2 103.62 3.74 0 5 -2 96.04 3.73 0 -5 2 98.22 3.78 0 5 -3 1096.45 20.44 0 5 3 1099.72 19.68 0 -5 3 1112.77 20.71 0 -5 -3 1130.92 19.68 0 -5 -3 1101.92 21.31 0 5 3 1121.32 21.41 0 -5 3 1165.16 21.51 0 5 -3 1068.23 21.24 0 5 -4 258.75 7.08 0 -5 4 253.75 7.31 0 5 4 252.40 6.58 0 -5 -4 265.06 6.54 0 5 4 259.34 7.75 0 -5 -4 241.81 7.51 0 -5 4 267.57 7.96 0 5 -4 249.96 7.69 0 5 -5 774.58 16.30 0 -5 5 775.79 16.73 0 -5 -5 780.10 15.48 0 5 5 758.30 15.60 0 -5 5 798.83 13.65 0 -5 -5 747.54 17.01 0 5 5 779.71 17.27 0 5 -5 723.59 17.01 0 -5 6 81.45 4.55 0 5 -6 93.37 4.42 0 5 6 88.73 4.06 0 -5 -6 91.12 4.10 0 5 6 92.07 4.91 0 -5 -6 81.06 4.53 0 5 -6 87.94 4.80 0 5 -7 763.28 17.07 0 -5 -7 778.40 16.42 0 5 7 729.92 16.66 0 -5 -7 722.95 17.91 0 5 7 775.79 18.33 0 -5 -8 590.48 14.24 0 5 -8 574.69 14.77 0 5 8 625.97 16.38 0 -5 -9 988.80 21.27 0 5 -9 968.53 21.76 0 5 9 1001.55 23.76 0 5 -10 405.32 12.36 0 -5 -10 396.58 11.87 0 5 10 426.32 14.19 0 -5 -11 374.62 11.71 0 5 -11 339.71 11.70 0 5 11 360.19 13.39 0 5 -12 16.32 2.60 0 -5 -12 19.33 2.65 0 5 12 15.15 2.74 0 5 -13 0.23 1.24 0 -5 -13 1.29 1.22 0 5 -14 51.66 4.69 0 -5 -14 48.59 4.50 0 5 14 51.98 5.49 0 5 -15 74.62 5.69 0 -5 -15 75.36 5.91 0 5 15 76.09 6.84 0 5 -16 27.58 3.66 0 -5 -16 33.84 3.96 0 5 16 21.47 3.95 0 5 -17 3.08 1.84 0 5 17 1.49 1.91 0 -5 -17 1.01 1.60 0 5 -18 50.82 5.33 0 -5 -18 43.71 4.97 0 5 18 47.25 6.18 0 5 19 -2.08 2.07 0 -5 -19 -0.02 1.38 0 5 -20 8.79 2.70 0 5 20 3.84 2.48 0 -5 -20 5.49 2.44 0 5 -21 2.67 1.90 0 5 21 -0.24 1.90 0 -5 -21 3.68 2.25 0 5 -22 15.22 3.66 0 5 22 12.57 3.82 0 -5 -22 7.09 2.50 0 5 -23 6.31 2.67 0 -5 23 5.78 3.19 0 5 23 3.55 2.92 0 -5 -23 8.43 2.91 0 5 -24 7.58 2.73 0 -5 -24 14.97 3.69 0 5 24 14.67 4.43 0 -5 24 7.67 3.45 0 -6 0 247.13 7.00 0 6 0 239.36 6.82 0 -6 0 244.48 6.53 0 6 0 233.71 6.56 0 6 -1 391.25 8.27 0 6 1 379.95 9.37 0 -6 -1 383.64 9.38 0 -6 1 379.32 9.47 0 6 1 371.07 8.97 0 -6 -1 396.42 9.00 0 -6 1 393.64 9.10 0 6 -1 371.85 9.06 0 -6 2 43.98 2.31 0 6 -2 43.51 2.28 0 6 2 46.46 2.02 0 6 2 45.38 2.68 0 -6 -2 44.90 2.69 0 -6 -2 44.40 2.57 0 6 -2 44.51 2.62 0 -6 2 45.30 2.64 0 6 -3 278.35 7.25 0 -6 3 271.21 7.41 0 6 3 269.74 6.52 0 -6 -3 267.97 6.51 0 6 3 287.04 8.12 0 -6 -3 270.50 7.88 0 6 -3 279.45 7.92 0 -6 3 286.06 8.04 0 6 -4 119.44 4.57 0 -6 4 122.64 4.77 0 6 4 120.58 4.10 0 -6 -4 123.08 4.10 0 -6 -4 108.03 4.83 0 6 4 120.97 5.17 0 -6 4 117.78 5.11 0 6 -4 117.92 5.01 0 6 -5 131.24 5.07 0 -6 5 122.50 5.20 0 6 5 128.34 4.64 0 -6 5 129.12 3.68 0 -6 -5 127.34 4.50 0 6 5 135.21 5.73 0 -6 -5 121.25 5.40 0 6 -5 119.11 5.45 0 -6 5 139.02 5.94 0 6 6 1063.87 20.84 0 -6 6 1023.13 22.08 0 6 -6 1056.71 21.41 0 -6 -6 1080.84 20.59 0 -6 6 1038.49 18.15 0 -6 -6 1031.22 22.47 0 6 6 1093.61 22.81 0 6 -6 992.40 22.46 0 6 -7 11.99 1.93 0 6 7 8.63 1.37 0 6 7 9.23 1.92 0 -6 -7 11.32 1.59 0 -6 7 10.30 0.80 0 -6 -8 672.16 15.49 0 6 -8 653.16 16.01 0 6 8 647.61 17.40 0 6 -9 53.04 3.97 0 -6 -9 48.19 3.48 0 6 9 54.44 4.60 0 -6 -10 337.74 10.84 0 6 -10 344.58 11.35 0 6 10 357.33 13.01 0 6 -11 3.31 1.70 0 6 11 2.64 1.69 0 -6 -11 2.88 1.59 0 6 -12 15.05 2.55 0 6 12 13.91 2.74 0 -6 -12 8.67 1.90 0 6 -13 12.80 2.37 0 6 13 12.81 2.85 0 -6 -13 9.99 2.09 0 -6 -14 97.85 6.25 0 6 -14 83.43 5.97 0 6 14 87.71 7.12 0 6 -15 29.89 3.82 0 6 15 28.67 4.31 0 -6 -15 27.64 3.57 0 6 -16 22.65 3.27 0 6 16 27.61 4.32 0 -6 -16 26.75 3.56 0 6 -17 11.32 2.73 0 6 17 8.20 3.10 0 -6 -17 5.69 2.08 0 6 -18 23.52 3.75 0 6 18 24.15 4.38 0 -6 -18 31.92 4.15 0 6 -19 8.49 2.69 0 6 19 1.23 2.18 0 -6 -19 3.88 1.96 0 6 -20 2.04 1.92 0 -6 -20 0.91 1.34 0 6 -21 1.23 1.51 0 6 21 -4.45 2.83 0 -6 -21 -1.62 2.06 0 6 -22 6.22 2.58 0 6 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294.61 9.25 0 9 5 895.95 18.29 0 9 -5 907.29 19.42 0 -9 5 913.44 19.96 0 -9 -5 933.16 18.38 0 9 5 948.82 21.22 0 -9 -5 861.44 20.53 0 -9 5 976.29 21.30 0 9 6 12.18 1.54 0 -9 6 10.53 1.67 0 9 -6 11.02 1.82 0 -9 6 14.59 2.24 0 -9 -6 9.68 1.39 0 9 6 10.06 1.93 0 9 -7 28.33 2.74 0 9 7 24.16 2.27 0 -9 7 27.96 1.90 0 -9 -7 28.05 2.40 0 9 7 26.06 3.01 0 -9 7 26.57 3.06 0 9 -8 89.07 5.03 0 9 8 82.41 5.60 0 -9 8 84.57 3.23 0 -9 -8 84.32 4.52 0 9 -9 85.89 5.12 0 9 9 69.93 5.42 0 -9 9 72.59 2.76 0 -9 -9 70.85 4.45 0 9 -10 245.01 9.63 0 9 10 242.91 10.92 0 -9 10 245.20 5.60 0 -9 -10 253.32 9.06 0 -9 -11 240.49 9.23 0 9 -11 232.99 9.66 0 9 11 242.92 11.16 0 9 -12 41.06 3.96 0 -9 -12 36.92 3.59 0 9 12 38.94 4.41 0 9 -13 215.48 9.63 0 -9 -13 201.73 9.17 0 9 13 211.47 11.13 0 9 -14 49.77 4.77 0 -9 -14 53.40 4.76 0 9 14 52.01 5.77 0 9 -15 27.07 3.63 0 9 15 22.74 3.97 0 -9 -15 27.41 3.56 0 9 -16 4.98 2.09 0 9 16 5.30 2.45 0 -9 -16 2.43 1.34 0 9 -17 4.12 1.97 0 9 17 -0.17 1.91 0 -9 -17 4.04 2.03 0 9 -18 10.40 2.70 0 9 18 3.88 2.35 0 -9 -18 6.10 2.19 0 9 -19 4.29 1.89 0 -9 -19 5.37 2.02 0 9 -20 4.46 2.16 0 9 20 -2.13 2.38 0 -9 -20 1.34 1.55 0 9 -21 5.64 2.60 0 9 21 2.45 1.79 0 -9 -21 1.03 1.42 0 9 -22 17.66 3.81 0 9 22 16.27 4.45 0 -9 -22 8.32 2.76 0 9 -23 8.09 2.77 0 -9 -23 7.52 2.73 0 9 23 7.75 3.35 0 -9 -24 2.92 2.13 0 9 24 2.11 2.50 0 10 0 76.17 4.46 0 -10 0 79.69 4.49 0 10 0 77.27 4.17 0 -10 0 83.20 4.26 0 10 -1 1061.56 20.39 0 10 1 1082.16 22.84 0 10 -1 1075.95 22.78 0 -10 -1 1068.79 22.75 0 -10 1 1059.49 22.85 0 10 1 1048.84 21.99 0 -10 -1 1070.28 22.09 0 -10 1 1102.79 22.13 0 10 -1 1035.44 22.01 0 10 -2 50.79 2.87 0 10 2 57.02 2.69 0 -10 -2 47.79 3.43 0 10 2 52.25 3.68 0 -10 2 45.34 3.47 0 -10 2 46.57 3.29 0 10 -2 46.49 3.27 0 -10 -2 48.22 3.23 0 10 2 49.13 3.27 0 -10 3 4.08 0.86 0 10 -3 4.79 1.39 0 10 3 5.71 0.88 0 -10 -3 4.01 0.84 0 10 3 3.30 0.98 0 -10 3 4.21 1.14 0 -10 -3 5.19 1.05 0 -10 3 4.60 1.20 0 10 -3 4.47 1.00 0 10 -4 60.33 3.55 0 -10 4 54.48 3.47 0 10 4 60.95 3.03 0 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0 -11 -3 1.70 0.80 0 -11 4 247.16 8.31 0 11 -4 261.53 8.20 0 11 4 262.59 7.38 0 11 4 263.38 9.56 0 -11 4 266.26 9.38 0 -11 -4 277.87 9.45 0 11 -5 90.42 4.65 0 -11 5 84.42 4.75 0 11 5 91.47 4.09 0 -11 -5 89.72 4.06 0 11 5 90.88 5.50 0 -11 5 89.20 5.40 0 -11 -5 99.01 5.60 0 11 -6 25.68 2.70 0 11 6 27.21 2.30 0 -11 -6 28.20 2.42 0 11 6 25.57 2.84 0 -11 -6 25.64 2.88 0 -11 6 28.71 3.16 0 11 -7 160.98 6.94 0 11 7 164.77 6.46 0 -11 -7 176.51 6.50 0 -11 7 162.94 5.61 0 11 7 165.00 8.15 0 -11 7 160.78 8.01 0 11 -8 2.71 1.81 0 -11 8 -0.07 1.61 0 11 8 -0.45 1.54 0 -11 -8 0.94 0.93 0 -11 8 1.47 0.68 0 11 -9 145.43 6.91 0 11 9 129.59 7.77 0 -11 9 131.71 4.67 0 -11 -9 130.44 6.09 0 11 -10 5.01 1.45 0 11 10 3.46 1.47 0 -11 -10 6.29 1.51 0 -11 10 6.72 0.90 0 11 -11 41.31 3.90 0 11 11 33.90 4.24 0 -11 -11 32.79 3.33 0 -11 11 35.01 1.89 0 11 -12 321.59 12.01 0 11 12 332.16 14.01 0 -11 -12 323.40 11.55 0 11 -13 -0.70 1.22 0 11 13 -1.86 1.79 0 -11 -13 -1.28 1.36 0 11 -14 45.84 4.69 0 11 14 46.96 5.68 0 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0 12 4 2.76 0.73 0 12 4 0.93 1.32 0 -12 4 1.86 0.81 0 -12 -4 1.07 0.88 0 -12 5 54.26 3.86 0 12 -5 67.27 4.11 0 12 5 60.28 3.31 0 12 5 56.19 4.52 0 -12 5 62.31 4.61 0 -12 -5 58.79 4.38 0 12 6 122.16 5.20 0 12 -6 117.15 5.79 0 -12 -6 125.84 5.30 0 12 6 117.56 6.57 0 -12 -6 125.54 6.57 0 -12 6 125.41 6.92 0 -12 7 16.71 2.53 0 12 -7 17.95 2.34 0 -12 -7 20.47 2.37 0 12 7 15.98 2.39 0 12 -8 393.37 12.25 0 -12 8 391.18 10.13 0 -12 -8 404.63 11.51 0 12 8 386.26 14.03 0 -12 8 393.70 14.08 0 -12 9 118.61 7.61 0 12 -9 132.25 6.67 0 12 9 122.44 7.57 0 -12 9 113.47 4.61 0 -12 -9 119.10 5.82 0 12 -10 31.67 3.32 0 12 10 23.92 3.43 0 -12 -10 26.81 2.85 0 -12 10 26.68 2.00 0 12 -11 40.36 4.02 0 12 11 33.70 4.35 0 -12 11 35.63 2.11 0 -12 -11 35.71 3.56 0 12 -12 64.91 5.17 0 12 12 65.37 6.10 0 -12 -12 56.11 4.51 0 -12 12 55.35 2.38 0 12 -13 26.78 3.55 0 12 13 30.62 4.37 0 -12 -13 23.85 3.18 0 12 -14 205.19 9.95 0 12 14 201.31 11.75 0 -12 -14 213.13 9.77 0 12 -15 13.64 3.01 0 -12 -15 7.85 2.32 0 12 -16 104.71 7.46 0 12 16 99.10 8.70 0 -12 -16 102.93 7.17 0 12 -17 10.33 2.98 0 12 17 7.53 2.83 0 -12 -17 13.78 3.20 0 12 -18 66.73 6.55 0 12 18 73.57 8.24 0 -12 -18 77.32 6.79 0 12 -19 1.86 2.42 0 12 19 1.93 