#------------------------------------------------------------------------------ #$Date: 2024-12-21 04:46:35 +0200 (Sat, 21 Dec 2024) $ #$Revision: 296941 $ #$URL: file:///home/coder/svn-repositories/cod/cif/1/57/35/1573525.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_1573525 loop_ _publ_author_name 'Patyk-Kaźmierczak, Ewa' 'Szymańska, Kornelia' 'Kaźmierczak, Michał' _publ_section_title ; Managing negative linear compressibility and thermal expansion through steric hindrance: a case study of 1,2-bis(4'-pyridyl)ethane cocrystals. ; _journal_issue 1 _journal_name_full IUCrJ _journal_paper_doi 10.1107/S2052252524011734 _journal_volume 12 _journal_year 2025 _chemical_formula_moiety 'C12 H12 N2, C4 H6 O4' _chemical_formula_sum 'C16 H18 N2 O4' _chemical_formula_weight 302.32 _chemical_name_systematic '4,4'-Ethane-1,2-diyldipyridine succinic acid' _space_group_crystal_system monoclinic _space_group_IT_number 15 _space_group_name_Hall '-I 2ya' _space_group_name_H-M_alt 'I 1 2/a 1' _atom_sites_solution_hydrogens geom _audit_creation_date 2023-08-24 _audit_creation_method ; Olex2 1.5 (compiled 2023.08.17 svn.r577a77a9 for OlexSys, GUI svn.r6817) ; _cell_angle_alpha 90 _cell_angle_beta 114.3(3) _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 16.46(6) _cell_length_b 4.3839(7) _cell_length_c 18.94(2) _cell_measurement_reflns_used 521 _cell_measurement_temperature 295(2) _cell_measurement_theta_max 24.0580 _cell_measurement_theta_min 2.3200 _cell_volume 1246(6) _computing_cell_refinement 'CrysAlisPro 1.171.42.49 (Rigaku OD, 2022)' _computing_data_collection 'CrysAlisPro 1.171.42.49 (Rigaku OD, 2022)' _computing_data_reduction 'CrysAlisPro 1.171.42.49 (Rigaku OD, 2022)' _computing_molecular_graphics 'Olex2 1.5 (Dolomanov et al., 2009)' _computing_publication_material 'Olex2 1.5 (Dolomanov et al., 2009)' _computing_structure_refinement 'SHELXL 2014/7 (Sheldrick, 2015)' _diffrn_ambient_pressure 3730000 _diffrn_ambient_temperature 295(2) _diffrn_detector 'CCD plate' _diffrn_detector_area_resol_mean 8.0169 _diffrn_detector_type EosS2 _diffrn_measured_fraction_theta_full 0.221 _diffrn_measured_fraction_theta_max 0.200 _diffrn_measurement_details ; List of Runs (angles in degrees, time in seconds): # Type Start End Width t~exp~ \w \q \k \f Frames -------------------------------------------------------------------------- 1 \w -52.00 27.00 1.00 35.00 -- -26.24 39.00 -12.00 79 2 \w -27.00 39.00 1.00 35.00 -- -26.24 -39.00 12.00 66 3 \w 18.00 52.00 1.00 35.00 -- -26.24-135.00-123.00 34 4 \w -52.00 27.00 1.00 35.00 -- -26.24 19.00-180.00 79 5 \w -27.00 39.00 1.00 35.00 -- -26.24 -39.00-167.00 66 6 \w -4.00 30.00 1.00 35.00 -- -26.24 -97.00 35.00 34 7 \w -97.00 -18.00 1.00 35.00 -- -26.24 135.00 -57.00 79 8 \w -63.00 16.00 1.00 35.00 -- -26.24 67.00 157.00 79 9 \w -10.00 57.00 1.00 35.00 -- 27.18 -53.00-162.00 67 10 \w -38.00 27.00 1.00 35.00 -- 27.18 39.00 -12.00 65 11 \w 18.00 52.00 1.00 35.00 -- -26.24-135.00 57.00 34 12 \w 0.00 31.00 1.00 35.00 -- -26.24 -99.00-150.00 31 13 \w -35.00 44.00 1.00 35.00 -- -26.24 -13.00 3.00 79 14 \w -29.00 4.00 1.00 35.00 -- 27.18 97.00 -35.00 33 ; _diffrn_measurement_device 'four-circle diffractometer' _diffrn_measurement_device_type 'New Xcalibur, EosS2' _diffrn_measurement_method '\w scans' _diffrn_orient_matrix_type 'CrysAlisPro convention (1999,Acta A55,543-557)' _diffrn_orient_matrix_UB_11 -0.0467767000 _diffrn_orient_matrix_UB_12 -0.0183996000 _diffrn_orient_matrix_UB_13 -0.0110914000 _diffrn_orient_matrix_UB_21 -0.0081198000 _diffrn_orient_matrix_UB_22 0.1395696000 _diffrn_orient_matrix_UB_23 -0.0204255000 _diffrn_orient_matrix_UB_31 -0.0036647000 _diffrn_orient_matrix_UB_32 -0.0784356000 _diffrn_orient_matrix_UB_33 -0.0337715000 _diffrn_radiation_monochromator graphite _diffrn_radiation_probe x-ray _diffrn_radiation_type 'Mo K\a' _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0950 _diffrn_reflns_av_unetI/netI 0.0924 _diffrn_reflns_Laue_measured_fraction_full 0.221 _diffrn_reflns_Laue_measured_fraction_max 0.200 _diffrn_reflns_limit_h_max 7 _diffrn_reflns_limit_h_min -7 _diffrn_reflns_limit_k_max 5 _diffrn_reflns_limit_k_min -4 _diffrn_reflns_limit_l_max 22 _diffrn_reflns_limit_l_min -23 _diffrn_reflns_number 1000 _diffrn_reflns_point_group_measured_fraction_full 0.221 _diffrn_reflns_point_group_measured_fraction_max 0.200 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 26.243 _diffrn_reflns_theta_min 2.359 _diffrn_source 'fine-focus sealed X-ray tube' _diffrn_source_type 'Enhance (Mo) X-ray Source' _exptl_absorpt_coefficient_mu 0.117 _exptl_absorpt_correction_T_max 0.998 _exptl_absorpt_correction_T_min 0.997 _exptl_absorpt_correction_type gaussian _exptl_absorpt_process_details ; CrysAlisPro 1.171.42.49 (Rigaku Oxford Diffraction, 2022) Numerical absorption correction based on gaussian integration over a multifaceted crystal model (Absorb Angel (2004) J. Appl. Cryst. 37:486-492) ; _exptl_crystal_colour colourless _exptl_crystal_colour_primary colourless _exptl_crystal_density_diffrn 1.612 _exptl_crystal_description plate _exptl_crystal_F_000 640 _exptl_crystal_recrystallization_method ;Single crystals were grown by slow evaporation of a solution obtained dissolving 4,4'-ethane-1,2-diyldipyridine and succinic acid in 1:1 mol ratio in hot methanol 99.8%. ; _exptl_crystal_size_max 0.191 _exptl_crystal_size_mid 0.09 _exptl_crystal_size_min 0.019 _refine_diff_density_max 0.235 _refine_diff_density_min -0.336 _refine_diff_density_rms 0.069 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.037 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 46 _refine_ls_number_reflns 253 _refine_ls_number_restraints 4 _refine_ls_restrained_S_all 1.029 _refine_ls_R_factor_all 0.1379 _refine_ls_R_factor_gt 0.0904 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.1895P)^2^] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.2204 _refine_ls_wR_factor_ref 0.2711 _reflns_Friedel_coverage 0.000 _reflns_number_gt 159 _reflns_number_total 253 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file yc5049.cif _cod_data_source_block ETYSUC_373 _cod_database_code 1573525 _shelx_shelxl_version_number 2014/7 _chemical_oxdiff_formula 'C4O4H4, N2C12H12' _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_estimated_absorpt_t_max 0.998 _shelx_estimated_absorpt_t_min 0.978 _exptl_oxdiff_absorpt_process_details ; Gaussian integration over a grid of 16 x 16 x 16 points = 4096 total grid points Based upon method of Burnham (1966) ; _diffrn_ambient_pressure_su 20000 _diffrn_orient_matrix_axis[1] matrixX _diffrn_orient_matrix_axis[2] matrixY _diffrn_orient_matrix_axis[3] matrixZ _olex2_refinement_description ; 1. Fixed Uiso At 1.2 times of: All C(H) groups, All C(H,H) groups At 1.5 times of: All O(H) groups 2. Restrained distances N1-C2 1.337 with sigma of 0.02 N1-C6 1.337 with sigma of 0.02 O2A-C1A 1.214 with sigma of 0.02 O1A-C1A 1.308 with sigma of 0.02 3.a Secondary CH2 refined with riding coordinates: C2A(H2AA,H2AB), C7(H7A,H7B) 3.b Aromatic/amide H refined with riding coordinates: C2(H2), C3(H3), C5(H5), C6(H6) 3.c Idealised tetrahedral OH refined as rotating group: O1A(H1A) ; _shelx_res_file ; etysuc_380_1.res created by SHELXL-2014/7 TITL etysuc_380_1_a.res in I2/a REM Old TITL ETYSUC_380_1 in I2/a REM SHELXT solution in I2/a REM R1 0.259, Rweak 0.283, Alpha 0.113, Orientation as input REM Formula found by SHELXT: C6 N3 O2 CELL 0.71073 16.4597 4.3839 18.9424 90 114.298 90 ZERR 4 0.0631 0.0007 0.0206 0 0.274 0 LATT 2 SYMM 0.5-X,+Y,-Z SFAC C H N O UNIT 64 72 8 16 DFIX 1.337 N1 C2 DFIX 1.337 N1 C6 DFIX 1.214 O2A C1A DFIX 1.308 O1A C1A L.S. 100 0 0 PLAN 5 SIZE 0.019 0.09 0.191 TEMP 22(2) CONF BOND $H list 4 MORE -1 fmap 2 53 acta OMIT -2 1 17 OMIT -2 3 13 OMIT 0 0 12 OMIT 0 1 13 OMIT 1 3 10 REM REM REM WGHT 0.189500 FVAR 0.59081 N1 3 0.389590 0.473809 0.147132 11.00000 0.03608 C2 1 0.334156 0.636224 0.087336 11.00000 0.03262 AFIX 43 H2 2 0.273289 0.600703 0.069956 11.00000 -1.20000 AFIX 0 C3 1 0.361778 0.851674 0.050227 11.00000 0.03019 AFIX 43 H3 2 0.320974 0.972571 0.011487 11.00000 -1.20000 AFIX 0 C4 1 0.462058 0.888249 0.074346 11.00000 0.01747 C5 1 0.517870 0.719890 0.136481 