2.31 0 -12 -19 3.67 2.14 0 12 -20 14.61 3.43 0 12 20 10.73 3.33 0 -12 -20 17.24 3.55 0 12 -21 1.99 1.84 0 -12 -21 3.55 2.24 0 12 -22 2.95 1.99 0 12 22 -0.43 2.04 0 -12 -22 0.99 1.68 0 12 -23 8.60 2.95 0 -12 -23 3.57 2.02 0 12 23 2.24 2.63 0 -12 -24 2.86 2.25 0 13 0 12.23 2.48 0 -13 0 7.80 1.97 0 13 -1 5.48 1.21 0 13 1 3.20 1.48 0 -13 1 4.36 1.43 0 -13 -1 3.39 1.25 0 13 -1 6.85 1.88 0 13 -2 8.87 1.43 0 13 2 3.92 1.35 0 -13 2 7.05 1.53 0 -13 -2 7.60 1.55 0 13 -3 298.18 9.01 0 13 3 283.01 7.98 0 13 3 281.90 10.53 0 -13 3 296.28 10.30 0 -13 -3 306.96 10.25 0 13 -4 30.34 3.02 0 13 4 27.99 2.22 0 13 4 28.36 3.29 0 -13 -4 29.25 3.14 0 -13 4 26.15 3.22 0 13 -5 658.63 16.19 0 13 5 651.06 14.73 0 13 5 644.34 18.16 0 -13 5 646.78 17.94 0 -13 -5 680.76 17.82 0 13 -6 284.37 9.62 0 13 6 275.32 8.55 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2.31 13 10 -2 3.28 2.03 13 10 -1 1.13 1.85 13 -10 -1 -0.22 1.58 13 10 0 4.81 2.84 13 -10 0 1.99 1.94 13 10 1 1.42 1.87 13 -10 1 -1.76 1.84 -13 10 -1 -2.81 3.01 13 10 2 -1.55 1.85 13 -10 2 1.65 2.06 -13 10 -2 -2.66 2.46 13 10 3 3.44 2.32 13 -10 3 1.47 1.82 -13 10 -3 5.75 3.02 13 10 4 4.30 2.70 13 -10 4 2.89 2.09 -13 10 -4 4.09 2.94 13 -10 5 4.27 2.43 13 10 5 3.17 2.04 -13 10 -5 3.97 3.04 13 -10 6 2.65 2.54 13 10 6 0.95 1.83 -13 10 -6 -1.68 2.17 13 11 -10 20.12 4.64 13 -11 -9 8.55 3.23 13 11 -9 10.77 3.84 13 -11 -8 10.46 3.58 13 11 -8 15.34 4.00 13 -11 -7 -3.30 2.26 13 11 -7 -0.95 1.74 13 -11 -6 11.81 3.67 13 11 -6 15.37 4.06 13 -11 -5 1.28 1.90 13 11 -5 -1.26 1.61 13 -11 -4 -0.90 1.82 13 11 -4 2.77 2.55 13 11 -3 1.55 1.95 13 -11 -3 2.67 2.14 13 11 -2 1.01 2.00 13 -11 -2 0.55 1.38 13 11 -1 -1.46 1.92 13 -11 -1 0.11 1.53 13 11 0 5.51 2.74 13 -11 0 7.17 2.97 13 -11 1 -0.07 1.52 13 11 1 2.01 2.05 13 11 2 2.11 2.11 13 -11 2 4.53 2.91 -13 11 -2 0.24 1.86 13 11 3 1.91 2.06 13 -11 3 2.04 2.08 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13 -2 18.26 4.10 13 13 -1 2.46 1.86 13 -13 -1 -1.72 2.26 13 13 0 11.57 3.76 13 -13 0 9.20 3.45 -13 13 0 5.95 2.72 13 -13 1 -0.56 1.90 13 13 1 5.41 3.30 -13 13 -1 1.11 2.21 13 13 2 11.48 3.94 13 -13 2 3.70 2.37 -13 13 -2 6.87 3.37 13 -13 3 1.15 1.92 13 13 3 4.91 2.90 13 -13 4 5.13 2.66 13 -13 5 3.73 2.73 13 -14 -6 3.98 2.74 13 -14 -5 11.28 3.91 13 14 -5 11.57 3.70 13 -14 -4 0.43 1.90 13 14 -4 6.27 3.14 13 -14 -3 -0.79 1.86 13 14 -3 4.55 2.51 13 14 -2 1.85 2.20 13 -14 -2 5.13 3.15 13 -14 -1 1.99 2.10 13 14 -1 0.33 1.81 13 -14 0 8.07 3.11 13 14 0 8.71 3.38 -13 14 0 1.09 2.24 13 -14 1 6.47 2.84 13 14 1 5.62 3.07 -13 14 -1 3.88 3.01 13 -14 2 8.62 3.58 13 -14 3 9.55 3.42 13 -14 4 9.04 3.39 13 -14 5 5.64 2.65 13 -15 -5 18.72 4.65 13 -15 -4 -1.88 2.08 13 -15 -3 13.68 4.21 13 -15 -2 4.72 3.42 13 -15 -1 27.88 5.49 13 -15 0 4.39 2.84 13 -15 1 7.76 3.15 13 -15 2 -0.05 1.85 13 -15 3 6.39 3.08 13 -15 4 2.86 2.36 13 -16 -4 6.42 3.15 13 -16 -3 25.56 5.57 13 -16 -2 2.41 1.68 13 -16 -1 2.42 2.69 13 -16 0 9.36 3.63 13 -16 1 0.03 1.59 13 -16 2 0.62 1.70 13 -16 3 -0.33 1.56 13 -16 4 -0.06 1.44 13 -17 -3 1.38 2.74 13 -17 -2 11.08 3.76 13 -17 -1 0.29 2.19 13 -17 0 -0.04 1.88 13 -17 1 0.00 1.73 13 -17 2 1.18 2.10 13 -17 3 1.02 1.41 13 -17 4 1.34 2.05 13 -18 -1 7.88 3.03 13 -18 0 5.82 3.28 13 -18 1 -3.15 2.35 13 -18 2 2.03 2.07 13 -18 3 -0.69 1.68 13 -19 1 -3.53 2.44 13 -19 2 -4.37 2.70 14 0 -7 0.23 2.27 14 0 -6 52.87 7.59 14 0 -5 0.33 1.89 14 0 -4 20.53 4.89 14 0 -3 4.45 2.79 14 0 -2 5.91 2.71 14 0 -1 1.25 1.64 -14 0 1 0.41 1.79 14 0 0 -2.11 2.42 -14 0 0 0.16 1.94 14 0 1 -4.36 2.62 -14 0 -1 0.48 2.24 14 0 2 2.51 2.82 -14 0 -2 1.41 1.91 14 0 3 -4.37 2.58 -14 0 -3 0.49 2.41 14 0 4 1.28 1.62 -14 0 -4 2.12 2.20 14 0 5 -3.63 2.85 -14 0 -5 -1.72 1.99 14 0 6 -2.77 2.20 14 -1 -6 3.05 3.32 14 1 -6 4.95 2.98 14 -1 -5 3.81 3.05 14 1 -5 12.28 3.81 14 -1 -4 12.45 4.04 14 1 -4 18.57 4.68 14 -1 -3 6.00 3.35 14 1 -3 3.03 2.66 14 -1 -2 3.15 2.29 14 1 -2 3.28 2.67 14 1 -1 0.59 2.00 -14 1 1 -1.53 2.29 -14 -1 1 -1.32 1.89 14 -1 0 7.46 3.19 14 1 0 2.60 2.21 -14 1 0 -0.23 1.98 -14 -1 0 2.68 2.15 14 -1 1 3.41 2.34 14 1 1 1.31 2.19 -14 1 -1 2.88 2.67 -14 -1 -1 6.27 3.00 14 -1 2 18.11 4.49 14 1 2 24.55 5.21 -14 1 -2 25.47 5.45 -14 -1 -2 23.60 5.10 14 1 3 0.59 2.40 14 -1 3 1.14 2.16 -14 1 -3 2.97 2.67 -14 -1 -3 0.85 2.07 14 1 4 8.00 3.09 14 -1 4 6.38 2.88 -14 1 -4 6.15 2.99 14 -1 5 3.65 2.27 14 1 5 5.65 2.76 -14 1 -5 2.00 2.72 14 -1 6 -3.52 2.30 14 1 6 0.98 1.73 -14 1 -6 0.12 1.66 14 -2 -6 52.34 7.52 14 2 -6 55.42 7.67 14 -2 -5 14.96 4.48 14 2 -5 14.15 4.33 14 -2 -4 26.16 5.35 14 2 -4 32.47 6.03 14 -2 -3 3.17 2.27 14 2 -3 3.35 2.79 14 -2 -2 4.69 2.49 14 2 -2 5.84 3.24 14 -2 -1 2.74 2.25 14 2 -1 -0.34 1.78 -14 -2 1 2.27 1.57 14 -2 0 0.53 1.76 14 2 0 -0.66 1.84 -14 2 0 -0.07 1.90 -14 -2 0 0.57 1.64 14 -2 1 4.70 2.80 14 2 1 2.05 2.17 -14 2 -1 3.46 2.80 14 2 2 1.74 2.51 14 -2 2 -0.75 1.93 -14 2 -2 0.75 1.99 14 2 3 2.14 2.39 14 -2 3 1.18 2.22 -14 2 -3 7.13 3.71 14 2 4 -0.22 1.68 14 -2 4 0.00 1.78 14 -2 5 0.00 1.78 14 2 5 0.09 2.19 -14 2 -5 -1.23 1.85 14 2 6 4.26 2.48 14 -2 6 1.26 1.96 -14 2 -6 0.73 1.94 14 -3 -6 -0.11 2.43 14 3 -6 6.83 3.45 14 -3 -5 3.74 2.85 14 3 -5 7.46 3.52 14 -3 -4 3.92 2.65 14 3 -4 1.66 2.49 14 -3 -3 1.91 2.29 14 3 -3 -0.28 2.24 14 -3 -2 2.55 2.21 14 3 -2 -2.55 2.37 14 -3 -1 1.40 2.15 14 3 -1 1.48 1.90 14 -3 0 8.17 3.20 14 3 0 5.00 2.66 -14 3 0 3.24 2.33 14 3 1 13.43 3.83 14 -3 1 12.49 3.78 -14 3 -1 11.77 3.91 14 3 2 0.31 1.92 14 -3 2 4.84 2.86 -14 3 -2 1.52 2.22 14 3 3 28.45 5.50 14 -3 3 27.78 5.75 14 3 4 3.02 2.57 14 -3 4 6.86 3.23 -14 3 -4 0.14 1.79 14 -3 5 27.38 5.43 14 3 5 25.18 5.30 -14 3 -5 35.20 6.40 14 -3 6 2.01 2.30 14 3 6 2.21 2.31 -14 3 -6 -1.22 1.69 -14 3 -7 2.09 2.46 14 -4 -6 0.63 2.10 14 4 -5 20.35 4.71 14 -4 -5 25.19 5.35 14 -4 -4 1.51 1.79 14 4 -4 0.66 1.86 14 -4 -3 13.24 3.93 14 4 -3 10.80 3.52 14 -4 -2 4.16 2.69 14 4 -2 2.38 1.81 14 -4 -1 15.32 4.24 14 4 -1 8.57 3.26 14 4 0 3.39 2.70 14 -4 0 4.40 2.77 -14 4 0 1.51 2.33 14 4 1 0.65 1.77 14 -4 1 4.05 2.79 -14 4 -1 1.70 2.45 14 -4 2 4.24 2.71 14 4 2 0.38 1.76 -14 4 -2 1.68 1.74 14 -4 3 5.94 3.09 14 4 3 3.48 2.60 -14 4 -3 4.74 3.04 14 -4 4 -4.27 2.56 14 4 4 -0.37 1.67 14 4 5 1.23 2.45 14 -4 5 3.71 2.57 -14 4 -5 9.30 3.91 14 4 6 -0.53 1.63 14 -4 6 1.48 1.86 -14 4 -6 -4.37 2.55 14 5 -5 0.21 1.90 14 -5 -5 0.17 2.02 14 5 -4 0.35 1.86 14 -5 -4 -0.11 2.10 14 5 -3 1.87 2.14 14 -5 -3 0.72 1.82 14 -5 -2 3.85 2.20 14 5 -2 0.82 1.75 14 -5 -1 0.22 1.51 14 5 -1 -0.23 1.84 14 -5 0 7.32 3.22 14 5 0 4.59 2.62 -14 5 0 6.54 3.06 14 -5 1 0.54 1.65 14 5 1 -0.26 1.83 -14 5 -1 -2.41 2.39 14 -5 2 2.63 2.24 14 5 2 2.02 2.47 -14 5 -2 1.94 2.40 14 -5 3 1.52 1.76 14 5 3 0.44 1.71 -14 5 -3 1.49 2.31 14 5 4 14.73 4.27 14 -5 4 14.53 4.27 -14 5 -4 18.20 4.97 14 5 5 3.34 2.26 14 -5 5 0.01 1.84 -14 5 -5 4.64 3.08 14 5 6 2.35 2.19 14 -6 -5 2.55 1.78 14 -6 -4 3.29 2.54 14 6 -3 -0.33 1.67 14 -6 -3 -0.29 2.06 14 6 -2 0.18 1.97 14 -6 -2 0.12 1.76 14 -6 -1 1.14 1.80 14 6 -1 -1.35 1.84 14 -6 0 2.00 1.95 14 6 0 7.83 3.00 -14 6 0 5.02 2.74 14 -6 1 0.63 2.05 14 6 1 3.10 2.30 -14 6 -1 -0.86 2.24 14 -6 2 6.91 3.44 14 6 2 2.01 2.28 -14 6 -2 3.06 2.72 14 6 3 1.02 2.02 14 -6 3 -1.56 2.09 -14 6 -3 -0.43 1.94 14 6 4 2.93 2.77 14 -6 4 1.49 2.44 -14 6 -4 0.43 1.71 14 -6 5 0.92 1.93 -14 6 -5 1.89 2.27 14 -7 -4 2.45 1.94 14 -7 -3 9.55 3.45 14 -7 -2 1.99 1.97 14 -7 -1 -0.37 1.86 14 -7 0 0.86 1.84 -14 7 0 0.96 1.86 14 -7 1 2.31 1.79 -14 7 -1 -1.36 2.37 14 -7 2 2.80 2.48 -14 7 -2 4.89 3.12 14 -7 3 -1.13 1.53 -14 7 -3 -2.04 2.19 14 -7 4 12.78 3.98 -14 7 -4 3.91 3.04 14 -7 5 2.95 2.25 14 -8 -3 -2.71 2.18 14 -8 -2 5.50 2.73 14 -8 -1 1.01 1.72 14 -8 0 -4.39 2.64 -14 8 0 -0.78 2.33 14 -8 1 1.83 2.10 -14 8 -1 -1.56 2.29 14 -8 2 2.95 2.38 -14 8 -2 4.31 3.23 14 -8 3 2.04 2.47 -14 8 -3 2.44 2.65 14 -8 4 5.22 2.83 14 -8 5 1.10 1.97 14 -9 -3 4.89 2.93 14 -9 -2 1.20 2.02 14 -9 -1 1.71 2.20 14 -9 0 0.43 1.79 -14 9 0 0.20 1.93 14 -9 1 11.97 3.90 -14 9 -1 12.04 4.30 14 -9 2 5.48 2.87 14 -9 3 11.30 3.81 14 -9 4 3.88 2.51 14 -10 -2 6.09 2.94 14 -10 -1 1.41 2.28 14 -10 0 5.88 3.05 14 -10 1 0.89 2.41 14 -10 2 2.96 2.65 14 -10 3 1.82 2.30 14 -10 4 1.50 1.84 14 -11 0 4.61 3.05 14 -11 1 14.71 4.41 14 -11 2 7.95 3.46 14 -11 3 1.51 2.01 14 -11 4 8.39 3.32 14 -12 1 2.74 2.03 14 -12 2 10.12 3.92 14 -12 3 1.50 2.12 14 -13 3 10.21 3.75 -15 0 2 3.34 2.31 -15 1 2 -3.11 2.59 -15 1 1 2.35 2.22 -15 1 0 4.32 2.37 -15 2 1 -0.79 1.90 -15 2 0 -2.00 2.26 -15 3 1 -1.90 2.29 -15 3 0 -1.06 2.23 -15 3 -1 0.49 1.71 -15 4 1 1.95 1.88 -15 4 0 1.62 2.09 0 0 0 0.00 0.00 ; _shelx_hkl_checksum 22478 _shelx_res_file ; TITL fe in P2(1)/n CELL 0.71073 11.2862 29.3083 19.6024 90.000 98.393 90.000 ZERR 4.00 0.0003 0.0008 0.0006 0.000 0.002 0.000 LATT 1 SYMM 0.5-X, 0.5+Y, 0.5-Z SFAC C H Cl Fe N O UNIT 176 180 16 20 168 28 EQIV $1 -0.5+X,0.5-Y,0.5+Z EQIV $2 -1+X,+Y,+Z EQIV $3 0.5-X,0.5+Y,0.5-Z DFIX 1.45 0.01 N41 C37 N41 C39 N41 C41 DFIX 1.54 0.01 C37 C38 C39 C40 C41 C42 DFIX 2.3 0.01 C37 C41 C37 C39 C39 C41 DFIX 1.45 0.01 N41' C37' N41' C39' N41' C41' DFIX 1.54 0.01 C37' C38' C39' C40' DFIX 2.3 0.01 C37' C41' C37' C39' C39' C41' DFIX 2.5 0.01 N41' C38' ISOR 0.05 0.01 C40 C41 C37 C42 C39 C41 ISOR 0.01 0.02 C37' C39' C41' EADP C37 C37' EADP C38 C38' EADP C39 C39' EADP N41 N41' EADP C40 C40' EADP C41 C41' eadp n28 n27 eadp c43 n42 L.S. 40 PLAN 2 HTAB N25 O3 HTAB N25 Cl1_$1 HTAB N35 O6 HTAB N35 N5_$2 HTAB N40 O5 HTAB N40 N27_$3 HTAB N30 O1 BOND $h MORE -1 HTAB CONF fmap 2 ACTA SHEL 999 0.8 OMIT -3 50.02 REM REM REM WGHT 0.096700 14.129202 FVAR 0.14090 0.48382 FE1 4 0.419399 0.309194 0.202807 11.00000 0.03775 0.03624 = 0.03843 -0.00697 0.00837 -0.00075 CL1 3 1.009536 0.280725 0.115934 11.00000 0.05313 0.10214 = 0.13322 -0.03786 0.03707 0.00371 O1 6 0.498302 0.285389 0.131123 11.00000 0.04582 0.05098 = 0.04234 -0.01592 0.01169 -0.00272 N1 5 0.540124 0.367625 0.204452 11.00000 0.03626 0.03775 = 0.03691 -0.00787 0.00729 -0.00126 C1 1 0.518237 0.410228 0.232718 11.00000 0.03109 0.03478 = 0.03337 -0.00159 0.00669 0.00357 FE2 4 0.312298 0.284372 0.346614 11.00000 0.04521 0.02963 = 0.04214 -0.00097 0.01062 -0.00168 CL2 3 -0.018753 0.111726 0.510017 11.00000 0.11434 0.06309 = 0.11725 0.02112 0.04205 -0.02725 O2 6 0.333175 0.327351 0.275977 11.00000 0.03986 0.02951 = 0.03719 -0.00304 0.00981 0.00111 N2 5 0.417722 0.418937 0.256949 11.00000 0.03537 0.02551 = 0.03445 -0.00368 0.00415 -0.00361 C2 1 0.644968 0.362494 0.184768 11.00000 0.03920 0.04422 = 0.03935 -0.00587 0.00904 -0.00157 AFIX 43 H2 2 0.697984 0.386849 0.192828 11.00000 -1.20000 AFIX 0 FE3 4 0.261086 0.384979 0.273487 11.00000 0.03335 0.02983 = 0.03125 -0.00245 0.00559 -0.00060 CL3 3 0.343630 0.631573 0.624151 11.00000 0.11419 0.05777 = 0.05352 -0.02054 0.01113 -0.00094 O3 6 0.316384 0.238821 0.415236 11.00000 0.05552 0.04051 = 0.06572 0.01482 0.01502 -0.00269 N3 5 0.427988 0.462735 0.279269 11.00000 0.03331 0.03230 = 0.03441 -0.00165 0.00311 -0.00475 C3 1 0.686258 0.323387 0.152226 11.00000 0.04017 0.05435 = 0.04196 -0.01195 0.00947 0.00404 FE4 4 0.274812 0.493551 0.318012 11.00000 0.03586 0.03056 = 0.03190 -0.00248 0.00410 0.00056 CL4 3 -0.347028 0.518785 -0.090799 11.00000 0.07838 0.10127 = 0.04357 0.01349 -0.00202 0.02711 O4 6 0.190044 0.443389 0.272794 11.00000 0.03219 0.03238 = 0.03267 -0.00128 0.00250 0.00092 N4 5 0.531477 0.478735 0.268517 11.00000 0.03769 0.03792 = 0.05919 -0.00521 0.01049 -0.00287 C4 1 0.611906 0.286503 0.126191 11.00000 0.04353 0.05016 = 0.03419 -0.00333 0.00992 0.00249 FE5 4 0.029911 0.453250 0.226441 11.00000 0.03388 0.03934 = 0.02963 -0.00138 0.00305 0.00187 O5 6 0.362123 0.545431 0.356883 11.00000 0.05348 0.03679 = 0.03514 -0.00262 0.00837 -0.00499 N5 5 0.590161 0.446705 0.238571 11.00000 0.03597 0.04172 = 0.05811 -0.00401 0.01302 -0.00526 C5 1 0.662009 0.250375 0.092517 11.00000 0.05341 0.05527 = 0.04795 -0.01309 0.01352 -0.00448 AFIX 43 H5 2 0.612712 0.227270 0.071971 11.00000 -1.20000 AFIX 0 O6 6 -0.132641 0.463447 0.186859 11.00000 0.03309 0.06806 = 0.03454 0.00345 0.00344 0.00400 N6 5 0.118427 0.288872 0.351131 11.00000 0.04341 0.03530 = 0.04337 0.00019 0.01017 -0.00734 C6 1 0.783195 0.248895 0.089691 11.00000 0.06864 0.05790 = 0.05423 -0.01101 0.01871 0.00888 AFIX 43 H6 2 0.815943 0.224269 0.069051 11.00000 -1.20000 AFIX 0 N7 5 0.092138 0.359668 0.290682 11.00000 0.03469 0.03491 = 0.03598 -0.00142 0.00756 0.00089 C7 1 0.855678 0.284025 0.117549 11.00000 0.04931 0.06840 = 0.06770 -0.01603 0.02184 0.00371 O7 6 -0.373132 0.568676 0.361401 11.00000 0.09056 0.11335 = 0.08931 -0.01984 0.01573 0.00472 AFIX 3 H7A 2 -0.414162 0.578017 0.326961 11.00000 -1.50000 H7B 2 -0.313152 0.584806 0.372211 11.00000 -1.50000 AFIX 0 N8 5 -0.001615 0.387503 0.270223 11.00000 0.03380 0.04630 = 0.03516 0.00130 0.00665 -0.00001 C8 1 0.808175 0.321084 0.145864 11.00000 0.05303 0.05700 = 0.05774 -0.01366 0.01831 -0.00077 AFIX 43 H8 2 0.857912 0.345397 0.161312 11.00000 -1.20000 AFIX 0 N9 5 -0.099942 0.369068 0.287619 11.00000 0.03629 0.06235 = 0.06154 0.00769 0.00841 -0.00266 C9 1 0.046979 0.324716 0.320813 11.00000 0.04004 0.03992 = 0.04353 -0.00380 0.00944 -0.00794 N10 5 -0.070785 0.329376 0.319423 11.00000 0.03782 0.05928 = 0.07525 0.01853 0.01218 -0.00288 C10 1 0.062428 0.258757 0.383191 11.00000 0.05107 0.03902 = 0.05512 -0.00181 0.01285 -0.00222 AFIX 43 H10 2 -0.018893 0.263686 0.383501 11.00000 -1.20000 AFIX 0 N11 5 0.326014 0.462642 0.421052 11.00000 0.04156 0.02790 = 0.03742 -0.00358 0.00426 -0.00194 C11 1 0.113179 0.218510 0.418323 11.00000 0.06738 0.03750 = 0.04772 0.00104 0.01852 -0.01052 N12 5 0.316957 0.385770 0.382338 11.00000 0.04057 0.02721 = 0.03086 0.00101 0.00726 0.00045 C12 1 0.236327 0.209860 0.429742 11.00000 0.06433 0.03649 = 0.04981 -0.00076 0.01686 -0.00130 N13 5 0.326242 0.344350 0.413027 11.00000 0.04563 0.02918 = 0.03864 0.00005 0.00279 0.00187 C13 1 0.276139 0.168081 0.460715 11.00000 0.07643 0.04239 = 0.09021 0.01133 0.01698 -0.00235 AFIX 43 H13 2 0.357142 0.160762 0.465998 11.00000 -1.20000 AFIX 0 N14 5 0.339671 0.349799 0.479668 11.00000 0.07107 0.03417 = 0.03499 0.00021 0.00738 -0.00119 C14 1 0.196666 0.138103 0.483148 11.00000 0.08756 0.04028 = 0.08546 0.01217 0.01983 0.00222 AFIX 43 H14 2 0.223575 0.110626 0.503526 11.00000 -1.20000 AFIX 0 N15 5 0.340434 0.394544 0.494248 11.00000 0.07114 0.03532 = 0.03494 -0.00085 0.00154 0.00361 C15 1 0.076479 0.149079 0.475209 11.00000 0.09180 0.03960 = 0.07452 0.00048 0.02134 -0.01943 N16 5 0.048718 0.423032 0.125156 11.00000 0.03809 0.04233 = 0.03403 -0.00050 0.00299 -0.00150 C16 1 0.032936 0.188478 0.442653 11.00000 0.07614 0.04517 = 0.06962 0.00418 0.01983 -0.00866 AFIX 43 H16 2 -0.048553 0.195003 0.436943 11.00000 -1.20000 AFIX 0 N17 5 0.215466 0.376044 0.165387 11.00000 0.03624 0.03691 = 0.03658 -0.00871 0.00819 -0.00249 C17 1 0.326345 0.415437 0.433143 11.00000 0.03814 0.03619 = 0.03015 -0.00388 0.00404 0.00151 N18 5 0.282127 0.345338 0.136459 11.00000 0.04053 0.04623 = 0.03482 -0.00920 0.01058 0.00077 C18 1 0.340822 0.488407 0.475996 11.00000 0.05783 0.03857 = 0.03467 -0.00284 0.00437 -0.00327 AFIX 43 H18 2 0.345486 0.473689 0.518336 11.00000 -1.20000 AFIX 0 N19 5 0.242503 0.343043 0.070149 11.00000 0.05966 0.07230 = 0.03654 -0.01204 0.00452 0.01527 C19 1 0.350443 0.536480 0.477346 11.00000 0.04820 0.03570 = 0.03766 -0.00726 0.00353 -0.00419 N20 5 0.151070 0.371512 0.055144 11.00000 0.06367 0.07796 = 0.03393 -0.00997 -0.00058 0.02122 C20 1 0.361833 0.563852 0.418729 11.00000 0.03912 0.03498 = 0.04246 -0.00459 0.00327 0.00104 N21 5 0.538347 0.277734 0.286159 11.00000 0.04724 0.03674 = 0.05149 -0.00223 0.00903 0.00163 C21 1 0.374499 0.610700 0.427322 11.00000 0.06450 0.03346 = 0.04877 -0.00157 0.00123 -0.00052 AFIX 43 H21 2 0.386167 0.628659 0.389758 11.00000 -1.20000 AFIX 0 N22 5 0.644280 0.260118 0.288041 11.00000 0.06043 0.06103 = 0.06535 0.01168 0.01889 0.02247 C22 1 0.370223 0.631181 0.489933 11.00000 0.06798 0.03451 = 0.06071 -0.01075 0.00584 -0.00400 AFIX 43 H22 2 0.377749 0.662677 0.494422 11.00000 -1.20000 AFIX 0 N23 5 0.676624 0.240115 0.350340 11.00000 0.06442 0.08882 = 0.07303 0.02578 0.02372 0.03096 C23 1 0.354437 0.604267 0.546998 