11.00000 0.03465 AFIX 43 H5 2 0.579535 0.736087 0.155148 11.00000 -1.20000 AFIX 0 C6 1 0.477077 0.521882 0.170428 11.00000 0.01882 AFIX 43 H6 2 0.514816 0.412849 0.213593 11.00000 -1.20000 AFIX 0 C1A 1 0.252283 0.040500 0.176315 11.00000 0.02764 O1A 4 0.336178 0.099984 0.212419 11.00000 0.04629 AFIX 147 H1A 2 0.348959 0.245713 0.191809 11.00000 -1.50000 AFIX 0 C2A 1 0.221159 -0.200392 0.212137 11.00000 0.02774 AFIX 23 H2AA 2 0.166040 -0.131669 0.213965 11.00000 -1.20000 H2AB 2 0.206768 -0.376530 0.178170 11.00000 -1.20000 AFIX 0 O2A 4 0.206401 0.162441 0.115236 11.00000 0.03628 C7 1 0.492025 1.092894 0.030268 11.00000 0.02742 AFIX 23 H7A 2 0.546694 1.193360 0.064208 11.00000 -1.20000 H7B 2 0.447241 1.247879 0.005439 11.00000 -1.20000 AFIX 0 HKLF 4 REM etysuc_380_1_a.res in I2/a REM R1 = 0.0904 for 159 Fo > 4sig(Fo) and 0.1379 for all 253 data REM 46 parameters refined using 4 restraints END WGHT 0.1895 0.0000 REM Highest difference peak 0.235, deepest hole -0.336, 1-sigma level 0.069 Q1 1 0.5505 0.8181 0.0880 11.00000 0.05 0.24 Q2 1 0.2406 0.1801 0.2025 11.00000 0.05 0.23 Q3 1 0.3906 0.9342 0.0611 11.00000 0.05 0.19 Q4 1 0.2906 0.1983 0.2235 11.00000 0.05 0.19 Q5 1 0.2500 0.8400 0.0000 10.50000 0.05 0.18 ; _shelx_res_checksum 30332 _shelx_hkl_file ; 0 0 -2 328.96 26.06 0 0 4 2256.10 73.06 0 0 -4 2536.97 103.60 0 0 -6 215.28 36.65 0 0 -8 628.51 71.37 0 0 -10 -4.80 6.76 0 0 -12 17.12 17.73 0 1 1 1342.66 74.83 0 -1 -1 1296.77 66.13 0 -1 -1 1368.51 56.65 0 -1 1 1389.85 65.00 0 -1 1 1469.61 93.61 0 1 -1 1213.03 65.61 0 1 -1 1395.25 63.68 0 1 -1 1454.20 61.85 0 -1 -1 1302.30 67.66 0 -1 1 1274.48 73.20 0 1 1 1318.70 71.70 0 -1 -1 1168.86 57.95 0 1 1 1421.90 51.40 0 1 -1 1255.77 55.54 0 1 1 1508.42 64.26 0 -1 1 1213.68 49.69 0 -1 3 955.42 44.87 0 -1 3 886.01 63.65 0 -1 3 913.90 49.89 0 1 -3 874.29 54.05 0 1 -3 747.14 44.57 0 -1 -3 887.13 65.17 0 1 -3 874.24 61.65 0 1 3 1074.27 52.60 0 -1 5 674.71 61.00 0 1 -5 601.02 56.51 0 1 5 867.40 48.56 0 -1 -5 681.47 69.07 0 1 -5 643.92 44.68 0 1 -5 494.06 30.83 0 -1 5 644.85 35.13 0 1 -7 1804.36 81.99 0 1 7 2005.05 81.43 0 1 -7 1992.04 83.97 0 -1 7 1869.67 62.09 0 -1 -7 1934.34 138.95 0 1 -9 334.29 41.56 0 1 -9 412.81 39.60 0 -1 11 63.09 21.97 0 1 -11 25.34 12.14 0 1 -13 -0.40 12.14 0 2 0 153.47 27.43 0 -2 0 131.88 19.38 0 2 0 165.30 29.58 0 -2 0 137.41 23.21 0 2 0 142.20 31.69 0 -2 0 181.54 42.44 0 -2 0 140.06 30.59 0 -2 0 150.67 31.08 0 -2 2 121.04 30.42 0 2 2 137.52 25.41 0 2 -2 141.41 27.61 0 -2 -2 117.69 27.11 0 -2 2 137.12 26.18 0 2 -2 120.15 28.62 0 2 2 128.80 19.69 0 -2 2 109.84 19.05 0 -2 -2 125.34 24.00 0 -2 -2 91.24 27.05 0 -2 -2 137.48 26.48 0 2 2 74.92 23.95 0 2 4 -0.87 5.95 0 -2 4 -3.34 5.79 0 2 4 2.73 4.18 0 -2 4 -4.91 6.50 0 -2 4 8.63 7.03 0 2 -4 -5.17 10.50 0 -2 -4 -6.58 10.68 0 2 -4 -2.25 3.52 0 -2 -4 -5.59 10.30 0 -2 -4 6.26 12.04 0 2 -4 -12.16 16.47 0 -2 6 920.75 91.85 0 -2 -6 875.47 89.78 0 2 -6 846.13 78.27 0 -2 6 921.55 58.05 0 2 -6 769.74 81.63 0 2 6 901.16 72.22 0 -2 -6 670.87 72.47 0 -2 -8 101.25 35.71 0 -2 8 398.31 39.34 0 2 -8 345.40 51.21 0 2 8 416.25 52.75 0 2 -10 129.26 33.89 0 3 -1 414.84 66.13 0 3 -1 516.86 69.21 0 3 -1 518.92 69.08 0 -3 1 516.79 75.28 0 3 1 411.25 66.72 0 -3 -1 494.69 71.06 0 3 1 537.57 66.27 0 -3 1 520.24 70.52 0 -3 -1 526.49 70.88 0 3 1 684.43 78.23 0 -3 -3 136.03 34.93 0 3 -3 106.17 34.52 0 3 -3 116.60 34.90 0 -3 -3 155.62 43.89 0 -3 -3 156.26 32.05 0 -3 3 175.30 45.27 0 -3 3 173.35 40.12 0 -3 3 181.07 32.84 0 3 -3 168.77 37.29 0 3 3 253.48 49.60 0 3 -5 36.10 33.48 0 -3 -5 -7.62 21.46 0 -3 5 3.52 15.52 0 -3 -5 -7.22 13.32 0 3 5 7.73 11.11 0 -3 5 11.11 7.22 0 3 -7 26.86 18.26 0 -3 -7 4.17 12.88 0 -3 7 30.73 14.76 0 3 -9 0.49 12.17 0 -4 0 65.62 32.82 0 4 0 85.98 35.96 0 -4 0 74.37 36.71 0 -4 2 297.13 61.63 0 -4 2 239.67 60.13 0 4 2 324.19 63.14 0 -4 -2 291.57 64.71 0 4 -2 249.59 53.40 0 4 4 48.02 24.76 0 -4 -4 27.42 23.22 0 4 -4 41.63 25.49 0 4 -6 481.54 89.35 0 4 -8 50.88 30.17 1 0 -15 1.57 11.43 1 0 -13 -8.46 11.47 1 0 -11 4.77 11.53 1 0 -9 7.83 11.63 1 0 -7 4.30 6.96 -1 0 5 -9.77 6.80 1 0 -5 1.90 5.72 1 0 -5 18.70 10.11 -1 0 5 -5.61 8.65 -1 0 3 2.36 2.31 1 0 -3 -0.46 1.79 1 0 -3 0.98 1.76 1 0 -3 4.04 3.69 -1 0 3 -2.81 3.14 1 -1 -14 -33.93 33.59 1 1 -12 5.07 8.20 1 -1 -12 21.12 21.83 1 1 -10 213.21 31.11 1 -1 -10 286.70 33.21 1 -1 -10 234.52 48.76 1 1 -10 281.13 36.40 1 1 -8 607.33 45.17 -1 1 8 910.58 52.15 1 -1 -8 830.84 85.29 1 1 -8 665.31 69.41 1 1 -8 914.30 64.39 -1 -1 8 803.95 75.40 1 -1 -8 855.27 56.54 1 1 -6 1774.82 70.25 -1 -1 6 2864.44 75.68 -1 -1 6 2328.39 80.53 -1 -1 6 2054.78 115.24 -1 1 6 2505.46 85.73 1 1 -6 2454.04 103.75 1 -1 -6 2433.27 95.16 1 1 -6 2176.77 115.91 -1 -1 6 1648.04 84.27 -1 1 6 2054.62 123.60 1 -1 -6 2241.09 120.27 1 1 -6 1697.36 59.30 1 1 -4 2743.49 86.31 -1 -1 4 2985.01 179.78 -1 1 4 2509.97 103.27 -1 1 4 2757.24 88.96 1 1 -4 2863.63 134.67 1 -1 -4 2662.19 86.15 1 -1 -4 2663.40 112.20 -1 1 4 2765.00 124.77 -1 -1 4 2717.76 94.85 1 1 -4 2780.66 112.53 1 1 -4 2807.50 112.77 -1 -1 4 2742.86 131.65 1 -1 -4 2937.32 102.24 1 1 -2 3152.45 111.27 1 -1 -2 2933.12 95.59 1 -1 -2 3609.04 112.62 1 1 -2 3063.32 121.56 1 1 -2 3557.82 99.82 -1 -1 2 3020.07 135.66 1 -1 -2 3026.33 98.55 1 -1 -2 3846.10 96.48 -1 1 2 3336.70 111.26 1 1 -2 3443.96 112.84 -1 1 2 3725.18 110.25 1 -1 0 3.94 2.39 -1 1 0 2.67 2.33 1 1 0 4.39 3.07 1 -1 0 5.78 3.65 -1 1 0 -3.79 6.32 1 -1 2 399.89 28.62 -1 1 -2 512.41 36.15 -1 1 -4 1.68 2.84 -1 1 -6 72.29 13.83 1 -2 -11 538.33 89.26 1 -2 -9 665.89 75.62 1 2 -9 672.21 78.86 -1 2 9 750.08 67.15 1 -2 -9 717.35 90.51 -1 -2 9 732.21 88.35 1 2 -9 590.31 79.28 1 -2 -7 15.37 14.29 1 2 -7 19.95 15.08 1 2 -7 15.53 15.11 -1 2 7 27.87 15.36 -1 -2 7 25.63 19.41 1 2 -7 25.15 14.40 1 -2 -7 20.08 14.92 -1 -2 7 29.09 16.27 -1 2 5 137.48 31.36 1 2 -5 141.52 26.85 -1 2 5 122.93 25.23 1 -2 -5 138.25 30.03 1 2 -5 144.47 34.79 -1 -2 5 139.52 29.66 1 2 -5 103.86 28.73 -1 2 5 108.03 29.72 -1 -2 5 163.70 37.97 1 -2 -5 117.55 23.23 1 -2 -5 135.97 21.17 1 -2 -5 108.29 26.00 -1 -2 3 1805.14 128.61 1 -2 -3 1706.48 86.30 -1 2 3 2340.78 122.49 -1 -2 3 2213.94 173.13 1 2 -3 1617.67 116.06 -1 -2 3 1857.64 108.17 -1 2 3 1781.87 115.84 1 2 -3 2077.21 115.93 1 2 -3 1855.82 97.04 1 -2 -3 2085.70 118.42 1 -2 -3 1761.52 94.43 1 2 -3 1775.38 108.48 1 -2 -3 1754.36 96.46 -1 2 3 2119.17 92.81 -1 2 3 1851.52 120.81 -1 -2 1 482.24 39.21 1 -2 -1 628.50 60.21 1 2 -1 615.49 55.29 -1 -2 1 506.22 73.37 1 -2 -1 522.25 41.83 -1 -2 1 533.61 65.21 1 2 -1 537.45 42.14 1 -2 -1 608.42 59.75 -1 2 1 624.56 59.51 1 -2 -1 428.63 40.27 -1 2 1 522.51 51.83 -1 -2 1 565.78 59.59 1 2 -1 596.65 55.58 -1 2 1 529.93 56.24 -1 2 1 494.66 56.38 1 2 -1 427.98 57.63 1 -2 1 70.36 18.07 -1 2 -1 41.30 12.24 1 -2 1 50.35 16.24 -1 2 -1 54.87 17.02 -1 -2 -1 58.01 20.00 -1 2 -1 52.01 15.09 1 -2 1 54.46 14.98 1 2 1 61.39 18.08 -1 -2 -1 66.11 21.35 1 2 1 46.62 13.07 -1 -2 -1 44.09 13.82 -1 2 -3 87.92 24.74 1 2 3 57.48 18.81 1 -2 3 93.19 18.79 -1 -2 -3 6.96 6.01 -1 2 -5 65.66 20.49 1 -2 5 82.28 19.23 -1 2 -7 104.79 32.10 1 -2 7 130.56 26.09 -1 2 -9 158.19 35.46 -1 -3 16 27.53 24.36 -1 3 10 713.81 90.01 1 3 -10 664.30 97.71 1 3 -8 46.65 25.72 1 3 -8 73.50 33.15 1 -3 -8 81.55 31.76 -1 3 8 62.02 28.59 -1 -3 8 57.04 19.70 1 -3 -8 75.41 27.77 1 3 -6 59.40 23.58 1 -3 -6 70.83 29.25 -1 -3 6 97.41 32.38 -1 -3 6 73.13 27.79 1 3 -6 59.70 25.16 1 3 -6 67.05 28.77 1 -3 -6 78.77 26.63 -1 3 6 88.21 29.09 1 3 -4 36.35 21.75 1 3 -4 15.58 18.85 -1 3 4 25.83 23.11 1 -3 -4 9.25 8.18 1 3 -4 29.96 17.54 1 -3 -4 12.03 12.62 -1 3 4 46.39 25.54 -1 -3 4 16.66 10.00 -1 -3 4 21.81 14.49 1 3 -2 265.78 47.70 -1 3 2 223.08 51.84 -1 3 2 323.82 54.12 1 -3 -2 265.77 50.68 1 -3 -2 185.59 33.20 1 -3 -2 246.48 47.54 -1 3 2 177.15 43.59 1 -3 -2 219.08 33.78 -1 -3 2 257.42 51.63 -1 -3 2 230.99 48.07 1 3 -2 281.27 51.85 -1 -3 0 165.02 42.82 -1 3 0 131.93 33.54 1 -3 0 191.89 46.06 -1 3 0 132.75 38.51 1 -3 0 152.26 37.55 1 3 0 130.97 31.74 -1 -3 0 132.80 34.68 1 3 0 123.09 31.17 1 -3 0 157.42 29.83 -1 3 -2 436.35 67.35 1 3 2 389.35 55.67 -1 -3 -2 186.06 45.21 1 -3 2 524.40 53.26 -1 3 -2 447.28 61.07 -1 -3 -2 82.66 26.50 -1 -3 -2 463.29 58.40 1 -3 4 224.12 33.90 -1 3 -4 211.57 47.08 -1 3 -6 87.72 28.27 1 -3 