11.00000 0.06103 0.04801 = 0.04890 -0.01455 0.00655 0.00034 N24 5 0.496151 0.270666 0.346607 11.00000 0.04621 0.03724 = 0.04409 0.00113 0.00799 0.00450 C24 1 0.348152 0.558044 0.542056 11.00000 0.06278 0.04560 = 0.03747 -0.00533 0.00655 -0.00047 AFIX 43 H24 2 0.342355 0.540544 0.581007 11.00000 -1.20000 AFIX 0 N25 5 0.583047 0.234374 0.450234 11.00000 0.07593 0.10841 = 0.06672 0.03444 0.01740 0.03110 AFIX 93 H25A 2 0.643523 0.220309 0.472521 11.00000 -1.20000 H25B 2 0.521323 0.240053 0.469879 11.00000 -1.20000 AFIX 0 C25 1 0.137236 0.391843 0.114460 11.00000 0.04219 0.04622 = 0.03420 -0.00344 0.00270 0.00228 N26 5 0.270705 0.239359 0.260615 11.00000 0.04980 0.03514 = 0.05213 -0.00701 0.01153 -0.00862 C26 1 -0.017109 0.437643 0.069266 11.00000 0.04675 0.05006 = 0.03180 -0.00467 0.00392 0.00176 AFIX 43 H26 2 0.006824 0.429426 0.027527 11.00000 -1.20000 AFIX 0 C27 1 -0.122431 0.465047 0.065879 11.00000 0.04008 0.04479 = 0.03520 -0.00041 -0.00329 -0.00252 N27 5 0.216337 0.200471 0.254322 11.00000 0.09857 0.05212 = 0.07431 -0.02247 0.02914 -0.02839 C28 1 -0.180338 0.475046 0.124230 11.00000 0.03466 0.04853 = 0.03860 0.00343 0.00251 -0.00719 N28 5 0.221537 0.184694 0.190688 11.00000 0.09857 0.05212 = 0.07431 -0.02247 0.02914 -0.02839 N29 5 0.314455 0.250040 0.201903 11.00000 0.05091 0.03729 = 0.05268 -0.01093 0.01162 -0.00348 C29 1 -0.291897 0.495431 0.111944 11.00000 0.04243 0.05731 = 0.04657 0.00776 0.00961 0.00487 AFIX 43 H29 2 -0.333827 0.500314 0.148758 11.00000 -1.20000 AFIX 0 N30 5 0.307354 0.213177 0.094784 11.00000 0.10975 0.08491 = 0.06996 -0.03543 0.03193 -0.03863 AFIX 93 H30A 2 0.345872 0.234960 0.078458 11.00000 -1.20000 H30B 2 0.284577 0.189888 0.069546 11.00000 -1.20000 AFIX 0 C30 1 -0.342389 0.508617 0.047359 11.00000 0.03984 0.05650 = 0.05383 0.00159 -0.00340 0.00773 AFIX 43 H30 2 -0.417124 0.522625 0.040803 11.00000 -1.20000 AFIX 0 N31 5 0.106055 0.508096 0.352291 11.00000 0.03715 0.04934 = 0.03809 -0.01168 0.00254 0.00249 C31 1 -0.281821 0.501063 -0.008738 11.00000 0.04765 0.05311 = 0.04206 0.00486 -0.00350 0.00437 N32 5 0.075856 0.535191 0.398980 11.00000 0.04475 0.07987 = 0.06301 -0.03519 0.00840 0.00119 C32 1 -0.176079 0.479284 -0.000025 11.00000 0.05184 0.06009 = 0.03610 0.00019 0.00555 0.00217 AFIX 43 H32 2 -0.137746 0.473523 -0.038034 11.00000 -1.20000 AFIX 0 N33 5 -0.043786 0.536269 0.394919 11.00000 0.04743 0.08889 = 0.06953 -0.03876 0.01134 0.00862 C33 1 0.584990 0.247429 0.384957 11.00000 0.06056 0.05706 = 0.05846 0.00784 0.00781 0.01400 N34 5 0.004543 0.490264 0.314564 11.00000 0.03442 0.04536 = 0.03504 -0.00131 0.00639 0.00530 C34 1 0.282447 0.215560 0.160558 11.00000 0.06777 0.05981 = 0.06400 -0.02411 0.02272 -0.01429 N35 5 -0.201079 0.500206 0.321669 11.00000 0.03747 0.09655 = 0.07922 -0.03174 0.01466 0.00158 AFIX 93 H35A 2 -0.222537 0.482055 0.287633 11.00000 -1.20000 H35B 2 -0.254372 0.513138 0.342279 11.00000 -1.20000 AFIX 0 C35 1 0.225189 0.570959 0.199185 11.00000 0.05891 0.02984 = 0.04759 0.00193 0.01279 -0.00030 N36 5 0.104754 0.514586 0.192263 11.00000 0.04446 0.04168 = 0.03404 0.00067 0.00522 0.00464 C36 1 -0.084992 0.508309 0.342518 11.00000 0.04234 0.05731 = 0.05036 -0.00794 0.01288 0.00365 N37 5 0.061882 0.544313 0.146625 11.00000 0.06119 0.05202 = 0.04323 0.00839 -0.00037 0.00514 PART 2 C37 1 0.194247 0.393978 -0.180757 21.00000 0.17245 0.11638 = 0.13819 -0.02768 0.03645 -0.01102 AFIX 23 H37A 2 0.123082 0.409056 -0.203983 21.00000 -1.20000 H37B 2 0.259698 0.415701 -0.177256 21.00000 -1.20000 AFIX 0 PART 1 C37' 1 0.232982 0.384597 -0.176962 -21.00000 0.17245 0.11638 = 0.13819 -0.02768 0.03645 -0.01102 AFIX 23 H37C 2 0.202419 0.412000 -0.201137 -21.00000 -1.20000 H37D 2 0.319739 0.386137 -0.170880 -21.00000 -1.20000 AFIX 0 PART 0 N38 5 0.134462 0.580633 0.149127 11.00000 0.08152 0.05065 = 0.05538 0.01654 -0.00361 -0.00539 PART 2 C38 1 0.172952 0.380488 -0.107494 21.00000 0.19203 0.12469 = 0.08739 -0.01148 -0.00620 0.00864 AFIX 137 H38A 2 0.102333 0.361922 -0.110281 21.00000 -1.50000 H38B 2 0.162588 0.407521 -0.081348 21.00000 -1.50000 H38C 2 0.240676 0.363621 -0.085238 21.00000 -1.50000 AFIX 0 PART 1 C38' 1 0.192055 0.384166 -0.105250 -21.00000 0.19203 0.12469 = 0.08739 -0.01148 -0.00620 0.00864 AFIX 137 H38D 2 0.109466 0.375199 -0.109806 -21.00000 -1.50000 H38E 2 0.201173 0.414131 -0.085397 -21.00000 -1.50000 H38F 2 0.240053 0.362902 -0.075915 -21.00000 -1.50000 AFIX 0 PART 0 N39 5 0.209426 0.530552 0.228219 11.00000 0.04349 0.03418 = 0.03722 -0.00024 0.00709 0.00097 PART 2 C39 1 0.348288 0.356896 -0.224382 21.00000 0.11528 0.13240 = 0.10376 -0.00402 0.01713 -0.02131 AFIX 23 H39A 2 0.390061 0.366516 -0.179937 21.00000 -1.20000 H39B 2 0.364928 0.379027 -0.258536 21.00000 -1.20000 AFIX 0 PART 1 C39' 1 0.262218 0.343742 -0.275220 -21.00000 0.11528 0.13240 = 0.10376 -0.00402 0.01713 -0.02131 AFIX 23 H39C 2 0.269416 0.374462 -0.292565 -21.00000 -1.20000 H39D 2 0.216259 0.326167 -0.311837 -21.00000 -1.20000 AFIX 0 PART 0 N40 5 0.321712 0.597892 0.217959 11.00000 0.07798 0.04843 = 0.06482 0.01318 0.00325 -0.01512 AFIX 93 H40A 2 0.377176 0.589289 0.250211 11.00000 -1.20000 H40B 2 0.327640 0.623625 0.197647 11.00000 -1.20000 AFIX 0 PART 2 C40 1 0.395677 0.309718 -0.242703 21.00000 0.12562 0.14338 = 0.13694 0.00070 0.02511 0.00310 AFIX 137 H40C 2 0.386367 0.306413 -0.291919 21.00000 -1.50000 H40D 2 0.351233 0.286214 -0.223576 21.00000 -1.50000 H40E 2 0.478902 0.307186 -0.224006 21.00000 -1.50000 AFIX 0 PART 1 C40' 1 0.388803 0.322970 -0.260560 -21.00000 0.12562 0.14338 = 0.13694 0.00070 0.02511 0.00310 AFIX 137 H40F 2 0.436471 0.334280 -0.293639 -21.00000 -1.50000 H40G 2 0.383439 0.290337 -0.263937 -21.00000 -1.50000 H40H 2 0.425362 0.331351 -0.214970 -21.00000 -1.50000 AFIX 0 PART 2 N41 5 0.221918 0.355987 -0.221862 21.00000 0.12141 0.08685 = 0.10065 -0.00895 0.01484 -0.00501 AFIX 3 H41 2 0.198798 0.328177 -0.200823 21.00000 -1.20000 AFIX 0 C41 1 0.158786 0.362111 -0.290195 21.00000 0.13919 0.16096 = 0.13574 0.01241 0.00015 0.01191 AFIX 23 H41A 2 0.193084 0.342431 -0.321971 21.00000 -1.20000 H41B 2 0.167144 0.393459 -0.304636 21.00000 -1.20000 AFIX 0 PART 1 N41' 5 0.195113 0.345973 -0.218957 -21.00000 0.12141 0.08685 = 0.10065 -0.00895 0.01484 -0.00501 AFIX 3 H41' 2 0.206892 0.318933 -0.191367 -21.00000 -1.20000 AFIX 0 C41' 1 0.070438 0.351183 -0.245967 -21.00000 0.13919 0.16096 = 0.13574 0.01241 0.00015 0.01191 AFIX 23 H41C 2 0.047299 0.321959 -0.267035 -21.00000 -1.20000 H41D 2 0.030511 0.353057 -0.205463 -21.00000 -1.20000 AFIX 0 PART 0 N42 5 -0.014736 0.337801 0.505446 11.00000 0.20418 0.12297 = 0.12332 0.05192 0.03906 0.03398 PART 2 C42 1 0.024092 0.350592 -0.292269 21.00000 0.11732 0.12511 = 0.13655 -0.00020 0.00216 -0.00649 AFIX 137 H42A 2 -0.022439 0.378023 -0.299916 21.00000 -1.50000 H42B 2 0.011744 0.337204 -0.249168 21.00000 -1.50000 H42C 2 -0.000348 0.329424 -0.329007 21.00000 -1.50000 AFIX 0 PART 1 C42' 1 0.011188 0.383705 -0.291967 -21.00000 0.17041 0.11736 = 0.13245 0.04487 0.03632 0.06010 AFIX 137 H42D 2 0.040142 0.413675 -0.278645 -21.00000 -1.50000 H42E 2 -0.073422 0.382264 -0.290640 -21.00000 -1.50000 H42F 2 0.026551 0.377293 -0.337898 -21.00000 -1.50000 AFIX 0 PART 0 C43 1 -0.013738 0.372694 0.483204 11.00000 0.20418 0.12297 = 0.12332 0.05192 0.03906 0.03398 C44 1 -0.016969 0.414710 0.451558 11.00000 0.13310 0.09588 = 0.07851 -0.00357 0.02157 0.00913 AFIX 137 H44A 2 -0.001811 0.411086 0.404930 11.00000 -1.50000 H44B 2 0.043139 0.434129 0.476186 11.00000 -1.50000 H44C 2 -0.094487 0.428208 0.451492 11.00000 -1.50000 AFIX 0 HKLF 4 REM fe in P2(1)/n REM R1 = 0.0536 for 8624 Fo > 4sig(Fo) and 0.0765 for all 11282 data REM 942 parameters refined using 66 restraints END WGHT 0.0574 15.5104 REM Instructions for potential hydrogen bonds EQIV $4 x+1/2, -y+1/2, z-1/2 HTAB C5 N42_$4 EQIV $5 x+1, y, z HTAB C8 N9_$5 EQIV $6 -x, -y+1, -z+1 HTAB C18 O7_$6 HTAB C21 N28_$3 HTAB N25 Cl1_$1 HTAB N25 O3 HTAB C29 N5_$2 HTAB N30 O1 EQIV $7 -x-1/2, y+1/2, -z+1/2 HTAB C30 Cl2_$7 EQIV $8 -x, -y+1, -z HTAB C32 N37_$8 HTAB C32 N38_$8 HTAB N35 N5_$2 HTAB N35 O6 HTAB N35 O7 HTAB C39 O7_$8 HTAB C39' O7_$8 HTAB N40 O5 HTAB N40 N27_$3 EQIV $9 x-1/2, -y+1/2, z-1/2 HTAB N41 N22_$9 HTAB N41 N23_$9 HTAB N41' N22_$9 HTAB N41' N23_$9 HTAB C44 N9 HTAB C44 N33_$6 REM Highest difference peak 0.873, deepest hole -0.609, 1-sigma level 0.086 Q1 1 -0.0649 0.1026 0.4578 11.00000 0.05 0.74 Q2 1 0.4451 0.6246 0.6379 11.00000 0.05 0.66 ; _shelx_res_checksum 72514 _shelxl_version_number 2.014 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy _atom_site_disorder_assembly _atom_site_disorder_group Fe Fe1 0.41940(6) 0.30919(2) 0.20281(4) 0.03719(19) Uani d 1 . . Cl Cl1 1.00954(16) 0.28073(8) 0.11593(13) 0.0938(7) Uani d 1 . . O O1 0.4983(3) 0.28539(13) 0.13112(18) 0.0459(9) Uani d 1 . . N N1 0.5401(4) 0.36763(14) 0.2045(2) 0.0368(9) Uani d 1 . . C C1 0.5182(4) 0.41023(16) 0.2327(2) 0.0329(10) Uani d 1 . . Fe Fe2 0.31230(7) 0.28437(2) 0.34661(4) 0.0386(2) Uani d 1 . . Cl Cl2 -0.0188(2) 0.11173(7) 0.51002(13) 0.0957(7) Uani d 1 . . O O2 0.3332(3) 0.32735(11) 0.27598(16) 0.0351(7) Uani d 1 . . N N2 0.4177(3) 0.41894(13) 0.2569(2) 0.0319(8) Uani d 1 . . C C2 0.6450(5) 0.36249(18) 0.1848(3) 0.0406(12) Uani d 1 . . H H2 0.6980 0.3868 0.1928 0.049 Uiso calc 1 . . Fe Fe3 0.26109(6) 0.38498(2) 0.27349(3) 0.03139(18) Uani d 1 . . Cl Cl3 0.34363(19) 0.63157(6) 0.62415(9) 0.0753(5) Uani d 1 . . O O3 0.3164(3) 0.23882(13) 0.4152(2) 0.0533(10) Uani d 1 . . N N3 0.4280(3) 0.46274(13) 0.2793(2) 0.0335(9) Uani d 1 . . C C3 0.6863(5) 0.3234(2) 0.1522(3) 0.0451(13) Uani d 1 . . Fe Fe4 0.27481(6) 0.49355(2) 0.31801(3) 0.03286(18) Uani d 1 . . Cl Cl4 -0.34703(17) 0.51879(7) -0.09080(8) 0.0755(5) Uani d 1 . . O O4 0.1900(3) 0.44339(11) 0.27279(16) 0.0326(7) Uani d 1 . . N N4 0.5315(4) 0.47874(15) 0.2685(2) 0.0446(11) Uani d 1 . . C C4 0.6119(5) 0.28650(19) 0.1262(3) 0.0422(12) Uani d 1 . . Fe Fe5 0.02991(6) 0.45325(2) 0.22644(3) 0.03444(19) Uani d 1 . . O O5 0.3621(3) 0.54543(12) 0.35688(17) 0.0416(8) Uani d 1 . . N N5 0.5902(4) 0.44670(15) 0.2386(2) 0.0447(10) Uani d 1 . . C C5 0.6620(5) 0.2504(2) 0.0925(3) 0.0516(14) Uani d 1 . . H H5 0.6127 0.2273 0.0720 0.062 Uiso calc 1 . . O O6 -0.1326(3) 0.46345(14) 0.18686(17) 0.0454(9) Uani d 1 . . N N6 0.1184(4) 0.28887(14) 0.3511(2) 0.0403(10) Uani d 1 . . C C6 0.7832(6) 0.2489(2) 0.0897(3) 0.0593(16) Uani d 1 . . H H6 0.8159 0.2243 0.0691 0.071 Uiso calc 1 . . N N7 0.0921(3) 0.35967(14) 0.2907(2) 0.0350(9) Uani d 1 . . C C7 0.8557(6) 0.2840(2) 0.1175(3) 0.0605(17) Uani d 1 . . O O7 -0.3731(5) 0.5687(2) 0.3614(3) 0.0975(18) Uani d 1 . . H H7A -0.4142 0.5780 0.3270 0.146 Uiso d 1 . . H H7B -0.3132 0.5848 0.3722 0.146 Uiso d 1 . . N N8 -0.0016(4) 0.38750(15) 0.2702(2) 0.0383(10) Uani d 1 . . C C8 0.8082(5) 0.3211(2) 0.1459(3) 0.0549(15) Uani d 1 . . H H8 0.8579 0.3454 0.1613 0.066 Uiso calc 1 . . N N9 -0.0999(4) 0.36907(18) 0.2876(3) 0.0533(12) Uani d 1 . . C C9 0.0470(5) 0.32472(18) 0.3208(3) 0.0408(12) Uani d 1 . . N N10 -0.0708(4) 0.32938(18) 0.3194(3) 0.0571(13) Uani d 1 . . C C10 0.0624(5) 0.25876(18) 0.3832(3) 0.0479(13) Uani d 1 . . H H10 -0.0189 0.2637 0.3835 0.057 Uiso calc 1 . . N N11 0.3260(4) 0.46264(13) 0.4211(2) 0.0358(9) Uani d 1 . . C C11 0.1132(6) 0.21851(18) 0.4183(3) 0.0499(14) Uani d 1 . . N N12 0.3170(3) 0.38577(13) 0.38234(19) 0.0327(9) Uani d 1 . . C C12 0.2363(6) 0.20986(18) 0.4297(3) 0.0494(14) Uani d 1 . . N N13 0.3262(4) 0.34435(14) 0.4130(2) 0.0382(9) Uani d 1 . . C C13 0.2761(7) 0.1681(2) 0.4607(4) 0.0692(19) Uani d 1 . . H H13 0.3571 0.1608 0.4660 0.083 Uiso calc 1 . . N N14 0.3397(4) 0.34980(15) 0.4797(2) 0.0468(11) Uani d 1 . . C C14 0.1967(7) 0.1381(2) 0.4831(4) 0.0704(19) Uani d 1 . . H H14 0.2236 0.1106 0.5035 0.084 Uiso calc 1 . . N N15 0.3404(4) 0.39454(15) 0.4942(2) 0.0478(11) Uani d 1 . . C C15 0.0765(7) 0.1491(2) 0.4752(4) 0.0677(19) Uani d 1 . . N N16 0.0487(4) 0.42303(14) 0.1252(2) 0.0384(9) Uani d 1 . . C C16 0.0329(7) 0.1885(2) 0.4427(3) 0.0627(17) Uani d 1 . . H H16 -0.0486 0.1950 0.4369 0.075 Uiso calc 1 . . N N17 0.2155(4) 0.37604(14) 0.1654(2) 0.0363(9) Uani d 1 . . C C17 0.3263(4) 0.41544(17) 0.4331(2) 0.0349(11) Uani d 1 . . N N18 0.2821(4) 0.34534(15) 0.1365(2) 0.0400(10) Uani d 1 . . C C18 0.3408(5) 0.48841(18) 0.4760(3) 0.0439(12) Uani d 1 . . H H18 0.3455 0.4737 0.5183 0.053 Uiso calc 1 . . N N19 0.2425(4) 0.34304(19) 0.0701(2) 0.0564(13) Uani d 1 . . C C19 0.3504(5) 0.53648(17) 0.4773(3) 0.0408(12) Uani d 1 . . N N20 0.1511(5) 0.37151(19) 0.0551(2) 0.0593(14) Uani d 1 . . C C20 0.3618(4) 0.56385(17) 0.4187(3) 0.0391(11) Uani d 1 . . N N21 0.5383(4) 0.27773(15) 0.2862(2) 0.0450(11) Uani d 1 . . C C21 0.3745(5) 0.61070(18) 0.4273(3) 0.0496(14) Uani d 1 . . H H21 0.3862 0.6287 0.3898 0.060 Uiso calc 1 . . N N22 0.6443(5) 0.26012(19) 0.2880(3) 0.0613(14) Uani d 1 . . C C22 0.3702(6) 0.6312(2) 0.4899(3) 0.0548(15) Uani d 1 . . H H22 0.3777 0.6627 0.4944 0.066 Uiso calc 1 . . N N23 0.6766(5) 0.2401(2) 0.3503(3) 0.0741(17) Uani d 1 . . C C23 0.3544(5) 0.6043(2) 0.5470(3) 0.0528(14) Uani d 1 . . N N24 0.4962(4) 0.27067(15) 0.3466(2) 0.0424(10) Uani d 1 . . C C24 0.3482(5) 0.55804(19) 0.5421(3) 0.0487(13) Uani d 1 . . H H24 0.3424 0.5405 0.5810 0.058 Uiso calc 1 . . N N25 0.5830(6) 0.2344(2) 0.4502(3) 0.0830(19) Uani d 1 . . H H25A 0.6435 0.2203 0.4725 0.100 Uiso calc 1 . . H H25B 0.5213 0.2401 0.4699 0.100 Uiso calc 1 . . C C25 0.1372(5) 0.39184(18) 0.1145(3) 0.0412(12) Uani d 1 . . N N26 0.2707(4) 0.23936(15) 0.2606(2) 0.0453(11) Uani d 1 . . C C26 -0.0171(5) 0.43764(19) 0.0693(3) 0.0431(12) Uani d 1 . . H H26 0.0068 0.4294 0.0275 0.052 Uiso calc 1 . . C C27 -0.1224(5) 0.46505(18) 0.0659(3) 0.0409(12) Uani d 1 . . N N27 0.2163(6) 0.20047(19) 0.2543(3) 0.0734(12) Uani d 1 . . C C28 -0.1803(4) 0.47505(19) 0.1242(3) 0.0409(12) Uani d 1 . . N N28 0.2215(6) 0.18469(19) 0.1907(3) 0.0734(12) Uani d 1 . . N N29 0.3145(4) 0.25004(15) 0.2019(2) 0.0466(11) Uani d 1 . . C C29 -0.2919(5) 0.4954(2) 0.1119(3) 0.0485(13) Uani d 1 . . H H29 -0.3338 0.5003 0.1488 0.058 Uiso calc 1 . . N N30 0.3074(6) 0.2132(2) 0.0948(3) 0.086(2) Uani d 1 . . H H30A 0.3459 0.2350 0.0785 0.104 Uiso calc 1 . . H H30B 0.2846 0.1899 0.0695 0.104 Uiso calc 1 . . C C30 -0.3424(5) 0.5086(2) 0.0474(3) 0.0511(14) Uani d 1 . . H H30 -0.4171 0.5226 0.0408 0.061 Uiso calc 1 . . N N31 0.1061(4) 0.50810(15) 0.3523(2) 0.0418(10) Uani d 1 . . C C31 -0.2818(5) 0.5011(2) -0.0087(3) 0.0486(13) Uani d 1 . . N N32 0.0759(4) 0.5352(2) 0.3990(3) 0.0625(15) Uani d 1 . . C C32 -0.1761(5) 0.4793(2) 0.0000(3) 0.0494(14) Uani d 1 . . H H32 -0.1377 0.4735 -0.0380 0.059 Uiso calc 1 . . N N33 -0.0438(5) 0.5363(2) 0.3949(3) 0.0683(16) Uani d 1 . . C C33 0.5850(6) 0.2474(2) 0.3850(3) 0.0588(16) Uani d 1 . . N N34 0.0045(4) 0.49026(15) 0.3146(2) 0.0381(9) Uani d 1 . . C C34 0.2824(6) 0.2156(2) 0.1606(3) 0.0626(17) Uani d 1 . . N N35 -0.2011(4) 0.5002(2) 0.3217(3) 0.0705(17) Uani d 1 . . H H35A -0.2225 0.4821 0.2876 0.085 Uiso calc 1 . . H H35B -0.2544 0.5131 0.3423 0.085 Uiso calc 1 . . C C35 0.2252(5) 0.57096(18) 0.1992(3) 0.0449(13) Uani d 1 . . N N36 0.1048(4) 0.51459(15) 0.1923(2) 0.0401(10) Uani d 1 . . C C36 -0.0850(5) 0.5083(2) 0.3425(3) 0.0494(14) Uani d 1 . . N N37 0.0619(5) 0.54431(17) 0.1466(2) 0.0529(12) Uani d 1 . . C C37 0.194(2) 0.3940(12) -0.1808(14) 0.141(6) Uani d 0.484(10) A 2 H H37A 0.1231 0.4091 -0.2040 0.169 Uiso calc 0.484(10) A 2 H H37B 0.2597 0.4157 -0.1773 0.169 Uiso calc 0.484(10) A 2 C C37' 0.233(2) 0.3846(11) -0.1770(13) 0.141(6) Uani d 0.516(10) A 1 H H37C 0.2024 0.4120 -0.2011 0.169 Uiso calc 0.516(10) A 1 H H37D 0.3197 0.3861 -0.1709 0.169 Uiso calc 0.516(10) A 1 N N38 0.1345(5) 0.58063(18) 0.1491(3) 0.0639(14) Uani d 1 . . C C38 0.173(13) 0.380(3) -0.107(2) 0.137(10) Uani d 0.484(10) A 2 H H38A 0.1023 0.3619 -0.1103 0.206 Uiso calc 0.484(10) A 2 H H38B 0.1626 0.4075 -0.0813 0.206 Uiso calc 0.484(10) A 2 H H38C 0.2407 0.3636 -0.0852 0.206 Uiso calc 0.484(10) A 2 C C38' 0.192(11) 0.384(2) -0.105(2) 0.137(10) Uani d 0.516(10) A 1 H H38D 