6 101.11 21.89 -1 3 -8 168.33 46.16 -1 3 -10 13.78 21.26 1 -4 -7 -2.24 14.37 -1 4 7 -7.48 19.13 1 4 -5 431.72 72.54 -1 -4 5 489.78 91.34 1 -4 -5 566.84 88.45 -1 -4 5 521.94 79.53 -1 4 5 574.63 86.96 1 4 -3 40.46 27.93 1 -4 -3 64.45 32.00 1 4 -3 54.62 25.26 -1 -4 3 12.32 14.44 -1 4 3 50.72 26.16 -1 -4 3 41.91 28.36 -1 4 1 -45.28 30.62 -1 -4 1 -0.09 20.17 1 4 -1 -10.45 14.95 -1 4 1 -10.75 13.92 -1 -4 1 -16.15 23.16 -1 4 -1 8.50 10.27 -1 4 -3 5.23 11.02 -1 4 -5 82.54 41.29 -1 4 -7 203.09 56.31 -1 4 -9 -20.62 25.20 2 0 -18 -1.68 17.06 2 0 -16 87.10 36.98 2 0 -14 9.26 17.64 2 0 -12 1307.26 104.29 2 0 -10 1027.84 81.93 2 0 -8 6.67 6.62 -2 0 8 13.16 10.44 -2 0 8 5.49 5.97 2 0 -8 1.31 4.42 -2 0 6 161.43 23.66 -2 0 6 167.23 37.93 2 0 -6 173.11 35.29 2 0 -6 193.55 23.19 2 0 -6 161.89 22.98 -2 0 4 260.90 29.61 -2 0 4 213.27 31.61 2 0 -4 352.83 40.06 2 0 -4 347.53 27.29 2 -1 -17 -5.28 25.85 2 -1 -15 159.59 47.65 -2 -1 13 223.30 53.67 2 -1 -13 306.30 61.17 2 1 -13 219.17 34.61 -2 -1 11 265.73 47.54 -2 -1 11 193.92 45.54 2 1 -11 207.27 29.80 2 1 -11 232.96 44.85 2 -1 -11 259.06 51.35 2 1 -9 74.04 15.46 2 1 -9 113.73 29.77 2 -1 -9 96.79 26.52 -2 1 9 82.54 21.85 -2 -1 9 71.31 22.73 -2 -1 9 120.50 30.62 -2 -1 7 800.49 79.66 -2 1 7 779.13 55.10 -2 1 7 712.25 43.69 2 1 -7 947.75 50.91 -2 -1 7 878.55 115.12 2 -1 -7 835.92 47.35 2 1 -7 990.62 98.67 2 1 -7 787.61 67.54 2 -1 -7 775.24 68.81 -2 1 7 768.81 73.31 -2 -1 7 863.41 49.58 -2 -1 5 6285.02 289.76 -2 1 5 6120.97 163.60 2 1 -5 6825.42 149.63 2 -1 -5 5781.13 151.71 -2 -1 5 5764.96 215.69 2 1 -5 6826.15 236.70 2 -1 -5 5779.81 181.44 2 1 -5 6868.95 201.02 2 -1 -5 6309.99 186.36 -2 1 3 9361.70 279.49 -2 -1 3 8278.03 339.11 -2 1 3 9209.94 198.98 -2 -1 3 8504.13 266.31 2 -1 -3 8499.04 194.29 2 -1 -3 9999.00 196.40 2 1 -3 9551.09 227.04 2 -1 -3 9303.70 204.03 -2 1 1 53.32 11.42 2 -1 -1 31.37 8.94 2 -2 -14 6.58 13.01 2 2 -12 14.29 11.53 2 -2 -12 7.84 20.17 -2 -2 10 26.28 21.88 2 2 -10 6.60 11.47 2 -2 -10 0.65 9.04 -2 2 10 9.46 17.02 2 -2 -10 13.68 8.71 -2 -2 8 113.63 37.98 -2 -2 8 118.79 27.67 2 -2 -8 149.89 31.53 2 2 -8 121.53 25.84 -2 2 8 116.48 26.92 2 2 -8 137.49 38.67 -2 2 8 72.79 28.83 2 -2 -8 114.39 32.47 2 2 -6 0.06 8.34 2 -2 -6 10.61 10.47 -2 2 6 26.51 16.26 -2 -2 6 12.00 22.59 2 -2 -6 3.69 6.53 2 2 -6 16.16 9.54 -2 -2 6 15.20 11.68 -2 2 6 8.93 13.69 2 -2 -6 9.61 7.12 2 2 -6 6.89 11.65 -2 -2 6 15.84 20.87 -2 2 6 27.37 16.25 2 -2 -4 876.93 73.96 -2 2 4 609.85 63.39 -2 -2 4 720.01 106.27 -2 -2 4 774.76 89.18 2 -2 -4 555.79 47.12 2 2 -4 796.08 63.51 -2 2 4 643.68 61.37 -2 2 4 668.98 68.38 2 2 -4 704.92 74.03 -2 -2 4 721.72 69.20 2 2 -4 681.60 69.07 2 -2 -4 762.67 64.06 -2 2 2 985.63 77.90 -2 2 2 761.07 65.04 -2 2 2 912.74 88.72 2 2 -2 807.11 61.24 2 -2 -2 1057.02 68.85 2 2 -2 1033.83 74.89 2 -2 -2 994.85 60.48 -2 -2 2 690.11 83.54 -2 2 0 99.95 22.62 2 -2 0 118.38 20.95 -2 2 -2 590.28 56.42 2 -2 2 469.82 42.71 -2 2 -4 169.09 30.69 2 -2 4 99.03 18.88 -2 2 -6 75.67 22.00 2 -2 6 155.84 26.20 2 -3 -13 55.87 32.37 -2 -3 11 807.59 111.83 2 -3 -11 629.98 95.61 2 3 -11 715.18 105.33 -2 -3 9 1412.12 146.81 2 -3 -9 1730.15 138.09 -2 3 9 1483.70 124.00 2 3 -9 999.10 92.68 2 -3 -9 1475.12 131.56 2 3 -9 1250.71 130.34 -2 -3 7 198.64 43.67 2 -3 -7 227.24 45.17 -2 -3 7 158.40 49.66 2 3 -7 160.30 45.72 2 3 -7 155.69 37.18 -2 3 7 197.06 44.03 2 -3 -7 232.94 49.10 2 -3 -5 71.50 21.46 2 3 -5 137.42 41.67 -2 -3 5 88.75 38.31 -2 3 5 45.81 21.13 -2 3 5 123.72 50.60 2 -3 -5 72.45 22.49 2 3 -5 72.69 26.43 2 -3 -5 59.19 25.83 -2 3 5 63.01 25.19 -2 3 5 30.74 14.44 -2 -3 5 60.97 26.14 2 3 -3 3.87 13.06 -2 3 3 8.07 10.57 2 -3 -3 4.36 13.97 -2 -3 3 5.12 22.43 -2 -3 3 -7.84 16.37 2 3 -3 -5.38 8.36 2 -3 -3 3.56 8.47 -2 3 3 23.97 17.04 -2 3 3 14.09 18.89 -2 -3 3 -1.03 18.45 -2 3 3 16.67 16.68 -2 3 1 -10.91 11.62 2 -3 -1 7.12 9.03 -2 3 1 10.36 11.91 -2 3 -1 64.59 26.17 2 -3 1 43.62 15.67 -2 3 -1 42.86 15.39 -2 3 -3 -1.62 14.66 2 -3 3 5.42 10.84 2 -3 5 19.54 14.09 -2 3 -5 47.17 25.32 -2 3 -7 140.06 39.29 2 -3 7 171.44 29.31 2 4 -8 4.02 14.40 2 4 -8 -5.53 19.78 -2 -4 6 227.62 53.14 -2 -4 6 111.53 40.89 2 4 -6 111.08 39.86 2 4 -6 122.67 35.06 -2 4 4 11.43 11.19 -2 4 2 -15.90 16.19 2 -4 -2 1.03 14.65 -2 4 0 -9.42 10.27 2 -4 0 18.71 11.83 -2 4 -2 67.32 32.75 2 -4 2 73.84 24.86 -2 4 -4 335.57 72.09 2 -4 4 299.22 52.84 -2 4 -6 10.40 18.50 2 -4 6 28.01 20.58 -2 5 -3 13.05 16.92 -2 5 -5 -5.86 18.43 3 0 -19 19.96 22.82 -3 0 19 15.65 26.76 3 0 -17 0.21 15.78 -3 0 17 -1.82 33.23 3 0 -15 -4.80 9.03 -3 0 15 1.89 22.22 3 0 -13 13.31 15.19 3 0 -11 5.20 9.92 -3 0 11 5.75 5.89 3 0 -11 -0.34 7.21 -3 0 11 -7.71 10.52 -3 0 11 -11.75 9.85 3 0 -9 -8.94 10.44 3 0 -9 -10.43 11.87 -3 0 9 -8.17 8.60 -3 0 9 -20.27 24.49 3 0 -9 -2.80 1.99 -3 0 9 -7.99 21.77 3 0 -9 -19.51 21.13 -3 0 7 -2.96 7.66 3 0 -7 5.58 4.84 3 0 -7 -0.59 6.74 -3 0 7 2.59 12.25 3 0 -7 2.13 4.40 3 -1 -18 12.32 20.90 3 -1 -16 689.33 100.84 3 -1 -14 239.69 55.52 3 1 -14 166.84 30.42 3 -1 -12 265.93 50.91 -3 -1 12 251.87 48.95 3 1 -12 206.88 43.60 -3 1 12 277.58 55.46 3 1 -12 194.57 29.27 -3 -1 12 171.63 42.84 -3 1 10 -2.14 15.67 -3 -1 10 -9.32 6.82 -3 -1 10 -1.58 9.59 3 -1 -10 5.51 11.19 3 1 -10 13.35 18.12 3 1 -10 2.60 4.05 3 -1 -10 -1.28 4.03 3 1 -10 7.04 4.41 3 -1 -8 174.91 31.57 -3 1 8 204.29 27.26 3 1 -8 185.39 20.96 -3 -1 8 180.62 51.57 3 -1 -8 196.42 25.03 -3 -1 8 191.88 40.65 -3 -1 8 191.54 25.59 3 1 -8 203.79 48.42 3 1 -8 203.08 36.26 3 -1 -8 149.54 13.57 -3 -1 6 97.13 28.13 3 -1 -6 101.89 22.22 -3 1 6 101.43 17.05 -3 1 6 88.53 32.89 3 -1 -6 77.46 15.62 3 1 -6 73.67 25.25 3 -1 -6 117.90 25.95 3 1 -6 102.21 23.94 -3 1 4 5245.89 128.53 -3 1 4 4210.92 194.87 3 -1 -4 3649.70 114.54 3 -1 -4 6186.00 156.20 3 -2 -17 81.62 43.75 3 -2 -15 737.46 111.24 3 -2 -13 35.71 19.55 -3 -2 13 40.70 24.52 3 2 -13 60.82 30.87 3 -2 -11 -1.59 12.51 3 2 -11 27.51 26.27 -3 -2 11 9.76 19.04 -3 2 11 0.88 24.00 -3 -2 9 2397.53 178.64 -3 2 9 1956.32 126.15 -3 -2 9 3099.31 268.56 3 -2 -9 2309.61 109.07 3 2 -9 2717.04 130.29 3 2 -9 2467.86 192.97 3 2 -9 2306.26 148.75 3 -2 -9 2548.75 153.95 -3 2 9 1872.15 144.54 -3 -2 9 2467.14 128.05 -3 2 7 195.37 39.44 3 -2 -7 164.24 32.00 -3 2 7 189.70 38.12 -3 -2 7 151.84 48.25 -3 -2 7 203.42 37.48 3 2 -7 220.50 33.01 -3 2 7 230.68 63.28 3 -2 -7 150.21 25.12 3 2 -7 201.74 46.23 3 2 -7 189.57 38.88 -3 -2 7 157.85 44.78 -3 -2 5 3.84 14.28 3 -2 -5 26.53 13.40 -3 2 5 31.17 16.47 3 2 -5 12.74 8.68 -3 2 5 29.66 17.84 3 -2 -5 34.10 11.98 3 2 -5 8.92 9.48 -3 2 3 1103.91 79.46 3 -2 -3 999.18 66.31 3 -2 -3 1074.51 68.72 -3 2 1 1375.32 84.97 3 -2 -1 1350.01 79.58 -3 2 -1 142.80 25.37 3 -2 1 143.54 23.00 3 -3 -16 39.47 31.51 -3 3 16 -42.38 51.49 3 -3 -14 -32.69 26.14 3 -3 -12 -20.61 18.37 -3 -3 12 -21.02 23.68 3 3 -12 -19.75 19.90 3 -3 -10 63.51 24.87 -3 -3 10 76.56 44.15 3 3 -10 57.99 32.02 -3 -3 10 55.24 27.37 -3 3 10 16.00 36.06 3 3 -10 57.88 20.84 -3 -3 8 470.92 69.65 -3 -3 8 310.11 66.27 -3 3 8 403.25 66.42 -3 3 8 499.36 114.99 3 -3 -8 423.60 53.48 3 3 -8 529.33 70.84 3 3 -8 525.80 85.63 3 -3 -8 439.34 62.31 -3 3 8 338.98 64.99 3 3 -6 26.49 13.43 3 -3 -6 42.73 18.51 -3 3 6 -7.13 15.95 -3 -3 6 -6.48 45.61 -3 -3 6 21.00 15.00 3 3 -6 7.24 9.36 3 -3 -6 40.27 16.63 -3 -3 6 -20.87 23.50 -3 3 6 22.68 22.12 -3 3 6 6.36 10.22 -3 3 4 197.28 46.14 -3 3 4 164.48 52.62 3 -3 -4 252.36 38.91 -3 3 4 214.33 47.06 3 -3 -4 190.69 31.66 -3 3 2 39.04 18.51 -3 3 2 30.88 15.43 3 -3 -2 27.86 17.60 -3 3 0 219.99 46.80 3 -3 0 233.47 39.57 -3 3 -2 -13.33 13.44 3 -3 2 -6.30 11.11 -3 3 -4 61.99 25.70 3 -3 4 129.95 28.51 3 -4 -11 22.33 26.21 3 4 -11 -10.46 11.30 -3 4 11 29.90 51.22 -3 -4 11 20.12 31.42 -3 4 9 48.86 35.50 -3 4 5 -25.55 25.88 3 -4 -5 14.32 10.25 -3 4 3 15.94 16.57 3 -4 -3 -4.94 8.03 -3 4 1 20.87 26.91 3 -4 -1 -4.25 9.56 -3 4 1 15.49 11.45 -3 4 -1 17.35 21.37 3 -4 1 -2.71 14.12 -3 4 -3 79.23 34.43 3 -4 3 68.54 27.26 -3 5 0 -3.06 29.37 -3 5 -2 106.91 54.73 4 0 -20 344.55 72.27 -4 0 20 919.23 175.49 4 0 -18 79.15 28.85 -4 0 18 100.28 48.94 4 0 -16 234.82 47.52 -4 0 16 199.41 67.56 -4 0 14 276.16 74.52 4 0 -14 264.93 44.94 4 0 -14 219.80 38.60 4 0 -12 7.03 5.29 -4 0 12 5.22 7.87 4 0 -12 11.70 8.19 -4 0 12 -1.22 8.31 -4 0 12 -14.28 10.75 -4 0 10 108.26 24.37 4 0 -10 81.89 20.27 -4 