0.1095 0.3752 -0.1098 0.206 Uiso calc 0.516(10) A 1 H H38E 0.2012 0.4141 -0.0854 0.206 Uiso calc 0.516(10) A 1 H H38F 0.2401 0.3629 -0.0759 0.206 Uiso calc 0.516(10) A 1 N N39 0.2094(4) 0.53055(14) 0.2282(2) 0.0382(9) Uani d 1 . . C C39 0.3483(13) 0.3569(7) -0.2244(10) 0.117(5) Uani d 0.484(10) A 2 H H39A 0.3901 0.3665 -0.1799 0.140 Uiso calc 0.484(10) A 2 H H39B 0.3649 0.3790 -0.2585 0.140 Uiso calc 0.484(10) A 2 C C39' 0.2622(15) 0.3437(7) -0.2752(10) 0.117(5) Uani d 0.516(10) A 1 H H39C 0.2694 0.3745 -0.2926 0.140 Uiso calc 0.516(10) A 1 H H39D 0.2163 0.3262 -0.3118 0.140 Uiso calc 0.516(10) A 1 N N40 0.3217(5) 0.59789(18) 0.2180(3) 0.0645(15) Uani d 1 . . H H40A 0.3772 0.5893 0.2502 0.077 Uiso calc 1 . . H H40B 0.3276 0.6236 0.1976 0.077 Uiso calc 1 . . C C40 0.396(3) 0.3097(9) -0.243(2) 0.135(7) Uani d 0.484(10) A 2 H H40C 0.3864 0.3064 -0.2919 0.202 Uiso calc 0.484(10) A 2 H H40D 0.3512 0.2862 -0.2236 0.202 Uiso calc 0.484(10) A 2 H H40E 0.4789 0.3072 -0.2240 0.202 Uiso calc 0.484(10) A 2 C C40' 0.389(2) 0.3230(11) -0.2606(18) 0.135(7) Uani d 0.516(10) A 1 H H40F 0.4365 0.3343 -0.2936 0.202 Uiso calc 0.516(10) A 1 H H40G 0.3834 0.2903 -0.2639 0.202 Uiso calc 0.516(10) A 1 H H40H 0.4254 0.3314 -0.2150 0.202 Uiso calc 0.516(10) A 1 N N41 0.2219(15) 0.3560(8) -0.2219(9) 0.103(4) Uani d 0.484(10) A 2 H H41 0.1988 0.3282 -0.2008 0.124 Uiso d 0.484(10) A 2 C C41 0.1588(15) 0.3621(9) -0.2902(10) 0.147(7) Uani d 0.484(10) A 2 H H41A 0.1931 0.3424 -0.3220 0.177 Uiso calc 0.484(10) A 2 H H41B 0.1671 0.3935 -0.3046 0.177 Uiso calc 0.484(10) A 2 N N41' 0.1951(15) 0.3460(8) -0.2190(9) 0.103(4) Uani d 0.516(10) A 1 H H41' 0.2069 0.3189 -0.1914 0.124 Uiso d 0.516(10) A 1 C C41' 0.0704(13) 0.3512(9) -0.2460(12) 0.147(7) Uani d 0.516(10) A 1 H H41C 0.0473 0.3220 -0.2670 0.177 Uiso calc 0.516(10) A 1 H H41D 0.0305 0.3531 -0.2055 0.177 Uiso calc 0.516(10) A 1 N N42 -0.0147(11) 0.3378(4) 0.5054(5) 0.149(3) Uani d 1 . . C C42 0.0241(18) 0.3506(10) -0.2923(16) 0.128(9) Uani d 0.484(10) A 2 H H42A -0.0224 0.3780 -0.2999 0.192 Uiso calc 0.484(10) A 2 H H42B 0.0117 0.3372 -0.2492 0.192 Uiso calc 0.484(10) A 2 H H42C -0.0003 0.3294 -0.3290 0.192 Uiso calc 0.484(10) A 2 C C42' 0.011(2) 0.3837(9) -0.2920(15) 0.139(10) Uani d 0.516(10) A 1 H H42D 0.0401 0.4137 -0.2786 0.208 Uiso calc 0.516(10) A 1 H H42E -0.0734 0.3823 -0.2906 0.208 Uiso calc 0.516(10) A 1 H H42F 0.0266 0.3773 -0.3379 0.208 Uiso calc 0.516(10) A 1 C C43 -0.0137(14) 0.3727(5) 0.4832(7) 0.149(3) Uani d 1 . . C C44 -0.0170(10) 0.4147(3) 0.4516(5) 0.102(3) Uani d 1 . . H H44A -0.0018 0.4111 0.4049 0.153 Uiso calc 1 . . H H44B 0.0431 0.4341 0.4762 0.153 Uiso calc 1 . . H H44C -0.0945 0.4282 0.4515 0.153 Uiso calc 1 . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Fe1 0.0378(4) 0.0362(4) 0.0384(4) -0.0008(3) 0.0084(3) -0.0070(3) Cl1 0.0531(10) 0.1021(15) 0.1332(19) 0.0037(10) 0.0371(11) -0.0379(14) O1 0.046(2) 0.051(2) 0.042(2) -0.0027(17) 0.0117(16) -0.0159(17) N1 0.036(2) 0.038(2) 0.037(2) -0.0013(18) 0.0073(17) -0.0079(18) C1 0.031(2) 0.035(3) 0.033(2) 0.004(2) 0.0067(19) -0.002(2) Fe2 0.0452(4) 0.0296(4) 0.0421(4) -0.0017(3) 0.0106(3) -0.0010(3) Cl2 0.1143(16) 0.0631(12) 0.1173(17) -0.0273(11) 0.0420(14) 0.0211(11) O2 0.0399(18) 0.0295(17) 0.0372(18) 0.0011(14) 0.0098(14) -0.0030(14) N2 0.035(2) 0.026(2) 0.034(2) -0.0036(17) 0.0042(16) -0.0037(16) C2 0.039(3) 0.044(3) 0.039(3) -0.002(2) 0.009(2) -0.006(2) Fe3 0.0334(4) 0.0298(4) 0.0312(4) -0.0006(3) 0.0056(3) -0.0024(3) Cl3 0.1142(15) 0.0578(10) 0.0535(9) -0.0009(10) 0.0111(9) -0.0205(8) O3 0.056(2) 0.041(2) 0.066(3) -0.0027(18) 0.0150(19) 0.0148(19) N3 0.033(2) 0.032(2) 0.034(2) -0.0048(17) 0.0031(17) -0.0017(17) C3 0.040(3) 0.054(3) 0.042(3) 0.004(3) 0.009(2) -0.012(3) Fe4 0.0359(4) 0.0306(4) 0.0319(4) 0.0006(3) 0.0041(3) -0.0025(3) Cl4 0.0784(11) 0.1013(14) 0.0436(8) 0.0271(10) -0.0020(8) 0.0135(9) O4 0.0322(17) 0.0324(17) 0.0327(17) 0.0009(14) 0.0025(13) -0.0013(14) N4 0.038(2) 0.038(2) 0.059(3) -0.003(2) 0.010(2) -0.005(2) C4 0.044(3) 0.050(3) 0.034(3) 0.002(2) 0.010(2) -0.003(2) Fe5 0.0339(4) 0.0393(4) 0.0296(4) 0.0019(3) 0.0031(3) -0.0014(3) O5 0.053(2) 0.0368(19) 0.0351(18) -0.0050(16) 0.0084(16) -0.0026(15) N5 0.036(2) 0.042(3) 0.058(3) -0.005(2) 0.013(2) -0.004(2) C5 0.053(3) 0.055(4) 0.048(3) -0.004(3) 0.014(3) -0.013(3) O6 0.0331(18) 0.068(3) 0.0345(19) 0.0040(17) 0.0034(15) 0.0035(17) N6 0.043(2) 0.035(2) 0.043(2) -0.0073(19) 0.0102(19) 0.0002(19) C6 0.069(4) 0.058(4) 0.054(4) 0.009(3) 0.019(3) -0.011(3) N7 0.035(2) 0.035(2) 0.036(2) 0.0009(18) 0.0076(17) -0.0014(18) C7 0.049(3) 0.068(4) 0.068(4) 0.004(3) 0.022(3) -0.016(3) O7 0.091(4) 0.113(5) 0.089(4) 0.005(3) 0.016(3) -0.020(3) N8 0.034(2) 0.046(3) 0.035(2) 0.0000(19) 0.0066(17) 0.0013(19) C8 0.053(3) 0.057(4) 0.058(4) -0.001(3) 0.018(3) -0.014(3) N9 0.036(2) 0.062(3) 0.062(3) -0.003(2) 0.008(2) 0.008(3) C9 0.040(3) 0.040(3) 0.044(3) -0.008(2) 0.009(2) -0.004(2) N10 0.038(3) 0.059(3) 0.075(4) -0.003(2) 0.012(2) 0.019(3) C10 0.051(3) 0.039(3) 0.055(3) -0.002(3) 0.013(3) -0.002(3) N11 0.042(2) 0.028(2) 0.037(2) -0.0019(17) 0.0043(18) -0.0036(17) C11 0.067(4) 0.038(3) 0.048(3) -0.011(3) 0.019(3) 0.001(2) N12 0.041(2) 0.027(2) 0.031(2) 0.0004(17) 0.0073(17) 0.0010(16) C12 0.064(4) 0.036(3) 0.050(3) -0.001(3) 0.017(3) -0.001(2) N13 0.046(2) 0.029(2) 0.039(2) 0.0019(18) 0.0028(18) 0.0000(18) C13 0.076(5) 0.042(3) 0.090(5) -0.002(3) 0.017(4) 0.011(3) N14 0.071(3) 0.034(2) 0.035(2) -0.001(2) 0.007(2) 0.0002(18) C14 0.088(5) 0.040(3) 0.085(5) 0.002(3) 0.020(4) 0.012(3) N15 0.071(3) 0.035(2) 0.035(2) 0.004(2) 0.002(2) -0.0008(19) C15 0.092(5) 0.040(3) 0.075(5) -0.019(3) 0.021(4) 0.000(3) N16 0.038(2) 0.042(2) 0.034(2) -0.0015(19) 0.0030(18) -0.0005(18) C16 0.076(4) 0.045(3) 0.070(4) -0.009(3) 0.020(3) 0.004(3) N17 0.036(2) 0.037(2) 0.037(2) -0.0025(18) 0.0082(18) -0.0087(18) C17 0.038(3) 0.036(3) 0.030(2) 0.002(2) 0.004(2) -0.004(2) N18 0.041(2) 0.046(3) 0.035(2) 0.001(2) 0.0106(18) -0.0092(19) C18 0.058(3) 0.039(3) 0.035(3) -0.003(3) 0.004(2) -0.003(2) N19 0.060(3) 0.072(3) 0.037(3) 0.015(3) 0.005(2) -0.012(2) C19 0.048(3) 0.036(3) 0.038(3) -0.004(2) 0.004(2) -0.007(2) N20 0.064(3) 0.078(4) 0.034(2) 0.021(3) -0.001(2) -0.010(2) C20 0.039(3) 0.035(3) 0.042(3) 0.001(2) 0.003(2) -0.005(2) N21 0.047(3) 0.037(2) 0.051(3) 0.002(2) 0.009(2) -0.002(2) C21 0.065(4) 0.033(3) 0.049(3) -0.001(3) 0.001(3) -0.002(2) N22 0.060(3) 0.061(3) 0.065(3) 0.022(3) 0.019(3) 0.012(3) C22 0.068(4) 0.035(3) 0.061(4) -0.004(3) 0.006(3) -0.011(3) N23 0.064(3) 0.089(4) 0.073(4) 0.031(3) 0.024(3) 0.026(3) C23 0.061(4) 0.048(3) 0.049(3) 0.000(3) 0.007(3) -0.015(3) N24 0.046(3) 0.037(2) 0.044(2) 0.004(2) 0.008(2) 0.0011(19) C24 0.063(4) 0.046(3) 0.037(3) 0.000(3) 0.007(3) -0.005(2) N25 0.076(4) 0.108(5) 0.067(4) 0.031(4) 0.017(3) 0.034(4) C25 0.042(3) 0.046(3) 0.034(3) 0.002(2) 0.003(2) -0.003(2) N26 0.050(3) 0.035(2) 0.052(3) -0.009(2) 0.012(2) -0.007(2) C26 0.047(3) 0.050(3) 0.032(3) 0.002(3) 0.004(2) -0.005(2) C27 0.040(3) 0.045(3) 0.035(3) -0.003(2) -0.003(2) 0.000(2) N27 0.099(3) 0.052(2) 0.074(3) -0.028(2) 0.029(2) -0.0225(19) C28 0.035(3) 0.049(3) 0.039(3) -0.007(2) 0.003(2) 0.003(2) N28 0.099(3) 0.052(2) 0.074(3) -0.028(2) 0.029(2) -0.0225(19) N29 0.051(3) 0.037(2) 0.053(3) -0.003(2) 0.012(2) -0.011(2) C29 0.042(3) 0.057(4) 0.047(3) 0.005(3) 0.010(2) 0.008(3) N30 0.110(5) 0.085(4) 0.070(4) -0.039(4) 0.032(4) -0.035(3) C30 0.040(3) 0.057(4) 0.054(3) 0.008(3) -0.003(3) 0.002(3) N31 0.037(2) 0.049(3) 0.038(2) 0.002(2) 0.0025(18) -0.012(2) C31 0.048(3) 0.053(3) 0.042(3) 0.004(3) -0.003(2) 0.005(3) N32 0.045(3) 0.080(4) 0.063(3) 0.001(3) 0.008(2) -0.035(3) C32 0.052(3) 0.060(4) 0.036(3) 0.002(3) 0.006(2) 0.000(3) N33 0.047(3) 0.089(4) 0.070(4) 0.009(3) 0.011(3) -0.039(3) C33 0.061(4) 0.057(4) 0.058(4) 0.014(3) 0.008(3) 0.008(3) N34 0.034(2) 0.045(2) 0.035(2) 0.0053(19) 0.0064(17) -0.0013(19) C34 0.068(4) 0.060(4) 0.064(4) -0.014(3) 0.023(3) -0.024(3) N35 0.037(3) 0.097(4) 0.079(4) 0.002(3) 0.015(3) -0.032(3) C35 0.059(3) 0.030(3) 0.048(3) 0.000(3) 0.013(3) 0.002(2) N36 0.044(2) 0.042(2) 0.034(2) 0.005(2) 0.0052(18) 0.0007(19) C36 0.042(3) 0.057(4) 0.050(3) 0.004(3) 0.013(2) -0.008(3) N37 0.061(3) 0.052(3) 0.043(3) 0.005(2) 0.000(2) 0.008(2) C37 0.172(11) 0.116(10) 0.138(8) -0.011(8) 0.036(8) -0.028(7) C37' 0.172(11) 0.116(10) 0.138(8) -0.011(8) 0.036(8) -0.028(7) N38 0.082(4) 0.051(3) 0.055(3) -0.005(3) -0.004(3) 0.017(2) C38 0.19(3) 0.125(13) 0.087(7) 0.009(12) -0.006(11) -0.011(7) C38' 0.19(3) 0.125(13) 0.087(7) 0.009(12) -0.006(11) -0.011(7) N39 0.043(2) 0.034(2) 0.037(2) 0.0010(19) 0.0071(19) -0.0002(18) C39 0.115(8) 0.132(9) 0.104(8) -0.021(7) 0.017(6) -0.004(7) C39' 0.115(8) 0.132(9) 0.104(8) -0.021(7) 0.017(6) -0.004(7) N40 0.078(4) 0.048(3) 0.065(3) -0.015(3) 0.003(3) 0.013(3) C40 0.126(8) 0.143(11) 0.137(12) 0.003(8) 0.025(7) 0.001(9) C40' 0.126(8) 0.143(11) 0.137(12) 0.003(8) 0.025(7) 0.001(9) N41 0.121(8) 0.087(10) 0.101(6) -0.005(8) 0.015(7) -0.009(6) C41 0.139(10) 0.161(10) 0.136(10) 0.012(8) 0.000(7) 0.012(8) N41' 0.121(8) 0.087(10) 0.101(6) -0.005(8) 0.015(7) -0.009(6) C41' 0.139(10) 0.161(10) 0.136(10) 0.012(8) 0.000(7) 0.012(8) N42 0.204(8) 0.123(7) 0.123(6) 0.034(6) 0.039(5) 0.052(5) C42 0.117(11) 0.125(12) 0.137(12) -0.006(9) 0.002(9) 0.000(9) C42' 0.17(2) 0.117(18) 0.13(2) 0.060(17) 0.036(16) 0.045(16) C43 0.204(8) 0.123(7) 0.123(6) 0.034(6) 0.039(5) 0.052(5) C44 0.133(8) 0.096(7) 0.079(6) 0.009(6) 0.022(5) -0.004(5) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle _geom_angle_publ_flag O1 Fe1 O2 . . 174.36(15) ? O1 Fe1 N29 . . 90.87(17) ? O2 Fe1 N29 . . 83.59(15) ? O1 Fe1 N18 . . 96.17(16) ? O2 Fe1 N18 . . 85.21(14) ? N29 Fe1 N18 . . 92.63(18) ? O1 Fe1 N21 . . 95.49(17) ? O2 Fe1 N21 . . 83.13(15) ? N29 Fe1 N21 . . 86.65(18) ? N18 Fe1 N21 . . 168.32(16) ? O1 Fe1 N1 . . 86.57(15) ? O2 Fe1 N1 . . 98.89(14) ? N29 Fe1 N1 . . 175.86(17) ? N18 Fe1 N1 . . 90.89(16) ? N21 Fe1 N1 . . 90.34(16) ? C4 O1 Fe1 . . 128.2(3) ? C2 N1 C1 . . 116.0(4) ? C2 N1 Fe1 . . 119.7(3) ? C1 N1 Fe1 . . 123.9(3) ? N2 C1 N5 . . 111.0(4) ? N2 C1 N1 . . 121.7(4) ? N5 C1 N1 . . 127.3(4) ? O3 Fe2 O2 . . 170.98(16) ? O3 Fe2 N24 . . 86.78(17) ? O2 Fe2 N24 . . 84.28(15) ? O3 Fe2 N26 . . 96.03(18) ? O2 Fe2 N26 . . 82.62(15) ? N24 Fe2 N26 . . 89.15(17) ? O3 Fe2 N13 . . 98.76(17) ? O2 Fe2 N13 . . 84.00(14) ? N24 Fe2 N13 . . 99.67(16) ? N26 Fe2 N13 . . 163.14(17) ? O3 Fe2 N6 . . 86.27(16) ? O2 Fe2 N6 . . 102.56(15) ? N24 Fe2 N6 . . 172.14(16) ? N26 Fe2 N6 . . 87.92(17) ? N13 Fe2 N6 . . 85.03(16) ? Fe3 O2 Fe2 . . 120.95(17) ? Fe3 O2 Fe1 . . 119.71(17) ? Fe2 O2 Fe1 . . 119.17(16) ? C1 N2 N3 . . 105.2(4) ? C1 N2 Fe3 . . 139.0(3) ? N3 N2 Fe3 . . 115.7(3) ? N1 C2 C3 . . 126.5(5) ? N1 C2 H2 . . 116.7 ? C3 C2 H2 . . 116.7 ? O2 Fe3 O4 . . 178.83(14) ? O2 Fe3 N2 . . 93.40(15) ? O4 Fe3 N2 . . 86.29(14) ? O2 Fe3 N7 . . 94.46(15) ? O4 Fe3 N7 . . 85.85(14) ? N2 Fe3 N7 . . 172.13(15) ? O2 Fe3 N17 . . 87.47(15) ? O4 Fe3 N17 . . 93.65(15) ? N2 Fe3 N17 . . 89.50(15) ? N7 Fe3 N17 . . 91.31(15) ? O2 Fe3 N12 . . 85.41(14) ? O4 Fe3 N12 . . 93.47(14) ? N2 Fe3 N12 . . 90.96(15) ? N7 Fe3 N12 . . 89.21(15) ? N17 Fe3 N12 . . 172.88(15) ? C12 O3 Fe2 . . 132.1(4) ? N4 N3 N2 . . 108.9(4) ? N4 N3 Fe4 . . 132.9(3) ? N2 N3 Fe4 . . 118.0(3) ? C8 C3 C4 . . 118.0(5) ? C8 C3 C2 . . 118.0(5) ? C4 C3 C2 . . 124.1(5) ? O4 Fe4 O5 . . 175.77(14) ? O4 Fe4 N39 . . 85.27(15) ? O5 Fe4 N39 . . 91.20(15) ? O4 Fe4 N31 . . 83.73(15) ? O5 Fe4 N31 . . 98.42(16) ? N39 Fe4 N31 . . 86.61(17) ? O4 Fe4 N3 . . 83.57(14) ? O5 Fe4 N3 . . 94.56(15) ? N39 Fe4 N3 . . 96.94(15) ? N31 Fe4 N3 . . 166.48(16) ? O4 Fe4 N11 . . 98.95(14) ? O5 Fe4 N11 . . 84.89(14) ? N39 Fe4 N11 . . 170.57(15) ? N31 Fe4 N11 . . 85.48(16) ? N3 Fe4 N11 . . 91.93(15) ? Fe3 O4 Fe4 . . 120.87(16) ? Fe3 O4 Fe5 . . 120.55(16) ? Fe4 O4 Fe5 . . 118.58(16) ? N3 N4 N5 . . 109.4(4) ? O1 C4 C5 . . 118.9(5) ? O1 C4 C3 . . 122.1(5) ? C5 C4 C3 . . 119.0(5) ? O6 Fe5 O4 . . 175.84(14) ? O6 Fe5 N34 . . 90.87(16) ? O4 Fe5 N34 . . 85.43(14) ? O6 Fe5 N36 . . 98.13(16) ? O4 Fe5 N36 . . 83.52(15) ? N34 Fe5 N36 . . 86.03(16) ? O6 Fe5 N8 . . 95.56(16) ? O4 Fe5 N8 . . 82.88(14) ? N34 Fe5 N8 . . 94.82(16) ? N36 Fe5 N8 . . 166.27(16) ? O6 Fe5 N16 . . 84.85(15) ? O4 Fe5 N16 . . 99.05(14) ? N34 Fe5 N16 . . 171.91(16) ? N36 Fe5 N16 . . 87.78(16) ? N8 Fe5 N16 . . 92.43(16) ? C20 O5 Fe4 . . 128.2(3) ? N4 N5 C1 . . 105.4(4) ? C6 C5 C4 . . 120.7(5) ? C6 C5 H5 . . 119.6 ? C4 C5 H5 . . 119.6 ? C28 O6 Fe5 . . 131.3(3) ? C10 N6 C9 . . 115.1(4) ? C10 N6 Fe2 . . 122.3(4) ? C9 N6 Fe2 . . 122.7(3) ? C5 C6 C7 . . 119.8(6) ? C5 C6 H6 . . 120.1 ? C7 C6 H6 . . 120.1 ? C9 N7 N8 . . 105.3(4) ? C9 N7 Fe3 . . 139.2(4) ? N8 N7 Fe3 . . 115.2(3) ? C8 C7 C6 . . 120.7(6) ? C8 C7 Cl1 . . 120.2(5) ? C6 C7 Cl1 . . 119.1(5) ? H7A O7 H7B . . 111.6 ? N9 N8 N7 . . 109.1(4) ? N9 N8 Fe5 . . 131.3(3) ? N7 N8 Fe5 . . 119.3(3) ? C7 C8 C3 . . 121.6(6) ? C7 C8 H8 . . 119.2 ? C3 C8 H8 . . 119.2 ? N8 N9 N10 . . 108.5(4) ? N7 C9 N10 . . 111.1(5) ? N7 C9 N6 . . 122.3(4) ? N10 C9 N6 . . 126.6(5) ? C9 N10 N9 . . 106.0(4) ? N6 C10 C11 . . 126.8(5) ? N6 C10 H10 . . 116.6 ? C11 C10 H10 . . 116.6 ? C18 N11 C17 . . 115.7(4) ? C18 N11 Fe4 . . 120.1(3) ? C17 N11 Fe4 . . 123.5(3) ? C16 C11 C12 . . 120.7(6) ? C16 C11 C10 . . 116.5(6) ? C12 C11 C10 . . 122.8(5) ? C17 N12 N13 . . 105.3(4) ? C17 N12 Fe3 . . 138.0(3) ? N13 N12 Fe3 . . 115.3(3) ? O3 C12 C11 . . 123.5(5) ? O3 C12 C13 . . 118.2(6) ? C11 C12 C13 . . 118.2(6) ? N14 N13 N12 . . 109.0(4) ? N14 N13 Fe2 . . 133.3(3) ? N12 N13 Fe2 . . 117.7(3) ? C14 C13 C12 . . 120.8(7) ? C14 C13 H13 . . 119.6 ? C12 C13 H13 . . 119.6 ? N13 N14 N15 . . 109.2(4) ? C13 C14 C15 . . 119.5(6) ? C13 C14 H14 . . 120.3 ? C15 C14 H14 . . 120.3 ? C17 N15 N14 . . 105.1(4) ? C16 C15 C14 . . 121.8(6) ? C16 C15 Cl2 . . 120.7(6) ? C14 C15 Cl2 . . 117.5(5) ? C26 N16 C25 . . 115.0(4) ? C26 N16 Fe5 . . 120.4(4) ? C25 N16 Fe5 . . 124.3(3) ? C15 C16 C11 . . 118.8(7) ? C15 C16 H16 . . 120.6 ? C11 C16 H16 . . 120.6 ? C25 N17 N18 . . 105.6(4) ? C25 N17 Fe3 . . 138.7(3) ? N18 N17 Fe3 . . 115.6(3) ? N12 C17 N15 . . 111.3(4) ? N12 C17 N11 . . 121.7(4) ? N15 C17 N11 . . 127.0(4) ? N19 N18 N17 . . 108.7(4) ? N19 N18 Fe1 . . 133.2(3) ? N17 N18 Fe1 . . 118.1(3) ? N11 C18 C19 . . 126.3(5) ? N11 C18 H18 . . 116.8 ? C19 C18 H18 . . 116.8 ? N18 N19 N20 . . 109.2(4) ? C18 C19 C24 . . 116.7(5) ? C18 C19 C20 . . 124.3(5) ? C24 C19 C20 . . 119.1(5) ? N19 N20 C25 . . 105.9(4) ? O5 C20 C21 . . 119.9(5) ? O5 C20 C19 . . 121.4(4) ? C21 C20 C19 . . 118.7(5) ? N22 N21 N24 . . 110.7(4) ? N22 N21 Fe1 . . 131.2(4) ? N24 N21 Fe1 . . 117.8(3) ? C22 C21 C20 . . 121.6(6) ? C22 C21 H21 . . 119.2 ? C20 C21 H21 . . 119.2 ? N21 N22 N23 . . 108.9(5) ? C21 C22 C23 . . 119.5(5) ? C21 C22 H22 . . 120.2 ? C23 C22 H22 . . 120.2 ? C33 N23 N22 . . 105.2(5) ? C24 C23 C22 . . 121.0(5) ? C24 C23 Cl3 . . 120.9(5) ? C22 C23 Cl3 . . 118.1(4) ? C33 N24 N21 . . 103.7(4) ? C33 N24 Fe2 . . 138.3(4) ? N21 N24 Fe2 . . 116.2(3) ? C23 C24 C19 . . 120.0(5) ? C23 C24 H24 . . 120.0 ? C19 C24 H24 . . 120.0 ? C33 N25 H25A . . 120.0 ? C33 N25 H25B . . 120.0 ? H25A N25 H25B . . 120.0 ? N17 C25 N20 . . 110.6(5) ? N17 C25 N16 . . 122.2(4) ? N20 C25 N16 . . 127.0(5) ? N27 N26 N29 . . 110.5(4) ? N27 N26 Fe2 . . 131.8(4) ? N29 N26 Fe2 . . 117.5(3) ? N16 C26 C27 . . 126.3(5) ? N16 C26 H26 . . 116.8 ? C27 C26 H26 . . 116.8 ? C32 C27 C28 . . 119.2(5) ? C32 C27 C26 . . 116.9(5) ? C28 C27 C26 . . 123.6(5) ? N26 N27 N28 . . 108.0(5) ? O6 C28 C29 . . 120.9(5) ? O6 C28 C27 . . 121.6(5) ? C29 C28 C27 . . 117.4(5) ? C34 N28 N27 . . 106.0(5) ? C34 N29 N26 . . 104.2(5) ? C34 N29 Fe1 . . 138.2(4) ? N26 N29 Fe1 . . 117.3(3) ? C30 C29 C28 . . 122.0(5) ? C30 C29 H29 . . 119.0 ? C28 C29 H29 . . 119.0 ? C34 N30 H30A . . 120.0 ? C34 N30 H30B . . 120.0 ? H30A N30 H30B . . 120.0 ? C29 C30 C31 . . 120.0(5) ? C29 C30 H30 . . 120.0 ? C31 C30 H30 . . 120.0 ? N32 N31 N34 . . 109.2(4) ? N32 N31 Fe4 . . 132.7(4) ? N34 N31 Fe4 . . 117.6(3) ? C32 C31 C30 . . 120.3(5) ? C32 C31 Cl4 . . 120.4(5) ? C30 C31 Cl4 . . 