0 10 132.09 44.56 4 0 -10 104.32 10.99 4 0 -10 141.55 41.58 -4 0 10 76.68 31.95 4 0 -10 122.47 25.24 4 0 -8 137.75 38.04 4 -1 -21 7.33 25.99 -4 1 21 78.30 72.02 4 -1 -19 155.17 55.39 -4 1 19 85.25 28.57 -4 1 17 448.09 116.35 4 -1 -17 370.55 71.56 4 -1 -15 21.29 16.43 -4 -1 15 9.17 11.75 4 1 -15 33.00 19.53 4 1 -15 -3.32 4.70 -4 1 15 -19.37 44.24 4 -1 -13 9.59 13.41 -4 -1 13 -22.71 24.49 4 1 -13 8.94 10.37 -4 1 13 16.62 20.87 -4 1 13 8.73 19.70 -4 1 11 17.78 18.28 -4 -1 11 31.05 14.39 4 -1 -11 -9.24 14.51 4 1 -11 12.27 15.49 -4 1 11 -1.53 15.72 -4 -1 11 41.98 45.59 4 -1 -11 3.06 5.38 4 1 -11 -16.65 16.63 -4 -1 9 18.40 15.41 -4 1 9 15.90 3.85 4 -1 -9 7.54 8.64 -4 -1 9 15.04 30.32 -4 1 9 17.90 7.72 -4 1 9 8.99 16.30 4 1 -9 6.51 3.14 -4 1 9 19.76 17.60 4 -1 -9 13.09 6.88 4 1 -9 6.01 7.91 4 -1 -9 18.79 10.43 4 1 -9 45.75 19.61 4 -1 -9 21.89 6.90 -4 1 7 2132.73 79.95 -4 1 7 1467.82 134.85 4 -1 -7 1708.13 77.06 4 -1 -7 2349.67 127.51 4 -1 -7 2455.13 112.04 4 -2 -20 50.95 44.76 -4 2 20 124.90 81.45 4 -2 -18 126.36 52.51 -4 2 18 57.15 59.66 4 -2 -16 18.97 15.33 4 2 -16 7.45 16.82 -4 2 16 35.11 26.13 -4 -2 14 1158.33 130.97 -4 2 14 1303.42 205.91 4 -2 -14 1189.66 125.15 4 2 -14 1123.89 127.86 -4 -2 12 751.59 101.91 -4 2 12 729.80 138.74 4 2 -12 817.84 101.93 4 -2 -12 785.60 91.77 -4 2 12 690.57 94.08 4 2 -10 179.70 44.09 -4 2 10 145.26 39.18 -4 -2 10 169.87 48.49 4 -2 -10 155.01 36.20 -4 2 10 159.12 35.95 -4 -2 10 245.14 84.92 -4 -2 10 171.85 37.19 -4 2 10 168.73 62.22 4 2 -10 162.28 28.67 4 -2 -10 183.47 28.73 4 2 -10 211.94 60.51 -4 2 8 1998.79 117.47 -4 2 8 1879.73 184.18 4 -2 -8 2123.96 109.52 4 -2 -8 2064.09 124.73 -4 2 6 167.08 49.03 -4 2 6 192.93 33.64 4 -2 -6 176.71 28.56 4 -2 -6 198.14 27.98 4 -2 -6 224.57 36.11 -4 2 4 114.90 24.98 4 -2 -4 127.09 24.31 4 -3 -17 -32.14 33.92 -4 3 17 -83.69 82.61 4 -3 -15 38.11 24.85 -4 -3 15 6.28 22.88 4 3 -15 45.30 27.00 -4 3 15 57.82 37.50 4 -3 -13 23.59 26.92 -4 -3 13 63.07 36.67 4 3 -13 32.30 34.74 -4 3 13 36.32 49.13 4 3 -11 106.25 40.71 -4 -3 11 90.91 40.45 4 -3 -11 118.67 38.30 -4 3 11 105.63 58.21 -4 3 11 114.81 41.66 4 -3 -9 222.16 44.17 -4 3 9 137.75 40.69 4 -3 -9 208.60 36.29 -4 3 9 184.59 66.16 -4 3 9 149.42 43.22 -4 3 7 11.69 13.30 4 -3 -7 -8.46 13.23 -4 3 7 0.35 16.19 4 -3 -7 -2.13 5.35 -4 3 7 12.03 22.80 -4 3 5 51.16 27.69 -4 3 5 30.04 18.71 4 -3 -5 48.41 16.39 -4 3 3 174.96 40.32 4 -3 -3 134.19 29.09 -4 3 1 369.45 55.06 4 -3 -1 423.79 50.20 4 -4 -14 22.88 19.51 -4 4 14 9.68 55.72 4 -4 -12 18.60 26.34 -4 4 12 19.55 64.16 4 -4 -10 2.66 16.48 -4 4 10 43.39 34.63 -4 4 8 52.17 26.39 4 -4 -8 -2.37 15.13 -4 4 6 6.47 12.66 4 -4 -6 13.77 15.00 -4 4 6 -3.28 11.37 -4 4 4 18.55 15.67 4 -4 -4 31.57 21.44 -4 4 4 57.38 32.08 -4 4 2 42.93 19.21 4 -4 -2 62.44 21.53 -4 4 2 2.39 9.17 -4 4 0 57.80 30.04 4 -4 0 40.30 18.21 -4 5 5 62.67 39.36 -4 5 3 8.22 27.22 5 0 -21 -11.33 16.80 5 0 -19 10.04 15.40 -5 0 19 -3.65 18.89 5 0 -17 -15.76 12.05 -5 0 17 52.22 41.20 -5 0 15 -2.65 19.69 5 0 -15 -5.58 5.52 5 0 -15 -7.17 8.62 5 0 -13 -11.77 14.53 -5 0 13 11.38 10.75 -5 0 13 -15.69 7.13 5 0 -13 -3.96 9.32 -5 0 13 -6.18 20.27 5 0 -13 18.29 19.82 -5 0 11 3.31 8.05 -5 0 11 0.32 24.59 5 0 -11 -4.60 14.29 5 0 -11 -1.61 8.80 5 -1 -22 -3.29 18.38 -5 1 22 56.55 55.05 5 -1 -20 58.14 27.71 -5 1 20 91.20 74.61 5 -1 -18 224.47 58.77 -5 1 18 145.48 72.66 -5 -1 16 61.72 29.78 5 -1 -16 48.12 27.11 5 1 -16 36.52 28.56 -5 1 16 6.71 19.94 -5 1 16 50.10 17.62 -5 1 14 143.06 38.19 5 1 -14 128.31 40.30 -5 -1 14 132.11 36.71 5 -1 -14 96.69 29.59 -5 1 14 87.45 47.20 -5 -1 12 -26.42 12.95 5 -1 -12 -5.52 8.15 -5 -1 12 21.84 21.05 5 -1 -12 0.60 2.97 5 1 -12 31.53 30.32 5 -1 -12 12.24 10.18 -5 1 12 -1.44 11.60 5 1 -12 -8.04 7.36 -5 1 10 78.67 34.22 5 -1 -10 103.93 27.04 -5 1 10 92.72 31.74 -5 1 10 102.66 19.71 5 -1 -10 83.61 16.17 5 -1 -10 129.91 37.65 5 -1 -10 106.77 18.26 5 -2 -21 -25.42 15.19 5 -2 -19 46.14 29.42 -5 2 19 -14.69 31.05 5 -2 -17 142.35 49.76 -5 -2 17 102.07 50.56 5 2 -17 120.94 50.24 -5 2 17 73.46 66.56 5 2 -15 -30.95 22.91 -5 -2 15 11.72 16.74 5 -2 -15 10.40 20.95 -5 2 15 7.73 16.08 -5 2 15 13.72 25.86 -5 -2 13 552.19 98.70 5 -2 -13 551.77 55.13 -5 -2 13 682.53 147.62 -5 2 13 537.51 119.52 5 2 -13 463.58 98.50 5 2 -13 337.40 66.69 5 -2 -13 464.62 72.21 -5 2 13 537.29 83.87 -5 2 11 3.32 12.97 5 -2 -11 22.08 14.76 5 -2 -11 31.62 13.14 -5 2 11 29.76 36.82 -5 2 9 149.18 53.37 5 -2 -9 210.36 42.24 -5 2 9 186.60 36.03 5 -2 -9 176.72 30.07 5 -2 -9 135.08 32.27 5 -2 -7 1828.79 95.20 5 -2 -7 1627.83 95.14 5 -3 -18 5.12 17.45 -5 3 18 73.22 62.24 5 -3 -16 15.54 21.37 -5 3 16 27.38 40.79 5 -3 -14 311.16 69.22 -5 3 14 447.38 137.71 5 -3 -12 3.49 22.29 5 -3 -12 28.72 15.18 -5 3 12 14.56 35.64 -5 3 12 8.35 13.85 -5 3 10 118.22 43.27 -5 3 10 78.98 53.32 5 -3 -10 119.42 35.33 -5 3 10 175.91 44.31 5 -3 -10 105.02 26.93 -5 3 8 45.89 27.65 -5 3 8 48.71 23.92 5 -3 -8 40.14 15.71 -5 3 6 76.02 26.99 5 -3 -6 68.55 22.20 -5 3 4 5.48 9.26 -5 4 15 12.34 31.40 5 -4 -15 84.87 43.75 -5 4 13 23.20 37.93 5 -4 -13 82.18 40.15 5 -4 -11 63.50 34.90 -5 4 9 -19.46 12.39 5 -4 -9 42.51 21.85 -5 4 9 13.49 22.88 -5 4 7 47.04 32.46 5 -4 -7 38.68 24.06 -5 4 7 17.89 11.82 -5 4 5 -12.67 18.33 5 -4 -5 -3.70 11.92 -5 4 5 29.03 27.01 -6 0 14 510.56 112.57 6 0 -14 393.89 87.95 6 0 -14 324.98 48.98 6 -1 -23 74.00 48.71 -6 1 21 131.42 90.56 6 -1 -21 31.23 38.81 -6 1 19 197.11 85.06 6 -1 -19 250.68 61.00 6 1 -19 181.70 52.33 -6 -1 17 873.85 108.98 6 1 -17 736.38 98.51 6 -1 -17 947.74 108.99 -6 1 17 864.76 121.84 -6 1 17 627.16 135.56 -6 1 15 141.60 42.16 -6 1 15 79.35 49.01 6 -1 -15 105.29 28.95 -6 -1 15 101.15 61.93 6 -1 -13 7.69 10.14 -6 1 13 25.75 31.27 6 -1 -13 -0.26 16.40 6 -2 -20 47.24 43.05 -6 2 20 93.20 71.27 6 -2 -18 -0.40 21.64 -6 2 18 -41.68 39.86 6 -2 -16 -19.36 34.95 -6 2 16 7.91 44.20 -6 2 16 -22.98 27.20 -6 2 14 45.25 31.89 6 -2 -14 -3.95 15.01 -6 2 14 -26.91 30.72 -6 2 12 49.89 43.78 6 -2 -12 50.19 24.44 6 -2 -12 58.97 18.10 -6 2 10 63.31 19.22 6 -2 -10 83.20 22.05 6 -2 -10 66.22 27.36 -6 3 17 79.80 87.79 6 -3 -17 68.90 37.85 -6 3 15 41.57 40.38 6 -3 -15 142.42 50.70 -6 3 15 194.98 63.71 -6 3 13 232.48 88.22 6 -3 -13 342.61 69.05 6 -3 -13 277.14 45.51 -6 3 13 236.62 60.71 -6 3 11 186.38 50.86 -6 3 11 120.82 37.55 6 -3 -11 137.31 29.48 -6 3 9 29.51 20.13 6 -3 -9 6.87 16.81 6 -4 -16 465.51 95.56 6 -4 -12 9.58 12.76 -6 4 12 54.87 39.35 6 -4 -10 55.81 23.33 -6 4 10 3.39 12.56 7 -2 -21 -6.11 16.91 7 -2 -19 116.12 44.14 7 -2 -17 18.53 12.67 -7 2 17 20.66 32.10 7 -2 -15 27.01 25.22 7 -3 -18 24.50 25.07 -7 3 16 -1.30 30.65 TITL ETYSUC_380_1 in I2/a REM I2/a (#15 in standard setting) CELL 0.71073 16.459720 4.383944 18.942383 90.0000 114.2980 90.0000 ZERR 3.00 0.063089 0.000716 0.020617 0.0000 0.2743 0.0000 LATT 2 SYMM -x+1/2, y,-z SFAC C H N O UNIT 48.00 48.00 6.00 12.00 SIZE 0.02 0.09 0.19 TREF HKLF 4 END _computing_structure_solution 'SHELXT 2014/4 (Sheldrick, 2014)' ; _shelx_hkl_checksum 44705 _hp_anvil_anvil_thickness 1.95 _hp_anvil_material diamond _hp_cell_type 'Diamond anvil cell' _hp_open_angle 30.00 _ins_header ; TITL ETYSUC_380_1 in I2/a REM I2/a (#15 in standard setting) CELL 0.71073 16.459720 4.383944 18.942383 90.0000 114.2980 90.0000 ZERR 3.00 0.063089 0.000716 0.020617 0.0000 0.2743 0.0000 LATT 2 SYMM -x+1/2, y,-z SFAC C H N O UNIT 48.00 48.00 6.00 12.00 SIZE 0.02 0.09 0.19 TREF HKLF 4 END ; _olex2_exptl_crystal_mounting_method ;Single crystal grown at ambient conditions was mounted in Merrill-Bassett diamond anvil cell and compressed to 3.73(2) GPa. Daphne oil 7575 was used as hydrostatic medium. ; _olex2_submission_special_instructions 'No special instructions were received' _oxdiff_exptl_absorpt_empirical_details ; Empirical correction (ABSPACK) includes: - Absorption correction using spherical harmonics - Frame scaling ; _oxdiff_exptl_absorpt_empirical_full_max 2.902 _oxdiff_exptl_absorpt_empirical_full_min 0.405 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x+1/2, y, -z' 'x+1/2, y+1/2, z+1/2' '-x+1, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y, z' '-x+1/2, -y+1/2, -z+1/2' 'x, -y+1/2, z+1/2' loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_site_symmetry_order _atom_site_calc_flag _atom_site_refinement_flags_posn _atom_site_refinement_flags_adp _atom_site_refinement_flags_occupancy _atom_site_disorder_assembly _atom_site_disorder_group N1 N 0.3896(17) 0.474(2) 0.1471(8) 0.036(4) Uiso 1 1 d D . . . . C2 C 0.3342(19) 0.636(2) 0.0873(7) 0.033(3) Uiso 1 1 d D . . . . H2 H 0.2733 0.6007 0.0700 0.039 Uiso 1 1 calc R U . . . C3 C 0.362(3) 0.852(2) 0.0502(9) 0.030(5) Uiso 1 1 d . . . . . H3 H 0.3210 0.9726 0.0115 0.036 Uiso 1 1 calc R U . . . C4 C 0.462(3) 0.888(2) 0.0743(9) 0.017(4) Uiso 1 1 d . . . . . C5 C 0.518(2) 0.720(2) 0.1365(8) 0.035(4) Uiso 1 1 d . . . . . H5 H 0.5795 0.7361 0.1551 0.042 Uiso 1 1 calc R U . . . C6 C 0.4771(18) 0.522(2) 0.1704(9) 0.019(4) Uiso 1 1 d D . . . . H6 H 0.5148 0.4128 0.2136 0.023 Uiso 1 1 calc R U . . . C1A C 0.2523(17) 0.041(3) 0.1763(9) 0.028(4) Uiso 1 1 d D . . . . O1A O 0.3362(17) 0.1000(19) 0.2124(7) 0.046(4) Uiso 1 1 d D . . . . H1A H 0.3490 0.2457 0.1918 0.069 Uiso 1 1 calc R U . . . C2A C 0.221(2) -0.2004(19) 0.2121(8) 0.028(3) Uiso 1 1 d . . . . . H2AA H 0.1660 -0.1317 0.2140 0.033 Uiso 1 1 calc R U . . . H2AB H 0.2068 -0.3765 0.1782 0.033 Uiso 1 1 calc R U . . . O2A O 0.2064(16) 0.1624(15) 0.1152(6) 0.036(3) Uiso 1 1 d D . . . . C7 C 0.492(2) 1.093(2) 0.0303(8) 0.027(3) Uiso 1 1 d . . . . . H7A H 0.5467 1.1934 0.0642 0.033 Uiso 1 1 calc R U . . . H7B H 0.4472 1.2479 0.0054 0.033 Uiso 1 1 calc R U . . . loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _axis.id _axis.type _axis.equipment _axis.parity _axis.depends_on _axis.zero _axis.vector[1] _axis.vector[2] _axis.vector[3] source . source . . . 0.99999988 0.00000000 -0.00049271 omega rotation goniometer -1 . -0.71463000 0.00000000 0.00000000 1.00000000 kappa rotation goniometer -1 omega -0.16291000 -0.76618634 0.00000000 0.64261846 phi rotation goniometer -1 kappa . 0.00013422 0.00000000 0.99999999 theta rotation goniometer -1 . -0.64400000 0.00000000 0.00000000 1.00000000 matrixX general general . phi . 1.00000000 0.00000000 0.00000000 matrixY general general . phi . 0.00000000 1.00000000 0.00000000 matrixZ general general . phi . 0.00000000 0.00000000 1.00000000 dacX translation general . phi . 0.00000000 1.00000000 0.00000000 dacY translation general . phi . -1.00000000 0.00000000 0.00000000 dacZ translation general . phi . 0.00000000 0.00000000 1.00000000 loop_ _exptl_crystal_face_index_h _exptl_crystal_face_index_k _exptl_crystal_face_index_l _exptl_crystal_face_perp_dist 8 1 -26 0.0701 -8 -1 26 0.0181 6 -4 -21 0.0896 -6 -5 17 0.0461 -8 3 25 0.0458 5 5 -17 0.0734 22 0 -1 0.0010 -21 0 1 0.0170 loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C2 N1 C6 117.7(15) . . ? N1 C2 H2 118.2 . . ? N1 C2 C3 124(3) . . ? C3 C2 H2 118.2 . . ? C2 C3 H3 121.1 . . ? C2 C3 C4 118(2) . . ? C4 C3 H3 121.1 . . ? C5 C4 C3 117(2) . . ? C5 C4 C7 124(3) . . ? C7 C4 C3 118(2) . . ? C4 C5 H5 121.7 . . ? C4 C5 C6 117(3) . . ? C6 C5 H5 121.7 . . ? N1 C6 C5 126.8(17) . . ? N1 C6 H6 116.6 . . ? C5 C6 H6 116.6 . . ? O1A C1A C2A 113.8(15) . . ? O2A C1A O1A 121.7(17) . . ? O2A C1A C2A 124(2) . . ? C1A O1A H1A 109.5 . . ? C1A C2A H2AA 107.7 . . ? C1A C2A H2AB 107.7 . . ? C2A C2A C1A 118(3) 7_545 . ? C2A C2A H2AA 107.7 7_545 . ? C2A C2A H2AB 107.7 7_545 . ? H2AA C2A H2AB 107.1 . . ? C4 C7 C7 108.1(11) . 5_675 ? C4 C7 H7A 110.1 . . ? C4 C7 H7B 110.1 . . ? C7 C7 H7A 110.1 5_675 . ? C7 C7 H7B 110.1 5_675 . ? H7A C7 H7B 108.4 . . ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag N1 C2 1.331(18) . ? N1 C6 1.34(2) . ? C2 H2 0.9300 . ? C2 C3 1.36(3) . ? C3 H3 0.9300 . ? C3 C4 1.53(6) . ? C4 C5 1.37(3) . ? C4 C7 1.44(2) . ? C5 H5 0.9300 . ? C5 C6 1.40(3) . ? C6 H6 0.9300 . ? C1A O1A 1.29(2) . ? C1A C2A 1.46(2) . ? C1A O2A 1.215(16) . ? O1A H1A 0.8200 . ? C2A C2A 1.42(4) 7_545 ? C2A H2AA 0.9700 . ? C2A H2AB 0.9700 . ? C7 C7 1.51(2) 5_675 ? C7 H7A 0.9700 . ? C7 H7B 0.9700 . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag N1 C2 C3 C4 5.4(18) . . . . ? C2 N1 C6 C5 -3(2) . . . . ? C2 C3 C4 C5 -5.6(19) . . . . ? C2 C3 C4 C7 173.7(8) . . . . ? C3 C4 C5 C6 2.0(15) . . . . ? C3 C4 C7 C7 -95(3) . . . 5_675 ? C4 C5 C6 N1 2.1(17) . . . . ? C5 C4 C7 C7 84(3) . . . 5_675 ? C6 N1 C2 C3 -1.5(19) . . . . ? O1A C1A C2A C2A 12(3) . . . 7_545 ? O2A C1A C2A C2A -173.1(18) . . . 7_545 ? C7 C4 C5 C6 -177.2(9) . . . . ? loop_ _exptl_oxdiff_crystal_face_indexfrac_h _exptl_oxdiff_crystal_face_indexfrac_k _exptl_oxdiff_crystal_face_indexfrac_l _exptl_oxdiff_crystal_face_x _exptl_oxdiff_crystal_face_y _exptl_oxdiff_crystal_face_z 8.2152 1.2290 -26.2250 -0.1160 0.6405 0.7592 -8.2367 -0.9420 26.4422 0.1093 -0.6047 -0.7889 5.6677 -3.9538 -20.5504 0.0356 -0.1781 0.9834 -5.8510 -4.8625 16.6373 0.1786 -0.9710 -0.1590 -7.6686 3.2216 25.1235 0.0208 -0.0013 -1.0730 5.0510 4.7890 -16.8713 -0.1373 0.9720 0.1756 22.3074 -0.4837 -1.1425 -1.0219 -0.2253 -0.0052 -20.7079 0.4187 1.3735 0.9457 0.1985 -0.0033 loop_ _hkl_oxdiff_h _hkl_oxdiff_k _hkl_oxdiff_l _hkl_oxdiff_f2 _hkl_oxdiff_sig _hkl_oxdiff_ba 0 0 -2 4911.94 389.072 7 0 0 4 33687.4 1090.90 13 0 0 -4 37881.2 1546.97 7 0 0 -6 3214.45 547.244 7 0 0 -8 9384.74 1065.66 7 0 0 -10 -71.7450 100.986 7 0 0 -12 255.626 264.684 7 0 1 1 20048.2 1117.28 14 0 -1 -1 19362.9 987.365 13 0 -1 -1 20434.2 845.910 9 0 -1 1 20752.8 970.540 1 0 -1 1 21943.8 1397.69 2 0 1 -1 18112.6 979.670 10 0 1 -1 20833.4 950.815 4 0 1 -1 21713.6 923.547 14 0 -1 -1 19445.5 1010.24 1 0 -1 1 19030.2 1092.98 13 0 1 1 19690.4 1070.66 10 0 -1 -1 17453.0 865.266 7 0 1 1 21231.3 767.465 4 0 1 -1 18750.7 829.297 5 0 1 1 22523.2 959.475 5 0 -1 1 18122.3 741.932 9 0 -1 3 14266.0 669.947 9 0 -1 3 13229.6 950.358 13 0 -1 3 13646.1 744.952 1 0 1 -3 13054.7 807.083 10 0 1 -3 11156.1 665.568 5 0 -1 -3 13246.3 973.123 7 0 1 -3 13053.9 920.539 4 0 1 3 16040.7 785.450 5 0 -1 5 10074.5 910.849 13 0 1 -5 8974.19 843.737 4 0 1 5 12951.8 725.069 5 0 -1 -5 10175.5 1031.36 7 0 1 -5 9614.86 667.110 10 0 1 -5 7377.10 460.330 7 0 -1 5 9628.76 524.539 9 0 1 -7 26942.1 1224.22 7 0 1 7 29938.8 1215.94 5 0 1 -7 29744.5 1253.84 10 0 -1 7 27917.3 927.042 9 0 -1 -7 28882.9 2074.70 7 0 1 -9 4991.47 620.618 7 0 1 -9 6164.02 591.333 10 0 -1 11 942.026 328.019 13 0 1 -11 378.402 181.276 7 0 1 -13 -6.04578 181.214 7 0 2 0 2291.53 409.554 5 0 -2 0 1969.23 289.371 7 0 2 0 2468.27 441.655 4 0 -2 0 2051.71 346.501 9 0 2 0 2123.27 473.201 10 0 -2 0 2710.66 633.771 2 0 -2 0 2091.35 456.763 13 0 -2 0 2249.75 464.133 1 0 -2 2 1807.38 454.149 13 0 2 2 2053.47 379.375 5 0 2 -2 2111.49 412.210 5 0 -2 -2 1757.35 404.843 13 0 -2 2 2047.49 390.967 1 0 2 -2 1794.06 427.386 10 0 2 2 1923.15 294.011 4 0 -2 2 1640.05 284.460 9 0 -2 -2 1871.60 358.424 7 0 -2 -2 1362.38 403.920 1 0 -2 -2 2052.75 395.378 2 0 2 2 1118.61 357.645 10 0 2 4 -13.0288 88.8645 5 0 -2 4 -49.9106 86.4335 9 0 2 4 40.7536 62.4057 4 0 -2 4 -73.2780 97.1279 1 0 -2 4 128.787 104.994 13 0 2 -4 -77.2715 156.767 10 0 -2 -4 -98.3223 159.493 7 0 2 -4 -33.5262 52.6122 5 0 -2 -4 -83.4859 153.841 13 0 -2 -4 93.5317 179.749 1 0 2 -4 -181.513 245.886 4 0 -2 6 13748.4 1371.45 13 0 -2 -6 13072.3 1340.53 7 0 2 -6 12634.2 1168.63 10 0 -2 6 13760.3 866.744 9 0 2 -6 11493.5 1218.91 4 0 2 6 13455.9 1078.38 5 0 -2 -6 10017.2 1082.08 1 0 -2 -8 1511.86 533.267 7 0 -2 8 5947.46 587.420 9 0 2 -8 5157.35 764.682 10 0 2 8 6215.33 787.660 5 0 2 -10 1930.14 505.974 10 0 3 -1 6194.32 987.420 10 0 3 -1 7717.65 1033.45 4 0 3 -1 7748.33 1031.53 5 0 -3 1 7716.56 1123.99 13 0 3 1 6140.73 996.262 10 0 -3 -1 7386.60 1061.04 1 0 3 1 8026.85 989.555 4 0 -3 1 7768.05 1053.02 1 0 -3 -1 7861.41 1058.36 13 0 3 1 10219.7 1168.15 5 0 -3 -3 2031.16 521.625 13 0 3 -3 1585.27 515.485 10 0 3 -3 1741.05 521.055 4 0 -3 -3 2323.61 655.417 1 0 -3 -3 2333.18 478.547 7 0 -3 3 2617.57 675.951 13 0 -3 3 2588.41 599.046 1 0 -3 3 2703.72 490.347 9 0 3 -3 2520.05 556.799 5 0 3 3 3784.94 740.604 5 0 3 -5 539.105 499.984 10 0 -3 -5 -113.739 320.500 1 0 -3 5 52.5373 231.807 13 0 -3 -5 -107.824 198.920 7 0 3 5 115.461 165.883 5 0 -3 5 165.886 107.881 9 0 3 -7 401.002 272.714 10 0 -3 -7 62.2709 192.331 7 0 -3 7 458.780 220.323 9 0 3 -9 7.38970 181.662 10 0 -4 0 979.768 489.998 13 0 4 0 1283.76 536.932 5 0 -4 0 1110.45 548.089 1 0 -4 2 4436.71 920.224 1 0 -4 2 3578.75 897.913 13 0 4 2 4840.73 942.852 5 0 -4 -2 4353.68 966.293 1 0 4 -2 3726.78 797.311 5 0 4 4 717.027 369.685 5 0 -4 -4 409.422 346.765 1 0 4 -4 621.579 380.637 10 0 4 -6 7190.27 1334.22 10 0 4 -8 759.691 450.432 10 1 0 -15 23.4747 170.628 7 1 0 -13 -126.271 171.196 7 1 0 -11 71.1892 172.148 7 1 0 -9 116.876 173.672 7 1 0 -7 64.2465 103.992 7 -1 0 5 -145.907 101.516 13 1 0 -5 28.3383 85.4031 7 1 0 -5 279.167 150.969 4 -1 0 5 -83.7925 129.106 14 -1 0 3 35.2581 34.4370 13 1 0 -3 -6.86285 26.7865 7 1 0 -3 14.6795 26.3395 4 1 0 -3 60.3368 55.0728 8 -1 0 3 -41.9789 46.8611 2 1 -1 -14 -506.575 501.629 7 1 1 -12 75.6764 122.506 7 1 -1 -12 315.298 325.981 7 1 1 -10 3183.60 464.591 7 1 -1 -10 4280.94 495.923 1 1 -1 -10 3501.71 728.046 7 1 1 -10 4197.68 543.548 10 1 1 -8 9068.40 674.462 7 -1 1 8 13596.5 778.699 5 1 -1 -8 12405.8 1273.52 7 1 1 -8 9934.26 1036.39 4 1 1 -8 13652.0 961.386 10 -1 -1 8 12004.4 1125.85 13 1 -1 -8 12770.7 844.196 1 1 1 -6 26501.0 1048.90 5 -1 -1 6 42771.0 1130.09 9 -1 -1 6 34766.8 1202.41 1 -1 -1 6 30681.3 1720.76 13 -1 1 6 37410.7 1280.05 5 1 1 -6 36642.9 1549.11 10 1 -1 -6 36332.9 1420.86 1 1 1 -6 32502.9 1730.80 4 -1 -1 6 24608.1 1258.32 3 -1 1 6 30678.9 1845.52 14 1 -1 -6 33463.3 1795.90 7 1 1 -6 25344.4 885.424 7 1 1 -4 40964.9 1288.74 5 -1 -1 4 44571.3 2684.45 2 -1 1 4 37478.1 1542.03 10 -1 1 4 41170.2 1328.31 5 1 1 -4 42758.9 2010.78 8 1 -1 -4 39751.0 1286.38 9 1 -1 -4 39769.0 1675.36 7 -1 1 4 41286.2 1863.01 14 -1 -1 4 40580.7 1416.26 1 1 1 -4 41519.9 1680.32 4 1 1 -4 41920.8 1683.81 10 -1 -1 4 40955.5 1965.83 13 1 -1 -4 43859.1 1526.57 1 1 1 -2 47071.4 1661.48 8 1 -1 -2 43796.5 1427.35 9 1 -1 -2 53889.1 1681.58 1 1 1 -2 45740.6 1815.06 10 1 1 -2 53124.3 1490.51 5 -1 -1 2 45094.8 2025.63 13 1 -1 -2 45188.3 1471.59 7 1 -1 -2 57428.8 1440.55 13 -1 1 2 49822.6 1661.32 10 1 1 -2 51424.1 1684.90 4 -1 1 2 55623.3 1646.27 5 1 -1 0 58.8978 35.7052 1 -1 1 0 39.8005 34.7623 10 1 1 0 65.5556 45.7790 5 1 -1 0 86.3562 54.4518 9 -1 1 0 -56.6547 94.3611 5 1 -1 2 5971.02 427.286 9 -1 1 -2 7651.08 539.733 10 -1 1 -4 25.1247 42.3445 10 -1 1 -6 1079.45 206.543 10 1 -2 -11 8038.16 1332.83 7 1 -2 -9 9942.80 1129.11 1 1 2 -9 10037.3 1177.56 10 -1 2 9 11199.9 1002.60 5 1 -2 -9 10711.3 1351.40 7 -1 -2 9 10933.1 1319.28 13 1 2 -9 8814.36 1183.75 4 1 -2 -7 229.531 213.373 7 1 2 -7 297.944 225.188 10 1 2 -7 231.868 225.571 4 -1 2 7 416.081 229.371 5 -1 -2 7 382.754 289.858 13 1 2 -7 375.543 214.959 5 1 -2 -7 299.838 222.762 1 -1 -2 7 434.342 242.944 1 -1 2 5 2052.81 468.220 10 1 2 -5 2113.09 400.896 5 -1 2 5 1835.50 376.677 5 1 -2 -5 2064.25 448.404 1 1 2 -5 2157.14 519.499 4 -1 -2 5 2083.21 442.825 1 1 2 -5 1550.86 429.042 10 -1 2 5 1613.06 443.809 14 -1 -2 5 2444.30 566.896 13 1 -2 -5 1755.21 346.934 9 1 -2 -5 2030.27 316.125 13 1 -2 -5 1617.00 388.184 7 -1 -2 3 26953.8 1920.32 13 1 -2 -3 25480.7 1288.56 9 -1 2 3 34951.8 1828.92 5 -1 -2 3 33057.9 2585.13 2 1 2 -3 24154.6 1732.95 10 -1 -2 3 27737.7 1615.18 1 -1 2 3 26606.3 1729.69 10 1 2 -3 31016.3 1730.99 8 1 2 -3 27710.5 1448.99 5 1 -2 -3 31143.0 1768.15 1 1 -2 -3 26302.5 1410.02 13 1 2 -3 26509.4 1619.73 4 1 -2 -3 26195.5 1440.36 7 -1 2 3 31642.8 1385.83 4 -1 2 3 27646.4 1803.84 14 -1 -2 1 7200.59 585.540 7 1 -2 -1 9384.64 899.101 1 1 2 -1 9190.38 825.602 5 -1 -2 1 7558.66 1095.58 2 1 -2 -1 7798.13 624.556 7 -1 -2 1 7967.72 973.728 13 1 2 -1 8025.07 629.170 8 1 -2 -1 9084.67 892.116 13 -1 2 1 9325.73 888.552 5 1 -2 -1 6400.14 601.291 9 -1 2 1 7801.90 773.835 4 -1 -2 1 8448.02 889.720 1 1 2 -1 8908.98 829.963 4 -1 2 1 7912.79 839.816 14 -1 2 1 7386.06 841.881 10 1 2 -1 6390.44 860.470 10 1 -2 1 1050.66 269.794 1 -1 2 -1 616.729 182.696 10 1 -2 1 751.820 242.483 13 -1 2 -1 819.297 254.166 5 -1 -2 -1 866.151 298.649 1 -1 2 -1 776.671 225.294 14 1 -2 1 813.166 223.684 9 1 2 1 916.604 269.983 5 -1 -2 -1 987.129 318.776 13 1 2 1 696.138 195.215 4 -1 -2 -1 658.402 206.329 7 -1 2 -3 1312.86 369.362 10 1 2 3 858.286 280.911 5 1 -2 3 1391.51 280.517 9 -1 -2 -3 103.977 89.7242 7 -1 2 -5 980.449 305.924 10 1 -2 5 1228.52 287.153 9 -1 2 -7 1564.73 479.274 10 1 -2 7 1949.48 389.562 9 -1 2 -9 2362.10 529.455 10 -1 -3 16 411.064 363.705 13 -1 3 10 10658.4 1344.04 5 1 3 -10 9919.07 1458.93 10 1 3 -8 696.631 384.029 4 1 3 -8 1097.41 494.989 10 1 -3 -8 1217.70 474.270 7 -1 3 8 926.000 426.862 5 -1 -3 8 851.765 294.144 13 1 -3 -8 1125.99 414.682 1 1 3 -6 886.933 352.076 5 1 -3 -6 1057.62 436.747 1 -1 -3 6 1454.49 483.446 1 -1 -3 6 1091.89 414.914 13 1 3 -6 891.449 375.727 4 1 3 -6 1001.19 429.521 10 1 -3 -6 1176.17 397.573 7 -1 3 6 1317.06 434.336 5 1 3 -4 542.805 324.838 10 1 3 -4 232.632 281.508 4 -1 3 4 385.734 345.026 10 1 -3 -4 138.048 122.089 1 1 3 -4 447.323 261.898 5 1 -3 -4 179.595 188.400 7 -1 3 4 692.636 381.317 5 -1 -3 4 248.834 149.369 1 -1 -3 4 325.732 216.337 13 1 3 -2 3968.60 712.314 4 -1 3 2 3331.03 774.044 3 -1 3 2 4835.12 808.070 5 1 -3 -2 3968.43 756.746 13 1 -3 -2 2771.21 495.692 9 1 -3 -2 3680.40 709.877 1 -1 3 2 2645.15 650.802 10 1 -3 -2 3271.18 504.440 7 -1 -3 2 3843.72 770.933 1 -1 -3 2 3449.07 717.747 13 1 3 -2 4199.82 774.218 5 -1 -3 0 2463.97 639.368 13 -1 3 0 1970.01 500.802 5 1 -3 0 2865.17 687.822 13 -1 3 0 1982.19 575.050 10 1 -3 0 2273.49 560.711 1 1 3 0 1955.58 473.960 5 -1 -3 0 1982.92 517.859 1 1 3 0 1837.93 465.431 4 1 -3 0 2350.49 445.354 9 -1 3 -2 6515.39 1005.66 10 1 3 2 5813.71 831.320 5 -1 -3 -2 2778.14 675.102 1 1 -3 2 7830.12 795.335 9 -1 3 -2 6678.66 911.897 5 -1 -3 -2 1234.25 395.669 13 -1 -3 -2 6917.64 871.971 7 1 -3 4 3346.42 506.238 9 -1 3 -4 3159.14 702.943 10 -1 3 -6 1309.83 422.062 10 1 -3 6 1509.79 326.907 9 -1 3 -8 2513.50 689.180 10 -1 3 -10 205.821 317.385 10 1 -4 -7 -33.4721 214.600 1 -1 4 7 -111.725 285.678 5 1 4 -5 6446.34 1083.10 5 -1 -4 5 7313.26 1363.85 13 1 -4 -5 8463.90 1320.78 1 -1 -4 5 7793.48 1187.53 1 -1 4 5 8580.24 1298.41 5 1 4 -3 604.088 417.058 4 1 -4 -3 962.397 477.827 1 1 4 -3 815.619 377.135 5 -1 -4 3 183.890 215.641 13 -1 4 3 757.305 390.542 5 -1 -4 3 625.735 423.433 1 -1 4 1 -676.096 457.181 10 -1 -4 1 -1.32272 301.101 13 1 4 -1 -156.092 223.161 5 -1 4 1 -160.519 207.866 5 -1 -4 1 -241.195 345.849 1 -1 4 -1 126.868 153.376 10 -1 4 -3 78.0349 164.524 10 -1 4 -5 1232.41 616.489 10 -1 4 -7 3032.52 840.872 10 -1 4 -9 -307.918 376.325 10 2 0 -18 -25.1439 254.749 7 2 0 -16 1300.54 552.197 7 2 0 -14 138.332 263.376 7 2 0 -12 19519.6 1557.25 7 2 0 -10 15347.4 1223.41 7 2 0 -8 99.6657 98.8069 4 -2 0 8 196.491 155.884 13 -2 0 8 82.0068 89.0858 14 2 0 -8 19.5382 66.0224 7 -2 0 6 2410.47 353.258 13 -2 0 6 2496.97 566.413 2 2 0 -6 2584.84 526.924 8 2 0 -6 2890.00 346.252 4 2 0 -6 2417.32 343.145 7 -2 0 4 3895.69 442.118 13 -2 0 4 3184.51 471.997 3 2 0 -4 5268.42 598.179 8 2 0 -4 5189.23 407.555 4 2 -1 -17 -78.8599 385.944 7 2 -1 -15 2382.94 711.479 7 -2 -1 13 3334.28 801.353 3 2 -1 -13 4573.62 913.319 7 2 1 -13 3272.53 516.812 7 -2 -1 11 3967.75 709.892 13 -2 -1 11 2895.54 679.953 3 2 1 -11 3094.91 444.995 7 2 1 -11 3478.49 669.691 4 2 -1 -11 3868.14 766.791 7 2 1 -9 1105.59 230.808 7 2 1 -9 1698.21 444.447 4 2 -1 -9 1445.17 396.009 7 -2 1 9 1232.43 326.220 14 -2 -1 9 1064.85 339.452 3 -2 -1 9 1799.27 457.179 13 -2 -1 7 11952.7 1189.49 13 -2 1 7 11633.8 822.678 10 -2 1 7 10635.1 652.351 5 2 1 -7 14151.5 760.181 5 -2 -1 7 13118.2 1718.92 2 2 -1 -7 12481.7 706.949 9 2 1 -7 14791.6 1473.33 8 2 1 -7 11760.3 1008.56 4 2 -1 -7 11575.7 1027.44 7 -2 1 7 11479.6 1094.65 14 -2 -1 7 12892.1 740.370 1 -2 -1 5 93846.0 4326.55 2 -2 1 5 91396.4 2442.88 10 2 1 -5 101915. 2234.19 5 2 -1 -5 86322.1 2265.29 9 -2 -1 5 86080.6 3220.61 13 2 1 -5 101926. 3534.36 8 2 -1 -5 86302.3 2709.18 8 2 1 -5 102565. 3001.55 4 2 -1 -5 94218.9 2782.68 7 -2 1 3 139786. 4173.22 3 -2 -1 3 123605. 5063.43 2 -2 1 3 137520. 2971.18 10 -2 -1 3 126981. 3976.46 13 2 -1 -3 126905. 2901.09 9 2 -1 -3 149302. 2932.61 8 2 1 -3 142614. 3390.02 4 2 -1 -3 138920. 