119.3(4) ? N31 N32 N33 . . 109.8(4) ? C31 C32 C27 . . 120.9(5) ? C31 C32 H32 . . 119.6 ? C27 C32 H32 . . 119.6 ? N32 N33 C36 . . 105.3(4) ? N23 C33 N25 . . 124.2(6) ? N23 C33 N24 . . 111.5(6) ? N25 C33 N24 . . 124.3(6) ? C36 N34 N31 . . 104.6(4) ? C36 N34 Fe5 . . 138.6(4) ? N31 N34 Fe5 . . 115.9(3) ? N29 C34 N28 . . 111.3(6) ? N29 C34 N30 . . 123.2(6) ? N28 C34 N30 . . 125.4(6) ? C36 N35 H35A . . 120.0 ? C36 N35 H35B . . 120.0 ? H35A N35 H35B . . 120.0 ? N39 C35 N38 . . 111.3(5) ? N39 C35 N40 . . 123.6(5) ? N38 C35 N40 . . 125.1(5) ? N37 N36 N39 . . 109.5(4) ? N37 N36 Fe5 . . 131.3(4) ? N39 N36 Fe5 . . 118.6(3) ? N34 C36 N35 . . 125.1(5) ? N34 C36 N33 . . 111.1(5) ? N35 C36 N33 . . 123.9(5) ? N36 N37 N38 . . 110.2(5) ? N41 C37 C38 . . 114(3) ? N41 C37 H37A . . 108.8 ? C38 C37 H37A . . 108.8 ? N41 C37 H37B . . 108.8 ? C38 C37 H37B . . 108.8 ? H37A C37 H37B . . 107.7 ? N41' C37' C38' . . 114.5(11) ? N41' C37' H37C . . 108.6 ? C38' C37' H37C . . 108.6 ? N41' C37' H37D . . 108.6 ? C38' C37' H37D . . 108.6 ? H37C C37' H37D . . 107.6 ? N37 N38 C35 . . 104.8(4) ? C37 C38 H38A . . 109.5 ? C37 C38 H38B . . 109.5 ? H38A C38 H38B . . 109.5 ? C37 C38 H38C . . 109.5 ? H38A C38 H38C . . 109.5 ? H38B C38 H38C . . 109.5 ? C37' C38' H38D . . 109.5 ? C37' C38' H38E . . 109.5 ? H38D C38' H38E . . 109.5 ? C37' C38' H38F . . 109.5 ? H38D C38' H38F . . 109.5 ? H38E C38' H38F . . 109.5 ? C35 N39 N36 . . 104.0(4) ? C35 N39 Fe4 . . 139.4(4) ? N36 N39 Fe4 . . 115.2(3) ? N41 C39 C40 . . 112(2) ? N41 C39 H39A . . 109.3 ? C40 C39 H39A . . 109.3 ? N41 C39 H39B . . 109.3 ? C40 C39 H39B . . 109.3 ? H39A C39 H39B . . 107.9 ? N41' C39' C40' . . 117(2) ? N41' C39' H39C . . 108.0 ? C40' C39' H39C . . 108.0 ? N41' C39' H39D . . 108.0 ? C40' C39' H39D . . 108.0 ? H39C C39' H39D . . 107.3 ? C35 N40 H40A . . 120.0 ? C35 N40 H40B . . 120.0 ? H40A N40 H40B . . 120.0 ? C39 C40 H40C . . 109.5 ? C39 C40 H40D . . 109.5 ? H40C C40 H40D . . 109.5 ? C39 C40 H40E . . 109.5 ? H40C C40 H40E . . 109.5 ? H40D C40 H40E . . 109.5 ? C39' C40' H40F . . 109.5 ? C39' C40' H40G . . 109.5 ? H40F C40' H40G . . 109.5 ? C39' C40' H40H . . 109.5 ? H40F C40' H40H . . 109.5 ? H40G C40' H40H . . 109.5 ? C41 N41 C39 . . 109.1(10) ? C41 N41 C37 . . 108.0(10) ? C39 N41 C37 . . 107.7(10) ? C41 N41 H41 . . 112.1 ? C39 N41 H41 . . 111.2 ? C37 N41 H41 . . 108.7 ? N41 C41 C42 . . 110(2) ? N41 C41 H41A . . 109.6 ? C42 C41 H41A . . 109.6 ? N41 C41 H41B . . 109.6 ? C42 C41 H41B . . 109.6 ? H41A C41 H41B . . 108.1 ? C39' N41' C37' . . 109.5(10) ? C39' N41' C41' . . 108.8(10) ? C37' N41' C41' . . 108.8(10) ? C39' N41' H41' . . 110.7 ? C37' N41' H41' . . 109.0 ? C41' N41' H41' . . 110.1 ? C42' C41' N41' . . 131(2) ? C42' C41' H41C . . 104.6 ? N41' C41' H41C . . 104.6 ? C42' C41' H41D . . 104.6 ? N41' C41' H41D . . 104.6 ? H41C C41' H41D . . 105.7 ? C41 C42 H42A . . 109.5 ? C41 C42 H42B . . 109.5 ? H42A C42 H42B . . 109.5 ? C41 C42 H42C . . 109.5 ? H42A C42 H42C . . 109.5 ? H42B C42 H42C . . 109.5 ? C41' C42' H42D . . 109.5 ? C41' C42' H42E . . 109.5 ? H42D C42' H42E . . 109.5 ? C41' C42' H42F . . 109.5 ? H42D C42' H42F . . 109.5 ? H42E C42' H42F . . 109.5 ? N42 C43 C44 . . 176.0(17) ? C43 C44 H44A . . 109.5 ? C43 C44 H44B . . 109.5 ? H44A C44 H44B . . 109.5 ? C43 C44 H44C . . 109.5 ? H44A C44 H44C . . 109.5 ? H44B C44 H44C . . 109.5 ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag Fe1 O1 . 1.903(3) ? Fe1 O2 . 1.922(3) ? Fe1 N29 . 2.098(4) ? Fe1 N18 . 2.151(4) ? Fe1 N21 . 2.164(5) ? Fe1 N1 . 2.186(4) ? Cl1 C7 . 1.744(6) ? O1 C4 . 1.300(6) ? N1 C2 . 1.306(6) ? N1 C1 . 1.403(6) ? C1 N2 . 1.317(6) ? C1 N5 . 1.337(6) ? Fe2 O3 . 1.891(4) ? Fe2 O2 . 1.912(3) ? Fe2 N24 . 2.114(4) ? Fe2 N26 . 2.138(4) ? Fe2 N13 . 2.179(4) ? Fe2 N6 . 2.207(4) ? Cl2 C15 . 1.742(7) ? O2 Fe3 . 1.872(3) ? N2 N3 . 1.356(5) ? N2 Fe3 . 2.095(4) ? C2 C3 . 1.423(7) ? C2 H2 . 0.9300 ? Fe3 O4 . 1.890(3) ? Fe3 N7 . 2.118(4) ? Fe3 N17 . 2.123(4) ? Fe3 N12 . 2.135(4) ? Cl3 C23 . 1.731(6) ? O3 C12 . 1.301(7) ? N3 N4 . 1.304(6) ? N3 Fe4 . 2.183(4) ? C3 C8 . 1.401(8) ? C3 C4 . 1.417(8) ? Fe4 O4 . 1.901(3) ? Fe4 O5 . 1.909(3) ? Fe4 N39 . 2.107(4) ? Fe4 N31 . 2.153(4) ? Fe4 N11 . 2.212(4) ? Cl4 C31 . 1.747(5) ? O4 Fe5 . 1.923(3) ? N4 N5 . 1.333(6) ? C4 C5 . 1.409(7) ? Fe5 O6 . 1.908(3) ? Fe5 N34 . 2.095(4) ? Fe5 N36 . 2.135(4) ? Fe5 N8 . 2.160(4) ? Fe5 N16 . 2.212(4) ? O5 C20 . 1.328(6) ? C5 C6 . 1.378(8) ? C5 H5 . 0.9300 ? O6 C28 . 1.311(6) ? N6 C10 . 1.300(7) ? N6 C9 . 1.403(7) ? C6 C7 . 1.377(9) ? C6 H6 . 0.9300 ? N7 C9 . 1.321(6) ? N7 N8 . 1.350(6) ? C7 C8 . 1.365(8) ? O7 H7A . 0.8086 ? O7 H7B . 0.8275 ? N8 N9 . 1.323(6) ? C8 H8 . 0.9300 ? N9 N10 . 1.338(7) ? C9 N10 . 1.332(7) ? C10 C11 . 1.442(8) ? C10 H10 . 0.9300 ? N11 C18 . 1.306(6) ? N11 C17 . 1.404(6) ? C11 C16 . 1.396(8) ? C11 C12 . 1.398(9) ? N12 C17 . 1.315(6) ? N12 N13 . 1.352(5) ? C12 C13 . 1.411(8) ? N13 N14 . 1.303(6) ? C13 C14 . 1.373(9) ? C13 H13 . 0.9300 ? N14 N15 . 1.342(6) ? C14 C15 . 1.381(10) ? C14 H14 . 0.9300 ? N15 C17 . 1.334(6) ? C15 C16 . 1.375(9) ? N16 C26 . 1.303(6) ? N16 C25 . 1.392(7) ? C16 H16 . 0.9300 ? N17 C25 . 1.317(6) ? N17 N18 . 1.350(6) ? N18 N19 . 1.313(6) ? C18 C19 . 1.413(7) ? C18 H18 . 0.9300 ? N19 N20 . 1.326(7) ? C19 C24 . 1.421(7) ? C19 C20 . 1.422(7) ? N20 C25 . 1.336(7) ? C20 C21 . 1.388(7) ? N21 N22 . 1.298(6) ? N21 N24 . 1.356(6) ? C21 C22 . 1.373(8) ? C21 H21 . 0.9300 ? N22 N23 . 1.356(7) ? C22 C23 . 1.401(9) ? C22 H22 . 0.9300 ? N23 C33 . 1.334(8) ? C23 C24 . 1.359(8) ? N24 C33 . 1.347(7) ? C24 H24 . 0.9300 ? N25 C33 . 1.339(8) ? N25 H25A . 0.8600 ? N25 H25B . 0.8600 ? N26 N27 . 1.292(7) ? N26 N29 . 1.354(6) ? C26 C27 . 1.428(7) ? C26 H26 . 0.9300 ? C27 C32 . 1.408(7) ? C27 C28 . 1.428(7) ? N27 N28 . 1.340(8) ? C28 C29 . 1.383(7) ? N28 C34 . 1.326(8) ? N29 C34 . 1.313(7) ? C29 C30 . 1.366(8) ? C29 H29 . 0.9300 ? N30 C34 . 1.361(9) ? N30 H30A . 0.8600 ? N30 H30B . 0.8600 ? C30 C31 . 1.395(8) ? C30 H30 . 0.9300 ? N31 N32 . 1.294(6) ? N31 N34 . 1.373(6) ? C31 C32 . 1.342(8) ? N32 N33 . 1.341(7) ? C32 H32 . 0.9300 ? N33 C36 . 1.343(7) ? N34 C36 . 1.328(7) ? N35 C36 . 1.336(7) ? N35 H35A . 0.8600 ? N35 H35B . 0.8600 ? C35 N39 . 1.337(6) ? C35 N38 . 1.341(8) ? C35 N40 . 1.352(7) ? N36 N37 . 1.291(6) ? N36 N39 . 1.367(6) ? N37 N38 . 1.340(7) ? C37 N41 . 1.435(10) ? C37 C38 . 1.542(10) ? C37 H37A . 0.9700 ? C37 H37B . 0.9700 ? C37' N41' . 1.428(10) ? C37' C38' . 1.542(10) ? C37' H37C . 0.9700 ? C37' H37D . 0.9700 ? C38 H38A . 0.9600 ? C38 H38B . 0.9600 ? C38 H38C . 0.9600 ? C38' H38D . 0.9600 ? C38' H38E . 0.9600 ? C38' H38F . 0.9600 ? C39 N41 . 1.435(10) ? C39 C40 . 1.544(10) ? C39 H39A . 0.9700 ? C39 H39B . 0.9700 ? C39' N41' . 1.428(10) ? C39' C40' . 1.541(10) ? C39' H39C . 0.9700 ? C39' H39D . 0.9700 ? N40 H40A . 0.8600 ? N40 H40B . 0.8600 ? C40 H40C . 0.9600 ? C40 H40D . 0.9600 ? C40 H40E . 0.9600 ? C40' H40F . 0.9600 ? C40' H40G . 0.9600 ? C40' H40H . 0.9600 ? N41 C41 . 1.434(10) ? N41 H41 . 0.9664 ? C41 C42 . 1.552(10) ? C41 H41A . 0.9700 ? C41 H41B . 0.9700 ? N41' C41' . 1.437(10) ? N41' H41' . 0.9577 ? C41' C42' . 1.41(3) ? C41' H41C . 0.9700 ? C41' H41D . 0.9700 ? N42 C43 . 1.112(14) ? C42 H42A . 0.9600 ? C42 H42B . 0.9600 ? C42 H42C . 0.9600 ? C42' H42D . 0.9600 ? C42' H42E . 0.9600 ? C42' H42F . 0.9600 ? C43 C44 . 1.377(14) ? C44 H44A . 0.9600 ? C44 H44B . 0.9600 ? C44 H44C . 0.9600 ? loop_ _geom_hbond_atom_site_label_D _geom_hbond_atom_site_label_H _geom_hbond_atom_site_label_A _geom_hbond_site_symmetry_A _geom_hbond_distance_DH _geom_hbond_distance_HA _geom_hbond_distance_DA _geom_hbond_angle_DHA N25 H25B Cl1 4_566 0.86 2.95 3.496(6) 123.3 N25 H25B O3 . 0.86 2.40 2.990(7) 126.0 N30 H30A O1 . 0.86 2.39 3.030(7) 132.1 N35 H35A O6 . 0.86 2.41 3.056(6) 132.1 N35 H35A N5 1_455 0.86 2.42 3.089(7) 134.7 N40 H40A O5 . 0.86 2.48 3.103(6) 129.7 N40 H40B N27 2_555 0.86 2.52 3.096(8) 125.3 N41 H41 N23 4_566 0.97 2.27 3.23(2) 170.7 C21 H21 N28 2_555 0.93 2.47 3.240(8) 140.2 N30 H30B N42 4_665 0.86 2.86 3.218(12) 106.8 _cod_database_fobs_code 2022177