3046.54 7 -2 1 1 796.132 170.583 10 2 -1 -1 468.399 133.444 9 2 -2 -14 98.1901 194.317 7 2 2 -12 213.399 172.199 4 2 -2 -12 117.121 301.104 7 -2 -2 10 392.364 326.655 13 2 2 -10 98.5199 171.265 4 2 -2 -10 9.71428 134.996 7 -2 2 10 141.276 254.080 5 2 -2 -10 204.270 130.028 1 -2 -2 8 1696.63 567.168 13 -2 -2 8 1773.71 413.172 1 2 -2 -8 2238.09 470.758 1 2 2 -8 1814.69 385.880 5 -2 2 8 1739.18 401.942 5 2 2 -8 2053.00 577.436 4 -2 2 8 1086.90 430.544 14 2 -2 -8 1708.01 484.870 7 2 2 -6 0.95548 124.523 4 2 -2 -6 158.356 156.309 7 -2 2 6 395.803 242.728 10 -2 -2 6 179.109 337.350 2 2 -2 -6 55.0491 97.4646 9 2 2 -6 241.322 142.468 5 -2 -2 6 226.923 174.384 1 -2 2 6 133.278 204.375 5 2 -2 -6 143.450 106.296 1 2 2 -6 102.886 173.929 8 -2 -2 6 236.467 311.595 13 -2 2 6 408.641 242.567 14 2 -2 -4 13094.1 1104.42 1 -2 2 4 9106.05 946.466 10 -2 -2 4 10751.0 1586.72 2 -2 -2 4 11568.5 1331.64 13 2 -2 -4 8298.84 703.588 9 2 2 -4 11886.8 948.303 5 -2 2 4 9611.30 916.365 5 -2 2 4 9989.06 1021.06 14 2 2 -4 10525.6 1105.33 8 -2 -2 4 10776.5 1033.23 1 2 2 -4 10177.5 1031.34 4 2 -2 -4 11387.9 956.526 7 -2 2 2 14717.1 1163.19 10 -2 2 2 11364.1 971.205 5 -2 2 2 13628.8 1324.67 3 2 2 -2 12051.5 914.353 5 2 -2 -2 15783.1 1028.11 9 2 2 -2 15436.9 1118.21 4 2 -2 -2 14854.8 903.028 7 -2 -2 2 10304.5 1247.36 13 -2 2 0 1492.49 337.753 10 2 -2 0 1767.54 312.768 9 -2 2 -2 8813.89 842.474 10 2 -2 2 7015.28 637.798 9 -2 2 -4 2524.81 458.213 10 2 -2 4 1478.76 281.886 9 -2 2 -6 1129.94 328.482 10 2 -2 6 2326.99 391.272 9 2 -3 -13 834.163 483.343 7 -2 -3 11 12058.7 1669.85 13 2 -3 -11 9406.68 1427.63 7 2 3 -11 10678.9 1572.69 4 -2 -3 9 21085.3 2192.05 13 2 -3 -9 25834.0 2061.85 1 -2 3 9 22154.1 1851.49 5 2 3 -9 14918.2 1383.92 5 2 -3 -9 22026.1 1964.36 7 2 3 -9 18675.2 1946.26 4 -2 -3 7 2966.01 652.127 1 2 -3 -7 3393.06 674.501 7 -2 -3 7 2365.25 741.500 13 2 3 -7 2393.50 682.604 4 2 3 -7 2324.70 555.086 5 -2 3 7 2942.45 657.383 5 2 -3 -7 3478.14 733.129 1 2 -3 -5 1067.56 320.376 7 2 3 -5 2051.84 622.262 4 -2 -3 5 1325.24 572.029 13 -2 3 5 684.067 315.570 10 -2 3 5 1847.28 755.551 3 2 -3 -5 1081.78 335.869 9 2 3 -5 1085.37 394.680 5 2 -3 -5 883.738 385.757 1 -2 3 5 940.884 376.195 5 -2 3 5 459.050 215.618 14 -2 -3 5 910.313 390.327 1 2 3 -3 57.7384 194.979 4 -2 3 3 120.426 157.846 10 2 -3 -3 65.1497 208.531 7 -2 -3 3 76.4661 334.968 2 -2 -3 3 -117.055 244.367 1 2 3 -3 -80.3877 124.818 5 2 -3 -3 53.0829 126.497 9 -2 3 3 357.879 254.488 5 -2 3 3 210.386 282.078 3 -2 -3 3 -15.3492 275.430 13 -2 3 3 248.890 249.113 14 -2 3 1 -162.942 173.536 10 2 -3 -1 106.353 134.869 9 -2 3 1 154.711 177.871 14 -2 3 -1 964.443 390.733 10 2 -3 1 651.336 234.048 9 -2 3 -1 639.971 229.730 14 -2 3 -3 -24.2531 218.890 10 2 -3 3 80.9858 161.866 9 2 -3 5 291.810 210.427 9 -2 3 -5 704.278 378.045 10 -2 3 -7 2091.29 586.608 10 2 -3 7 2559.92 437.602 9 2 4 -8 59.9650 215.009 4 2 4 -8 -82.6299 295.401 5 -2 -4 6 3398.71 793.477 1 -2 -4 6 1665.28 610.627 13 2 4 -6 1658.56 595.204 4 2 4 -6 1831.63 523.566 5 -2 4 4 170.649 167.096 10 -2 4 2 -237.454 241.712 10 2 -4 -2 15.4520 218.719 9 -2 4 0 -140.713 153.390 10 2 -4 0 279.366 176.602 9 -2 4 -2 1005.21 489.059 10 2 -4 2 1102.63 371.225 9 -2 4 -4 5010.57 1076.42 10 2 -4 4 4467.83 789.062 9 -2 4 -6 155.255 276.230 10 2 -4 6 418.307 307.349 9 -2 5 -3 194.843 252.586 10 -2 5 -5 -87.4631 275.247 10 3 0 -19 298.021 340.786 7 -3 0 19 233.749 399.585 3 3 0 -17 3.20759 235.570 7 -3 0 17 -27.2113 496.195 3 3 0 -15 -71.6182 134.879 7 -3 0 15 28.2779 331.739 3 3 0 -13 198.766 226.787 7 3 0 -11 77.5972 148.193 7 -3 0 11 85.7911 87.8979 13 3 0 -11 -5.13831 107.632 4 -3 0 11 -115.170 157.007 3 -3 0 11 -175.386 147.013 14 3 0 -9 -133.453 155.894 4 3 0 -9 -155.790 177.223 7 -3 0 9 -122.049 128.451 13 -3 0 9 -302.618 365.647 3 3 0 -9 -41.8360 29.6738 9 -3 0 9 -119.247 325.077 2 3 0 -9 -291.356 315.545 8 -3 0 7 -44.1282 114.383 13 3 0 -7 83.2770 72.2203 7 3 0 -7 -8.84143 100.659 8 -3 0 7 38.7189 182.982 3 3 0 -7 31.8637 65.7146 4 3 -1 -18 183.934 312.095 7 3 -1 -16 10292.9 1505.78 7 3 -1 -14 3579.01 829.022 7 3 1 -14 2491.25 454.296 7 3 -1 -12 3970.82 760.219 7 -3 -1 12 3760.78 730.847 13 3 1 -12 3089.01 650.978 4 -3 1 12 4144.79 828.124 14 3 1 -12 2905.23 437.071 7 -3 -1 12 2562.73 639.740 3 -3 1 10 -31.9278 233.933 14 -3 -1 10 -139.176 101.895 1 -3 -1 10 -23.5725 143.203 13 3 -1 -10 82.3351 167.064 7 3 1 -10 199.277 270.509 4 3 1 -10 38.8010 60.4670 7 3 -1 -10 -19.0641 60.1190 9 3 1 -10 105.179 65.8938 5 3 -1 -8 2611.68 471.432 7 -3 1 8 3050.45 407.016 10 3 1 -8 2768.15 312.897 5 -3 -1 8 2696.99 769.979 2 3 -1 -8 2932.83 373.672 9 -3 -1 8 2865.08 606.929 13 -3 -1 8 2860.02 382.164 1 3 1 -8 3042.90 723.035 8 3 1 -8 3032.39 541.387 4 3 -1 -8 2232.89 202.570 4 -3 -1 6 1450.35 419.994 13 3 -1 -6 1521.44 331.740 7 -3 1 6 1514.49 254.565 10 -3 1 6 1321.85 491.139 3 3 -1 -6 1156.56 233.263 9 3 1 -6 1100.02 376.992 8 3 -1 -6 1760.47 387.520 8 3 1 -6 1526.13 357.472 4 -3 1 4 78330.0 1919.13 10 -3 1 4 62876.1 2909.75 3 3 -1 -4 54496.2 1710.25 9 3 -1 -4 92367.4 2332.32 7 3 -2 -17 1218.73 653.250 7 3 -2 -15 11011.6 1661.07 7 3 -2 -13 533.215 291.935 7 -3 -2 13 607.730 366.079 13 3 2 -13 908.129 460.888 4 3 -2 -11 -23.7980 186.842 7 3 2 -11 410.836 392.284 4 -3 -2 11 145.750 284.231 13 -3 2 11 13.1704 358.351 14 -3 -2 9 35799.2 2667.39 13 -3 2 9 29211.2 1883.67 10 -3 -2 9 46277.9 4010.02 2 3 -2 -9 34486.4 1628.63 9 3 2 -9 40570.0 1945.46 5 3 2 -9 36849.4 2881.37 8 3 2 -9 34436.4 2221.06 4 3 -2 -9 38057.2 2298.73 7 -3 2 9 27954.4 2158.19 14 -3 -2 9 36838.5 1912.03 1 -3 2 7 2917.24 588.876 14 3 -2 -7 2452.31 477.859 7 -3 2 7 2832.54 569.203 10 -3 -2 7 2267.30 720.387 2 -3 -2 7 3037.42 559.668 1 3 2 -7 3292.45 492.907 5 -3 2 7 3444.46 944.879 3 3 -2 -7 2242.85 375.066 9 3 2 -7 3012.39 690.318 8 3 2 -7 2830.64 580.549 4 -3 -2 7 2356.90 668.681 13 -3 -2 5 57.3838 213.243 13 3 -2 -5 396.135 200.078 7 -3 2 5 465.460 245.880 10 3 2 -5 190.273 129.644 5 -3 2 5 442.928 266.330 3 3 -2 -5 509.131 178.829 9 3 2 -5 133.133 141.534 4 -3 2 3 16483.3 1186.46 10 3 -2 -3 14919.5 990.090 9 3 -2 -3 16044.2 1026.10 7 -3 2 1 20535.9 1268.74 10 3 -2 -1 20158.0 1188.32 9 -3 2 -1 2132.23 378.858 10 3 -2 1 2143.31 343.464 9 3 -3 -16 589.368 470.463 7 -3 3 16 -632.750 768.783 3 3 -3 -14 -488.090 390.300 7 3 -3 -12 -307.731 274.277 7 -3 -3 12 -313.921 353.511 13 3 3 -12 -294.901 297.103 4 3 -3 -10 948.311 371.300 7 -3 -3 10 1143.23 659.259 13 3 3 -10 865.861 478.181 4 -3 -3 10 824.897 408.662 1 -3 3 10 238.842 538.370 3 3 3 -10 864.215 311.250 5 -3 -3 8 7031.62 1040.06 1 -3 -3 8 4630.48 989.484 13 -3 3 8 6021.18 991.762 10 -3 3 8 7456.24 1717.05 3 3 -3 -8 6324.99 798.588 9 3 3 -8 7903.79 1057.76 5 3 3 -8 7851.12 1278.53 4 3 -3 -8 6560.15 930.457 7 -3 3 8 5061.59 970.352 14 3 3 -6 395.520 200.568 4 3 -3 -6 637.982 276.384 7 -3 3 6 -106.510 238.103 10 -3 -3 6 -96.8086 680.969 2 -3 -3 6 313.511 224.021 1 3 3 -6 108.116 139.800 5 3 -3 -6 601.344 248.357 9 -3 -3 6 -311.680 350.918 13 -3 3 6 338.667 330.283 3 -3 3 6 95.0229 152.626 14 -3 3 4 2945.66 689.001 14 -3 3 4 2455.98 785.641 3 3 -3 -4 3768.22 581.000 7 -3 3 4 3200.28 702.757 10 3 -3 -4 2847.28 472.748 9 -3 3 2 582.888 276.375 14 -3 3 2 461.116 230.456 10 3 -3 -2 416.007 262.828 9 -3 3 0 3284.77 698.820 10 3 -3 0 3486.08 590.906 9 -3 3 -2 -198.981 200.726 10 3 -3 2 -94.1334 165.940 9 -3 3 -4 925.570 383.702 10 3 -3 4 1940.43 425.724 9 3 -4 -11 333.454 391.386 7 3 4 -11 -156.170 168.661 4 -3 4 11 446.463 764.728 3 -3 -4 11 300.477 469.228 13 -3 4 9 729.574 530.066 3 -3 4 5 -381.556 386.406 10 3 -4 -5 213.821 153.003 9 -3 4 3 238.025 247.403 10 3 -4 -3 -73.8138 119.951 9 -3 4 1 311.593 401.742 10 3 -4 -1 -63.4043 142.760 9 -3 4 1 231.333 171.004 14 -3 4 -1 259.074 319.088 10 3 -4 1 -40.5174 210.761 9 -3 4 -3 1182.98 514.109 10 3 -4 3 1023.35 407.080 9 -3 5 0 -45.6892 438.543 10 -3 5 -2 1596.37 817.187 10 4 0 -20 5144.74 1079.12 7 -4 0 20 13725.7 2620.29 3 4 0 -18 1181.79 430.803 7 -4 0 18 1497.33 730.705 3 4 0 -16 3506.20 709.505 7 -4 0 16 2977.48 1008.73 3 -4 0 14 4123.60 1112.64 3 4 0 -14 3955.84 671.003 7 4 0 -14 3281.93 576.320 4 4 0 -12 105.015 78.9457 4 -4 0 12 77.9999 117.445 13 4 0 -12 174.675 122.275 7 -4 0 12 -18.2664 124.117 14 -4 0 12 -213.150 160.554 3 -4 0 10 1616.50 363.931 13 4 0 -10 1222.82 302.660 7 -4 0 10 1972.36 665.362 2 4 0 -10 1557.72 164.155 9 4 0 -10 2113.57 620.856 8 -4 0 10 1144.99 477.129 3 4 0 -10 1828.63 376.898 4 4 0 -8 2056.77 568.068 8 4 -1 -21 109.392 388.038 7 -4 1 21 1169.09 1075.41 3 4 -1 -19 2317.02 827.099 7 -4 1 19 1272.90 426.537 3 -4 1 17 6690.74 1737.35 3 4 -1 -17 5532.87 1068.47 7 4 -1 -15 317.884 245.382 7 -4 -1 15 136.954 175.515 13 4 1 -15 492.746 291.585 4 4 1 -15 -49.5856 70.2099 7 -4 1 15 -289.164 660.528 3 4 -1 -13 143.138 200.210 7 -4 -1 13 -339.095 365.724 13 4 1 -13 133.422 154.890 4 -4 1 13 248.162 311.682 3 -4 1 13 130.362 294.225 14 -4 1 11 265.505 272.993 14 -4 -1 11 463.681 214.845 13 4 -1 -11 -138.033 216.599 7 4 1 -11 183.141 231.314 4 -4 1 11 -22.8528 234.707 3 -4 -1 11 626.888 680.789 2 4 -1 -11 45.6234 80.3903 9 4 1 -11 -248.653 248.370 8 -4 -1 9 274.726 230.064 13 -4 1 9 237.374 57.5228 13 4 -1 -9 112.573 128.949 7 -4 -1 9 224.578 452.753 2 -4 1 9 267.308 115.302 10 -4 1 9 134.238 243.388 2 4 1 -9 97.2629 46.9243 5 -4 1 9 295.052 262.824 3 4 -1 -9 195.513 102.794 9 4 1 -9 89.6692 118.122 8 4 -1 -9 280.558 155.691 8 4 1 -9 683.059 292.807 4 4 -1 -9 326.814 103.091 4 -4 1 7 31845.3 1193.74 10 -4 1 7 21917.0 2013.57 3 4 -1 -7 25505.3 1150.59 9 4 -1 -7 35084.5 1903.94 8 4 -1 -7 36659.3 1672.91 7 4 -2 -20 760.790 668.367 7 -4 2 20 1865.01 1216.25 3 4 -2 -18 1886.80 784.071 7 -4 2 18 853.362 890.832 3 4 -2 -16 283.260 228.927 7 4 2 -16 111.221 251.120 4 -4 2 16 524.275 390.213 3 -4 -2 14 17295.9 1955.62 13 -4 2 14 19462.2 3074.52 3 4 -2 -14 17763.7 1868.70 7 4 2 -14 16781.6 1909.14 4 -4 -2 12 11222.5 1521.73 13 -4 2 12 10897.1 2071.64 3 4 2 -12 12211.7 1521.94 4 4 -2 -12 11730.4 1370.21 7 -4 2 12 10311.4 1404.71 14 4 2 -10 2683.18 658.320 4 -4 2 10 2169.04 585.057 14 -4 -2 10 2536.38 724.071 13 4 -2 -10 2314.50 540.565 7 -4 2 10 2375.99 536.813 10 -4 -2 10 3660.38 1267.93 2 -4 -2 10 2565.96 555.292 1 -4 2 10 2519.46 929.069 3 4 2 -10 2423.05 428.084 5 4 -2 -10 2739.57 428.913 9 4 2 -10 3164.63 903.541 8 -4 2 8 29845.3 1754.05 10 -4 2 8 28067.6 2750.07 3 4 -2 -8 31714.3 1635.26 9 4 -2 -8 30820.3 1862.47 7 -4 2 6 2494.73 732.033 3 -4 2 6 2880.70 502.264 10 4 -2 -6 2638.52 426.377 9 4 -2 -6 2958.59 417.840 8 4 -2 -6 3353.16 539.216 7 -4 2 4 1715.66 372.947 10 4 -2 -4 1897.67 362.926 9 4 -3 -17 -479.846 506.465 7 -4 3 17 -1249.62 1233.47 3 4 -3 -15 569.018 370.996 7 -4 -3 15 93.7571 341.704 13 4 3 -15 676.352 403.198 4 -4 3 15 863.374 559.932 3 4 -3 -13 352.177 401.969 7 -4 -3 13 941.715 547.565 13 4 3 -13 482.289 518.664 4 -4 3 13 542.391 733.573 3 4 3 -11 1586.47 607.901 4 -4 -3 11 1357.51 603.978 13 4 -3 -11 1771.96 571.817 7 -4 3 11 1577.21 869.135 3 -4 3 11 1714.31 622.117 14 4 -3 -9 3317.20 659.599 7 -4 3 9 2056.87 607.611 10 4 -3 -9 3114.76 541.847 9 -4 3 9 2756.28 987.889 3 -4 3 9 2231.15 645.277 14 -4 3 7 174.600 198.642 14 4 -3 -7 -126.380 197.530 7 -4 3 7 5.22795 241.708 10 4 -3 -7 -31.7880 79.8467 9 -4 3 7 179.659 340.431 3 -4 3 5 763.855 413.493 14 -4 3 5 448.534 279.424 10 4 -3 -5 722.914 244.667 9 -4 3 3 2612.41 602.003 10 4 -3 -3 2003.64 434.308 9 -4 3 1 5516.47 822.081 10 4 -3 -1 6327.86 749.498 9 4 -4 -14 341.571 291.354 7 -4 4 14 144.499 832.036 3 4 -4 -12 277.725 393.275 7 -4 4 12 291.971 958.084 3 4 -4 -10 39.7535 246.036 7 -4 4 10 647.910 517.152 3 -4 4 8 778.996 394.118 10 4 -4 -8 -35.3213 225.854 9 -4 4 6 96.5739 189.024 10 4 -4 -6 205.578 224.021 9 -4 4 6 -48.9995 169.705 14 -4 4 4 276.927 234.020 10 4 -4 -4 471.358 320.063 9 -4 4 4 856.755 479.076 14 -4 4 2 640.965 286.843 10 4 -4 -2 932.264 321.485 9 -4 4 2 35.6334 136.984 14 -4 4 0 863.038 448.611 10 4 -4 0 601.688 271.947 9 -4 5 5 935.705 587.747 10 -4 5 3 122.730 406.397 10 5 0 -21 -169.241 250.836 7 5 0 -19 149.981 229.954 7 -5 0 19 -54.4282 282.038 3 5 0 -17 -235.333 179.862 7 -5 0 17 779.802 615.145 3 -5 0 15 -39.5139 294.011 3 5 0 -15 -83.3199 82.4305 4 5 0 -15 -107.063 128.676 7 5 0 -13 -175.693 216.914 4 -5 0 13 169.930 160.589 13 -5 0 13 -234.303 106.466 3 5 0 -13 -59.0841 139.193 7 -5 0 13 -92.2860 302.636 2 5 0 -13 273.111 295.983 8 -5 0 11 49.4929 120.251 13 -5 0 11 4.78129 367.223 2 5 0 -11 -68.7588 213.372 8 5 0 -11 -24.1143 131.399 4 5 -1 -22 -49.1025 274.486 7 -5 1 22 844.351 821.960 3 5 -1 -20 868.131 413.820 7 -5 1 20 1361.73 1114.06 3 5 -1 -18 3351.68 877.491 7 -5 1 18 2172.20 1084.94 3 -5 -1 16 921.626 444.630 13 5 -1 -16 718.508 404.795 7 5 1 -16 545.266 426.393 4 -5 1 16 100.151 297.674 3 -5 1 16 748.016 263.058 14 -5 1 14 2136.12 570.289 14 5 1 -14 1915.86 601.758 4 -5 -1 14 1972.65 548.120 13 5 -1 -14 1443.73 441.877 7 -5 1 14 1305.77 704.745 3 -5 -1 12 -394.459 193.317 13 5 -1 -12 -82.4671 121.644 7 -5 -1 12 326.182 314.352 2 5 -1 -12 8.97561 44.3607 9 5 1 -12 470.728 452.695 8 5 -1 -12 182.789 152.053 8 -5 1 12 -21.4646 173.255 3 5 1 -12 -120.123 109.825 4 -5 1 10 1174.65 510.982 3 5 -1 -10 1551.91 403.802 7 -5 1 10 1384.41 473.889 2 -5 1 10 1532.88 294.289 10 5 -1 -10 1248.40 241.413 9 5 -1 -10 1939.83 562.179 8 5 -1 -10 1594.33 272.712 4 5 -2 -21 -379.526 226.883 7 5 -2 -19 688.896 439.245 7 -5 2 19 -219.355 463.645 3 5 -2 -17 2125.55 743.000 7 -5 -2 17 1524.12 754.985 13 5 2 -17 1805.81 750.115 4 -5 2 17 1096.82 993.788 3 5 2 -15 -462.076 342.152 4 -5 -2 15 174.964 250.009 13 5 -2 -15 155.280 312.826 7 -5 2 15 115.398 240.103 3 -5 2 15 204.816 386.121 14 -5 -2 13 8245.06 1473.83 13 5 -2 -13 8238.82 823.212 9 -5 -2 13 10191.4 2204.23 2 -5 2 13 8025.89 1784.69 3 5 2 -13 6922.05 1470.73 8 5 2 -13 5037.91 995.794 4 5 -2 -13 6937.53 1078.23 7 -5 2 13 8022.71 1252.26 14 -5 2 11 49.6002 193.712 14 5 -2 -11 329.633 220.369 7 5 -2 -11 472.142 196.163 9 -5 2 11 444.332 549.749 3 -5 2 9 2227.58 796.874 3 5 -2 -9 3140.98 630.642 7 -5 2 9 2786.26 537.917 10 5 -2 -9 2638.66 448.980 9 5 -2 -9 2016.97 481.788 8 5 -2 -7 27307.0 1421.57 9 5 -2 -7 24306.2 1420.54 8 5 -3 -18 76.3972 260.510 7 -5 3 18 1093.32 929.351 3 5 -3 -16 231.976 319.042 7 -5 3 16 408.857 609.063 3 5 -3 -14 4646.20 1033.58 7 -5 3 14 6680.21 2056.24 3 5 -3 -12 52.1211 332.817 7 5 -3 -12 428.864 226.682 9 -5 3 12 217.460 532.123 3 -5 3 12 124.662 206.801 14 -5 3 10 1765.18 646.155 14 -5 3 10 1179.35 796.156 3 5 -3 -10 1783.07 527.530 7 -5 3 10 2626.59 661.677 10 5 -3 -10 1568.17 402.067 9 -5 3 8 685.255 412.834 14 -5 3 8 727.391 357.161 10 5 -3 -8 599.418 234.596 9 -5 3 6 1135.11 403.048 10 5 -3 -6 1023.52 331.462 9 -5 3 4 81.7843 138.284 10 -5 4 15 184.217 468.902 3 5 -4 -15 1267.24 653.224 7 -5 4 13 346.457 566.378 3 5 -4 -13 1227.07 599.539 7 5 -4 -11 948.161 521.155 7 -5 4 9 -290.585 185.047 10 5 -4 -9 634.725 326.326 9 -5 4 9 201.481 341.690 14 -5 4 7 702.367 484.647 10 5 -4 -7 577.488 359.308 9 -5 4 7 267.076 176.418 14 -5 4 5 -189.169 273.723 10 5 -4 -5 -55.1961 178.027 9 -5 4 5 433.466 403.355 14 -6 0 14 7623.48 1680.90 2 6 0 -14 5881.49 1313.18 8 6 0 -14 4852.57 731.291 4 6 -1 -23 1104.89 727.281 7 -6 1 21 1962.26 1352.24 3 6 -1 -21 466.334 579.494 7 -6 1 19 2943.23 1270.08 3 6 -1 -19 3743.07 910.823 7 6 1 -19 2713.03 781.390 4 -6 -1 17 13048.1 1627.29 13 6 1 -17 10995.4 1470.94 4 6 -1 -17 14151.3 1627.43 7 -6 1 17 12912.3 1819.32 14 -6 1 17 9364.63 2024.17 3 -6 1 15 2114.30 629.556 14 -6 1 15 1184.80 731.796 3 6 -1 -15 1572.20 432.241 7 -6 -1 15 1510.30 924.661 2 6 -1 -13 114.824 151.450 7 -6 1 13 384.522 466.899 2 6 -1 -13 -3.87262 244.819 8 6 -2 -20 705.439 642.857 7 -6 2 20 1391.67 1064.21 3 6 -2 -18 -6.01255 323.162 7 -6 2 18 -622.374 595.142 3 6 -2 -16 -289.039 521.800 7 -6 2 16 118.174 659.974 3 -6 2 16 -343.204 406.182 14 -6 2 14 675.621 476.109 14 6 -2 -14 -58.9286 224.133 7 -6 2 14 -401.763 458.643 3 -6 2 12 744.964 653.684 3 6 -2 -12 749.488 364.922 7 6 -2 -12 880.473 270.295 9 -6 2 10 945.336 286.934 10 6 -2 -10 1242.34 329.299 9 6 -2 -10 988.785 408.582 8 -6 3 17 1191.57 1310.88 3 6 -3 -17 1028.75 565.209 7 -6 3 15 620.688 602.909 3 6 -3 -15 2126.60 757.065 7 -6 3 15 2911.41 951.229 14 -6 3 13 3471.35 1317.23 3 6 -3 -13 5115.73 1030.98 7 6 -3 -13 4138.17 679.558 9 -6 3 13 3533.08 906.450 14 -6 3 11 2782.96 759.388 14 -6 3 11 1804.00 560.681 10 6 -3 -11 2050.28 440.179 9 -6 3 9 440.569 300.507 10 6 -3 -9 102.630 251.058 9 6 -4 -16 6950.82 1426.80 7 6 -4 -12 143.047 190.478 9 -6 4 12 819.314 587.546 14 6 -4 -10 833.335 348.323 9 -6 4 10 50.6594 187.573 14 7 -2 -21 -91.2467 252.526 7 7 -2 -19 1733.82 659.052 7 7 -2 -17 276.660 189.198 7 -7 2 17 308.546 479.323 14 7 -2 -15 403.338 376.610 7 7 -3 -18 365.895 374.356 7 -7 3 16 -19.4622 457.592 14